• Title/Summary/Keyword: electronic structures

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First-principle study on interplay between structural and electronic properties of armchair CNTs

  • Lee, Hayoung;Kim, Cheol-Woon
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.472-474
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    • 2014
  • Carbon nanotubes (CNTs) have been intensively investigated since they have been considered as building blocks of nanoscience and nanotechnology. Theoretical and computational studies on CNTs have revealed their physical and chemical properties and helped researchers build various experimental devices to study them in depth. However, there have been only few systematic studies on detailed changes in electronic structures of CNTs due to geometrical structure modifications. In this regard, it is necessary to perform systematic investigations of the modifications in electronic structures of CNTs, as their geometrical configurations are altered, using the first-principles density functional theory. In other words, it is essential to determine the true equilibrium structure of CNTs. We are going to construct different atomic configurations of each nanotube by maintaining the original symmetries, but changing all the other bonding types one by one. Furthermore, as for CNTs, for example, the way the graphene sheet is wrapped is represented by a pair of indices (n,m) and electronic structures of CNTs vary depending on different indices. Therefore, we plan to study and discuss all the significant couplings between electronic and geometric structures in CNTs.

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Highly Sensitive Trimethylamine Sensing Characteristics of V-doped NiO Porous Structures (바나듐이 도핑된 NiO 다공성 구조의 고감도 Trimethylamine 감응 특성)

  • Park, Sei Woong;Yoon, Ji-Wook;Park, Joon-Shik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.25 no.3
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    • pp.218-222
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    • 2016
  • Pure and V-doped NiO porous structures were prepared by the evaporation-induced surfactant assembly and subsequent pyrolysis of assembled structures, and their gas sensing characteristics were investigated. Pure NiO porous structures showed negligible gas responses (S=$R_g/R_a$, $R_g$: sensor resistance in analytic gas; $R_a$: sensor resistance in air) to 5 ppm trimethylamine (S=1.17) as well as other interfering gases such as ethanol, p-xylene, toluene, benzene and formaldehyde (S=1.02-1.13). In contrast, the V-doped NiO porous structures exhibited a high response and selectivity to 5 ppm trimethylamine (S=14.5) with low cross-responses to other interfering gases (S=4.0-8.7) at $350^{\circ}C$. The high gas response of V-doped NiO porous structures to trimethylamine was explained by electronic sensitization, that is, the increase in the chemoresistive variation due to the decrease in the hole concentration. The enhanced selectivity to trimethylamine was discussed in relation to the interaction between basic trimethylamine gas and acidic V catalysts.

Electronic Structures of Graphene Intercalated by Oxygen on Ru(0001): Scanning Tunneling Spectroscopy Study

  • Jang, Won-Jun;Jeon, Jeung-Hum;Yoon, Jong-Keon;Kahng, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.114-114
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    • 2011
  • Graphene is the hottest topic in condensed-matter physics due to its unusual electronic structures such as Dirac cones and massless linear dispersions. Graphene can be epitaxially grown on various metal surfaces with chemical vapor deposition (CVD) processes. Such epitaxial graphene shows modified electronic structures caused by substrates. In the method for removal of the effect of substrate, there are bi, tri-layer graphene, gold intercalation, and oxygen intercalation. Here, We will present the changes of geometric and electronic structure of graphene grown on Ru(0001) by oxygen intercalation between graphene and Ru(0001). Using Scanning tunneling microscopy (STM) and spectroscopy (STS), we observed the aspect that the band gap features near the fermi level of graphene on Ru(0001) system is shifted and narrow. Based on the observed results, two effects by intercalated oxygen were considered.

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Characterization of Interdigitated Capacitors for Integrated Circuit Application (집적회로 응용을 위한 빗살형 캐패시터의 특성연구)

  • Kim, Kil-Han;Lee, Kyu-Bok;Kim, Jong-Kyu;Yun, Il-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.130-133
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    • 2004
  • The characterization of interdigitated capacitors was investigated. The test structures are manufactured by low temperature co-fired ceramic(LTCC) process and their s-parameters were measured. The optimized equivalent circuit models for test structures were obtained using the partial element equivalent circuit(PEEC) method. Predictive modeling was performed on different test structures using optimized parameters to verify the circuit models. From this result, the manufacturability on the process can be improved through the predictive modeling for the characteristics of interdigitated capacitors.

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A Study on the Atomic and Electronic Structures of DNA-nucleobases-adsorbed Graphene Through First-principles LCAO Method (제일원리 LCAO 방법을 이용한 DNA Nucleobase 흡착된 그라핀의 원자 및 전자구조 연구)

  • Lee, Eun-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.6
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    • pp.510-514
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    • 2011
  • Based on first-principles LCAO method, we study the electronic and atomic structures of DNA nucleobases adenine (A), thymine (T), guanine (G), and cytosine (C) adsorbed on graphene surfaces. The ${\pi}-{\pi}$ stacking interactions between graphene and nucleobases lead to the bilayer geometries similar to the Bernal stacked graphite. Through the density of states and charge density analyses, it is found that nucleobases are physisorbed on graphene by dispersive interactions with negligible charge exchange. Our calculations reproduce the atomic structures obtained in previous plane wave calculations accurately with much less computation, and well describe the delocalized ${\pi}-{\pi}$ interactions in graphene-nucleobases system, indicating that the LCAO method is very efficient for investigating graphene-bio systems.

