• Title/Summary/Keyword: electronic transitions

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Measurement of Ar Temperature of Hollow Cathode Discharge Plasma

  • Lee, Jun-Hoi;Shin, Jae-Soo;Lee, Sung-Jik;Lee, Min-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.381-385
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    • 2005
  • The plasma temperature of Ar gas in hollow cathode discharge were measured. This is done by measuring the line profile of the 1s/sub 8/-2p/sub 8/ transition in Ar, using a single-frequency diode laser. Low power diode lasers have been successfully used for investigation of the line profiles of Ar transitions in hollow cathode discharges. It turns out that the plasma temperature of Ar is 640∼783 K in the discharge current range at 7∼10 mA.

A Study on Stimulus reaction and Physical Properties of PBDG (PBDG의 자격반응과 물성에 관한 연구)

  • Chang, Hun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1047-1049
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    • 2001
  • The displacemant current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitions of Poly-${\gamma}$ -benzyl D-glutamate(PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBDG on the water surface. We measured analyzed displacement current that occur when differed temperature. Could know that displacement current is proportional in increase of temperature and great as experiment result.

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Spectroscopic Identification of Isomeric 2,3- and 2,6-Dimethylbenzyl Radicals in Corona Discharge

  • Yoon, Young Wook;Lee, Sang Kuk
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.763-767
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    • 2013
  • We resolved the controversial assignments of the visible vibronic bands observed from corona discharge of 1,2,3-trimethylbenzene. The vibronic bands belonging to the jet-cooled 2,6-dimethylbenzyl radical were clearly identified from the spectrum observed from corona discharge of 2,6-dimethylbenzyl chloride. After subtracting the bands of the 2,6-isomer from the spectrum observed from corona discharge of 1,2,3-trimethylbenzene, the vibronic bands of the 2,3-isomer were also identified. By comparing data with the known vibrational data of 1,2,3-trimethylbenzene and the results of ab initio calculations, we determined the electronic energies of the $D_1{\rightarrow}D_0$ transitions and vibrational mode frequencies in the ground electronic states of the 2,3-and 2,6-dimethylbenzyl radicals.

A partitioning-based synthesis algorithm for the design of low power combinational circuits under area constraints (면적 제약조건하의 저전력 조합회로 설계를 위한 분할 기반 합성 알고리즘)

  • Choi, Ick-Sung;Kim, Hyoung;Hwang, Sun-Young
    • Journal of the Korean Institute of Telematics and Electronics C
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    • v.35C no.7
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    • pp.46-58
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    • 1998
  • In this paper, we propose a synthesis algorithm for the design of low powe rcombinational circuits under area constraints. The proposed algorithm partitions a given circuit into several subcircuits such that only a selected subcircuit is activated at a time, hence reduce unnecessary signal transitions. Partitioning of a given circuit is performed through adaptive simulated annealing algorithm employing the cost function reflecting poer consumption under area constraints. Experimental reuslts for the MCNC benchmark circuits show that the proposed algorithm generates the circuits which consume less power by 61.1% and 51.1%, when compared to those generated by the sis 1.2 and the precomputation algorithm, respectively.

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Rubbing Angle Effects on the Electro-Optic Characteristics of In-Plane Switching Liquid Crystal Display

  • Kim, Hyang-Yul;Song, Il-Sub;Lee, Seung-Hee
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.1
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    • pp.24-28
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    • 2003
  • We have studied the influence of rubbing angles with respect to in-plane field direction on electro-optic characteristics of in-plane switching (IPS) liquid crystal display. The results show that the threshold voltage increases and the operational voltage decreases as the rubbing angle increases. Further, the total response time and also response times associated with grey-to-grey transitions become fast as the rubbing angle decreases.

