• 한국전기전자재료학회논문지
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• 제22권6호
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• pp.484-488
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• 2009

In this study, in order to develop the lead-free piezoelectric ceramics with high piezoelectric and dielectric properties, $[(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}(Nb_{0.96}Sb_{0.04})]O_3$ ceramics were fabricated using $Ag_2O$ as sintering aid and a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $SrTiO_3$ substitution. $SrTiO_3$ substitution enhanced density, dielectric constant(${\varepsilon}_r$) and electromechanical coupling factor($k_p$). However, mechanical quality factor was deteriorated. And also, Curie temperature ($T_c$), and phase transition temperature($T_p$) were rapidly decreased. At the 0.5 mol% $SrTiO_3$ substitution, density, electromechanical coupling factor($k_p$), dielectric constant(${\varepsilon}_r$) and piezoelectric constant($d_{33}$) of specimen showed the optimum value of $4.437\;g/cm^3$, 0.457, 1294, 265 pC/N, respectively.

• 한국항공우주학회지
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• 제39권6호
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• pp.517-525
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• 2011

차분 진동형 가속도계는 입력 가속도에 따른 공진 주파수의 변화를 감지하는 공진형 센서이다. 이 때 가속도계 전기적 동역학의 수학적 모델링 및 구조 특성의 실험적 검증이 정밀한 제어기 및 높은 양질계수를 가지는 구조 설계에 앞서 필요하게 된다. 본 논문에서는 차분 진동형 가속도계의 공진자, 전극 모듈 및 전치증폭기 등의 전기적 모델링을 제시한다. 이러한 모델링 기법은 공진 주파수, 유효 질량, 유효 강성, 양질 계수 등을 측정함으로써 실험적으로 검증된다. 또한 모델링을 통해 예측된 진폭과 측정된 전치증폭기 출력의 직접적인 비교는 본 연구의 유효성을 보여준다.

• 한국세라믹학회지
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• 제51권6호
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• pp.623-628
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• 2014

Orthorhombic $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals are fabricated using the cost-effective solid-state single crystal growth (SSCG) method; their dielectric and piezoelectric properties are also characterized. Measurements show that (001) $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals have an electromechanical coupling factor ($k_{33}$) higher than 0.83, piezoelectric charge constant ($d_{33}$) of about 400 [pC/N], and piezoelectric voltage constant ($g_{33}$) higher than 50 [${\times}10^{-3}Vm/N$]. The transition temperature ($T_{OT}$) of the (001) $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals between orthorhombic and tetragonal phases is also observed to be about $61^{\circ}C$. Because their electromechanical coupling factor ($k_{33}$) and piezoelectric voltage constant ($g_{33}$) are higher than those of soft PZT ceramics, it is expected that (001) $Ba(Ti_{0.94}Zr_{0.06})O_3$ single crystals can be used as "lead-free" piezoelectric materials in many piezoelectric applications.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.161-164
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• 2001

In this paper, we investigated the dielectric and piezoelectric properties of Pb(Sb, Nb)O$_3$-Pb(Zr, Ti)O$_3$ ceramic(PSN) for piezoelectric transformer and actuator etc. Effect of MnO$_2$ addition on the PSN ceramic was investigated. Anisotropic properties of electromechanical coupling factor and piezoelectric properties proved to be varied with amount of MnO$_2$ impurity and sintering temperature. The electromechanical coupling factor k$_{p}$ of 0.38 and the mechanical quality factor Q$_{m}$ of 1944 were obtained from the specimen with 0.4 wt% MnO$_2$ sintered at 115$0^{\circ}C$ addition. Experimental results indicated that the PSN ceramic with MnO$_2$ impurity can be effectively used for piezoelectric transformer and actuator.tor.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권3호
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• pp.156-156
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• 2000

The piezoelectric properties and the doping effect for $0.95Pb(Zr_xTi_{l-x})O_3+0.O5Pb(Mn_{1/3}Nb_{2/3})O_3$compositions were studied. Also, the heat generation and the change of electromechanical characteristics, the important problem in practical usage, were investigated under high electric field driving. As a experiment results under low electric field, the value of $k_p$ and ${\varepsilon}_{33}^T$ were maximized, but $Q_m$ was minimized $(k_p=0.57, Q_m=1550)$ in the composition of x=0.51. In order to increase the values of $Q_m$, $Nb_2O_5$ was used as a dopant. As the result of that, the grain size was suppressed and the uniformity of grain was improved. Also, the values of $k_p$ decreased, and the values of $Q_m$ increased with doping concentration of $Nb_2O_5$ . As a experiment results under high electric field driving, when vibration velocity was ower than 0.6[m/s], the temperature increase was 20[℃], and the change ratio of mechanical quality factor was less than 10[%]. So, its electromechanical characteristics was very stable. Conclusively, piezoelectric ceramic composition investigated at this paper is suitable for application to high power piezoelectric devices.