Electronic State of ZnO doped with Al, Ga and In, Calculated by Density Functional Theory (범함수궤도법을 이용하여 계산한 Al, Ga, In이 도핑된 ZnO의 전자상태)

  • Lee, Dong-Yoon;Lee, Won-Jae;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.218-221
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    • 2004
  • The electronic state of ZnO doped with Al, Ga and In, which belong to III family elements in periodic table, was calculated using the density functional theory. In this study, the program used for the calculation on theoretical structures of ZnO and doped ZnO was Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The detail of electronic structure was obtained by the describe variational $X{\alpha}(DV-X{\alpha})$(DV-Xa) method, which is a sort of molecular orbital full potential method. The optimized crystal structures obtained by calculations were compared to the measured structure. The density of state and energy levels of dopant elements was shown and discussed in association with properties.

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A Study of Electronic Records Folder Management (전자기록철의 구조와 관리방안 - 영국 ERMS 표준을 중심으로 -)

  • Seol, Moon-Won;Cheon, Kwon-Ju
    • Journal of Korean Society of Archives and Records Management
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    • v.5 no.2
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    • pp.49-72
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    • 2005
  • This study aims to analyze the structures of electronic records classification and suggest managing requirements for electronic folder as basic entity for ERM. This present study begins with analyzing the various types of electronic folders based on the Requirements for Electronic Records Management Systems: Functional Requirements of U.K. It designs some examples of classification structures for clarifying the meaning of the electronic folders, components and markers. Finally, it analyses some implications for korean environments including application of electronic folder concept, principles of folder open and closure, and introduction of electronic part entity for efficient folder management.

A Study on the Dielectric Characteristics in Epoxy Resins due to Variation of Network Structures (망목 구조 변화에 따른 에폭시 수지의 유전 특성에 관한 연구)

  • 김재환;손인환;심종탁;김경환;김명호;최병옥
    • Electrical & Electronic Materials
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    • v.10 no.7
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    • pp.651-658
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    • 1997
  • In this paper, effect of interpenetrating polymer network(IPN) introduction on the dielectric properties, heat proof properties, internal structure and defects of the Epoxy/SiO$_2$composite materials, were investigated. we reported a relation between network structures and electrical properties, especially dielectric characteristics with variation of network structures for epoxy composite materials. According to experimental results, the specimens which have single network structures have lower dielectric constant than interpenetrating polymer network(IPN) specimens, but have relatively larger dependency to variation of temperature and frequency. It was confirmed that change of structures is attained by introducing of IPN to insulating materials. Therefore it is counted that introduction of multiple structure including IPN is necessary to improve heat proof and electrical properties.

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Reliability analysis for fatigue damage of railway welded bogies using Bayesian update based inspection

  • Zuo, Fang-Jun;Li, Yan-Feng;Huang, Hong-Zhong
    • Smart Structures and Systems
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    • v.22 no.2
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    • pp.193-200
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    • 2018
  • From the viewpoint of engineering applications, the prediction of the failure of bogies plays an important role in preventing the occurrence of fatigue. Fatigue is a complex phenomenon affected by many uncertainties (such as load, environment, geometrical and material properties, and so on). The key to predict fatigue damage accurately is how to quantify these uncertainties. A Bayesian model is used to account for the uncertainty of various sources when predicting fatigue damage of structural components. In spite of improvements in the design of fatigue-sensitive structures, periodic non-destructive inspections are required for components. With the help of modern nondestructive inspection techniques, the fatigue flaws can be detected for bogie structures, and fatigue reliability can be updated by using Bayesian theorem with inspection data. A practical fatigue analysis of welded bogies is utilized to testify the effectiveness of the proposed methods.

Graphene Based Nano-electronic and Nano-electromechanical Devices

  • Lee, Sang-Wook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.13-13
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    • 2011
  • Graphene based nano-electronic and nano-electromechanical devices will be introduced in this presentation. The first part of the presentation will be covered by our recent results on the fabrication and physical properties of artificially twisted bilayer graphene. Thanks to the recently developed contact transfer printing method, a single layer graphene sheet is stacked on various substrates/nano-structures in a controlled manner for fabricating e.g. a suspended graphene device, and single-bilayer hybrid junction. The Raman and electrical transport results of the artificially twisted bilayer indicates the decoupling of the two graphene sheets. The graphene based electromechanical devices will be presented in the second part of the presentation. Carbon nanotube based nanorelay and A new concept of non-volatile memory based on the carbon nanotube field effect transistor together with microelectromechanical switch will be briefly introduced at first. Recent progress on the graphene based nano structures of our group will be presented. The array of graphene resonators was fabricated and their mechanical resonance properties are discussed. A novel device structures using carbon nanotube field effect transistor combined with suspended graphene gate will be introduced in the end of this presentation.

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