OPTICAL SPECTROSCOPY AND LIGAND FIELD PARAMETERS OF CIS-DIBROMO(1,4,8,11-TETRAAZACYCLOTETRADECANE) CHROMIUM(III) BROMIDE

  • Choi, Jong-Ha
    • Journal of Photoscience
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    • v.4 no.3
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    • pp.121-125
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    • 1997
  • The 77 K emission and excitation, and room-temperature visible spectra of cis[Cr(cyclam)Br$_2$]Br (cyclam=1,4,8,11-tetraazacyclotetradecane) are reported. The mid- and far-infrared spectra at room-temperature are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. It is found that nitrogen atoms of the cyclam ligand have strong $\sigma$-donor characters, but bromide ligand has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion. The zerophonon line in the excitation spectrum splits into two components by 172 cm$^{2-}$, and the large $^2E_g$ splitting can be reproduced by the ligand field theory.

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A. Study on the PAAS(Polyamic Acid Alkylamine Salts) Langmuir Films and Langmuir-Blodgett Films using BAM(Brewster angle microscopy) (BAM(Brewster angle microscopy)을 이용한 PAAS(Polyamic Acid Alkylamine Salts)의 Langmuir막과 Langmuir-Blodgett막의 특성 연구)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.147-151
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    • 1996
  • Brewster angle microscopy(BAM) makes it possible to observe the monolayer states on the water subphase and the phase transitions from a gaseous phase via a expanded phase to a condensed phase. Also BAM can be used to observe the films on the solid substrate such as Langmuir-Blodgett(LB) films. In this Paper Polyamic Acid Alkylamine Salts(PAAS) was used for forming L films and LB films and $\pi$-A isotherm showed pressure of each phase. We obtained BAM images as surface pressure increased. Images of LB films were compared with data from ellipsometry which was used to measure the film thickness. Images of both L films and LB films were analyzed with computer in the point of brightness.

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Measurement of plasma temperature in hollow cathode discharge

  • Lee, Jun-Hoi;Yoon, Man-Young;Kim, Song-Kang;Park, Jae-Jun;Jeon, Byung-Hoon;Woo, Young-Dug
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.488-491
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    • 2002
  • We report the observation of line shapes in the optogalvanic spectrum, which are different from those of absorption, for transitions origination from the $3P_2$ ($1s_5$ in Paschen notation) metastable level of argon. The OG line shapes resemble those of absorption and be used to diagnose the characteristics of the discharge plasma. The measured plasma temperatures of Ar hollow cathode discharge for several metal cathodes are about 620~780K at discharge current of 7~10mA.

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A Study on the Electrical Properties of Biology Thin (생체박막의 전기특성에 관한 연구)

  • 오재한;김동관;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.243-246
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    • 1999
  • The displacement current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is the water, With Maxwll-displacement-current-measuring method, the phase transitions of Poly(λ-benzyl- L-glutamate)(PBLG) on a water surface were detected, Displacement currents generated during the compression of monolayers of PBLG on the surface of water were investigated. As results, the displacement pick was generated when the area per molecule was about 15 $\AA$$^{2}$ in low pressure, and tit was generarted when the area per molecule about 27$\AA$$^{2}$ in high pressure.

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A study on Electrical Properties of the Polyamic Acid Alkylamine Salts(PAAS) LB films (Polyamic Acid Alkylamine Salts(PAAS) LB 박막의 전기적 특성에 관한 연구)

  • 이호식;이원재;김태완;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.298-301
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    • 1997
  • This paper describes the thermally stimulated current(TSC) measurements arachidic acid(AA) and polyamic acid alkylamine salts(PAAS) LB film, which is a precursor of polyimide(PI). The measurements were performed from room temperature to about 250$^{\circ}C$ and the temperature was increased at a rate of 0.02 $^{\circ}C$/s linearly[4]. It shows that peaks of TSC are observed at about 80$^{\circ}C$ in the arachidic acid and about 80$^{\circ}C$, 160$^{\circ}C$ in the PAAS LB films. The DSC and TGA of PAAS, arachidic acid are measure. Monolayer phases on the water subphase such as Langmuir(L) films and the phase transitions from gas phase to solid phase via liquid phase are observed using Brewster angle microscopy(BAM). BAM is also used to observe the Langemuir-Blodgett(LB) films.

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