• 한국전기전자재료학회논문지
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• 제17권8호
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• pp.830-834
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• 2004

In this study, lead-free pirzoelectric ceramics were investigated for pressure sensor applications as a function of the amount of ${La}_2{O}_3$ addition at $Bi(Na, K)Ti{O}_3-SrTi{O}_3$system. With increasing the amount of addition, the density and dielectric constant increased up to 0.9 wt% ${La}_2{O}_3$ addition and decreased above 0.9 wt% ${La}_2{O}_3$addition. Electromechanical coupling factor( $K_{P}$) showed the maximum value at 0.2 wt% ${La}_2{O}_3$addition and decreased above 0.2 wt% ${La}_2{O}_3$ addition. Electromechanical coupling $factor{(K)}_P$, density, dielectric constant$(\varepsilon_\Gamma)$, piezoelectric constant$(d_33)$ and curie temperature$(T_C)$ showed optimum value of 0.40, 5.75 g/㎤, 768, 215 pC/N and 320 $^{\circ}C$ at 0.2 wt%${La}_2{O}_3$addition, respectively.

• 한국세라믹학회지
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• 제23권3호
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• pp.15-20
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• 1986

Formation of powders and electromechanical coupling factor of $Pb(Mn_{1/3} Sb_{2/3})_{0.08} Ti_{0.495}Zr_{0.425}O_3$ by hydro-thermal synthesis are described. The hydrothermal reactions each were accomplished at 12$0^{\circ}C$~25$0^{\circ}C$ for 5hours and sintering was accomplished at 1, .20$0^{\circ}C$ for 1hours. The PZT powders by hydrothermal synthesis were formed above 16$0^{\circ}C$ and the forms were cubic types. The ratio of grain size of sintered sample to powder was slowly decreased with the rising of hydrothermal reactino temperature but decreased rapidly above 22$0^{\circ}C$ Sintering density was decreased with the rising of hydrothermal reaction temperature above 16$0^{\circ}C$ but dielectric constant was increased. Electromechanical coupling factor $K_P$ was almost constant at 16$0^{\circ}C$~24$0^{\circ}C$ range and the value of $K_P$ was about 0.43-0.45.

• 한국기계가공학회지
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• 제16권1호
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• pp.70-76
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• 2017

The pollution problem of fossil energy sources has caused the development of green energy harvesting systems. Piezoelectric energy harvesting technology has been developed under those external environmental factors. A piezoelectric energy harvester can be defined as a device which transforms mechanical vibration or impact energy into electrical energy. Most researches have focused on bender structures. However, these have a limitation on energy efficiency because of the small effective electromechanical coupling factor, around 10%. Therefore, we should look for a new design for energy harvesting. A cymbal energy harvester can be a good candidate for the high-power energy harvester because it uses a high amplification mechanism using endcaps while keeping a higher electromechanical coupling factor. In this research, we focused on energy efficiency improvements of the cymbal energy harvester by changing the polarization direction, because the electromechanical coupling factor of the k33 mode and the k15 mode is larger than that of the k31 mode. Theoretically, we checked the cymbal harvester with radial polarization and it could obtain 6 times larger energy than that with the k31 direction polarization. Furthermore, we verified the theoretical expectation using the finite element method program. Consequently, we could expect a more efficient cymbal harvester with the radial polarization by comparing two polarization directions.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.806-808
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• 2001

In this thesis, specimens was manufactured in general method annexing PMB-PZT system ceramic, and the following conclusion has been deduced. In XRD, the crystal structure of ceramic has the tetragonal structure which is close to rombohedral structure, and consequently the specimen characterized by MPB was manufactured. According to dopping with xPMB, electromechanical factor(kp) little is changed. kp was maximum value 23.37[%] at xPMB 0.03[mol%]. mechanical quality factor(Qm) was maximum value 237.04 at xPMB 0.03[mo1%].

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.650-652
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• 2002

In this paper, specimens was manufactured in general method annexing PAN-PZT+0.8wt%Mn+1wt% Nb ceramics doped by Sr(0.0 ~ 1.2 wt%). and the following conclusion has been deduced. In XRD, the crystal structure of ceramic has the rombohedral structure and consequently the specimen characterized by MPB was manufactured. According to dopping with Sr, electromechanical factor(kp) little is changed. kp was maximum value 31.31[%] at Sr 1.2[wt%]. mechanical quality factor(Qm) was maximum value 371.879 at Sr 0.6[wt%].