[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2014.35.7.2077

Synthesis and Characterization of the Surface Modified SBA-15 with Dicobaltcarbonyl Complex

Park, Sora (Department of Bio & Chemical Engineering, Hongik University)
Jeon, Yea-Sel (Department of Bio & Chemical Engineering, Hongik University)
Jun, Ki-Won (Center for Green Energy, Korea Research Institute of Chemical Technology)
Lee, Yun-Jo (Center for Green Energy, Korea Research Institute of Chemical Technology)
Han, Doug-Young (Korea Basic Science Institute-Seoul Center, Inside of Korea University)
Kim, Hyung Jin (School of Applied Chemical Engineering, Chonnam National University)
Hwang, Kwang-Jin (Department of Bio & Chemical Engineering, Hongik University)

Publication Information

Bulletin of the Korean Chemical Society / v.35, no.7, 2014 , pp. 2077-2080 More about this Journal

Abstract

Cobalt-immobilized SBA-15 6a-c was synthesized from alkyne-attached SBA 5a-c by the reaction with $Co_2(CO)_8$ in toluene. Alkyne group was introduced into amino SBA-15 (4) by imine-linkage or substitution with propargyl bromide to afford iminoalkyne 5a and aminoalkyne 5b, respectively. Meanwhile, alkyne 5c was prepared in one-step by reacting triethoxysilyl hexyne with SBA-15. Dicobalt-complexes 6a-c were characterized by means of FT-IR, solid-state NMR and elemental analysis.

Keywords

Alkyne; Cobalt complex; Mesoporous SBA-15; Immobilization;

Citations & Related Records

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