• Title/Summary/Keyword: elemental analysis

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Chemical Abundance Analysis of Ultra Metal-Poor ([Fe/H] < -4.0) Stars

  • Jeong, Mi Ji;Lee, Young Sun
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.87.1-87.1
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    • 2017
  • We present preliminary results of elemental abundances of six ultra-metal poor (UMP; [Fe/H] < -4.0) stars derived from high-resolution spectra obtained by Gemini/GRACES. The UMP candidates were selected for the high-resolution follow-up from the low-resolution spectra of Sloan Digital Sky Survey (SDSS). We investigate possible progenitors of the UMP objects by comparing the measured abundance patterns with yields that various supernova models predict. Our results can provide stringent constraints on the mass range of the first generation of stars, which are the progenitors of the UMP objects.

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A study on plane-strain forging using UBET (상계요소법을 이용한 평면변형 단조에 관한 연구)

  • 이종헌;김진욱
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.1
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    • pp.7-15
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    • 1998
  • An upper bound elemental technique(UBET) program has been developed to analyze forging load, die-cavity filling and effective strain distribution for flash and flashless forgings. The program consists of forward and backward tracing processes. In the forward program, flash, die filling and forging load are predicted. In backward tracing process, the optimum dimensions of initial billet in conventional forging are determined from the final-shape data based on flash design. And the analysis is described for merit of flashless precision forging. Experiments are carried out with pure plasticine billets at room temperature. The theoretical predictions of forging load and flow pattern are in good agreement with the experimental results.

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Structural Characters of (Phenol-Formaldehyde-Aniline Polymer)-Nickel(Ⅱ) Nitrate ((Phenol-Formaldehyde-Aniline 중합체)-Nickel(Ⅱ) Nitrate 구조에 관한 연구)

  • Doo Soon Shin;Bong Keun Park
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.409-415
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    • 1988
  • In this study, an aniline modified Bakelite-A resine was synthesized by polymerizing phenol, formaldehyde and aniline. Structural properties of the polymer were examined by IR spectroscopy, elemental analysis and vapour pressure osmometry. By visible spectroscopy, it was found that nitrogens of amine groups in the polymer are strongly coordinated to Ni(Ⅱ). Also a nitrate ion-selective PVC membrane electrode based on the polymer-Ni(Ⅱ) complex as ion carrier was preparaed. The electrode gave a linear response with a Nernstian slope within the concentration range $10^{-1}$ M∼$10^{-4}$M $KNO_3$.

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Spectral and Thermal Properties of Some Uranyl Complexes of Some Schiff-Bases Derived from Glycylglycine

  • Sh. A. Sallam;M. I. Ayad
    • Journal of the Korean Chemical Society
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    • v.47 no.3
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    • pp.199-205
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    • 2003
  • Complexes of uranyl ion $UO^{+2}_2$with Schiff-bases obtained by condensing glycylglycine with salicylaldehyde; 2-hydroxy-1-naphthaldehyde, 2,3-dihydroxybenzaldehyde, and 2,4-dihydroxybenzaldehyde have been synthesized and characterized through elemental analysis, conductivity measurements, magnetic susceptibility determinations, u.v., i.r. and $^1H$ nmr spectra as well as d.t.a., t.g. and d.s.c. techniques. Structures and mechanisms of thermal decomposition are proposed.

Synthesis of New 8-Formyl-4-methyl-7-hydroxy Coumarin Derivatives

  • Manidhar, D.M.;Rao, K. Uma Maheswara;Reddy, N. Bakthavatchala;Sundar, Ch. Syama;Reddy, C. Suresh
    • Journal of the Korean Chemical Society
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    • v.56 no.4
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    • pp.459-463
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    • 2012
  • 8-Formyl-4-Methyl-7-Hydroxy Coumarin Derivatives were synthesized via Penchem condensation followed by Duffs reaction. Treatment of this with N,N-di substituted cyano acetamides in the presence of piperdine afforded New 8-Formyl-4-Methyl-7-Hydroxy Coumarin Derivatives (7a-o). Their structures were characterized by IR, $^1H$ and $^{13}C$ NMR and Mass spectral and elemental analysis data.

Synthesis, Characterization and Biological Activities of Novel (E)-3-(1-(Alkyloxyamino)ethylidene)-1-alkylpyrrolidine-2,4-dione Derivatives

  • Zhu, Zhao-Yong;Shi, Qing-Ming;Han, Bao-Feng;Wang, Xian-Feng;Qiang, Sheng;Yang, Chun-Long
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2467-2472
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    • 2010
  • Twenty novel tetramic acid derivatives (E)-3-(1-(alkyloxyamino)ethylidene)-1-alkylpyrrolidine-2,4-diones were synthesized by the reaction of 3-(1-hydroxyethylidene)pyrrolidine-2,4-diones with O-alkyl hydroxylamines. The title compounds were confirmed by IR, $^1H$ NMR, MS and elemental analysis. The structure of compound 6r was further verified by X-ray diffraction crystallography. The bioassays showed that most of the title compounds exhibited noticeable herbicidal and fungicidal activities.

Synthesis and Characterization of the Surface Modified SBA-15 with Dicobaltcarbonyl Complex

  • Park, Sora;Jeon, Yea-Sel;Jun, Ki-Won;Lee, Yun-Jo;Han, Doug-Young;Kim, Hyung Jin;Hwang, Kwang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2077-2080
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    • 2014
  • Cobalt-immobilized SBA-15 6a-c was synthesized from alkyne-attached SBA 5a-c by the reaction with $Co_2(CO)_8$ in toluene. Alkyne group was introduced into amino SBA-15 (4) by imine-linkage or substitution with propargyl bromide to afford iminoalkyne 5a and aminoalkyne 5b, respectively. Meanwhile, alkyne 5c was prepared in one-step by reacting triethoxysilyl hexyne with SBA-15. Dicobalt-complexes 6a-c were characterized by means of FT-IR, solid-state NMR and elemental analysis.

A Study on Stabilization and Mechanical Properties of Polyacrylonitrile-based Fiber with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴계 전구체섬유의 열안정화 및 그 물성에 관한 연구)

  • 신익기;이신희;박수민
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.76-85
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    • 2003
  • In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

Synthesis of novel disperse dyes derived from phthalimide containning diester groups and their dyeing properties

  • Choi, Jae-Hong;Choi, Jong-Yun;Lee, Hyun-Young;Kwon, Oh-Tak
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.03a
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    • pp.45-46
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    • 2009
  • In this study, 12 azo disperse dyes based on phthalimide were synthesized including their precursors. The chemical structures of the dyes and the corresponding precursors were analyzed by the GC-MASS, $^1H$ NMR spectra and elemental analysis. The dyeability on PET, such as step dyeing and build-up properties and color fastness were examined using conventional exhaust dyeing procedures.

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Shape-Stabilized Phase Change Materials : Frozen Gels From Polypropylene and n-Paraffin for Latent Heat Storage

  • Kim, Jong-Hwan;Ko, Jae-Wang;Son, Tae-Won
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.03a
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    • pp.120-121
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    • 2009
  • We prepared polymer-PCM gels such as prepared frozen gel from polypropylene and n-Paraffin for thermal storage and release materials, their basic properties and possible applications especially in latent heat storage. The preparation methods are used to melting method and absorption method respectively. The composition and properties of prepared frozen gels from polypropylene and n-Paraffin were observed by DSC, FT-IR spectra, ARES and Elemental analysis. We can prepare frozen gels in different temperature for latent heat storage materials as controlling composition of phase change material as well as using different incorporating phase change materials. These frozen gels can be used to latent heat storage materials for several applications.

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