• 제목/요약/키워드: electrolyzing

검색결과 17건 처리시간 0.03초

수중 펄스코로나 방전을 중첩한 고효율 강전해수 발생장치 (A High Efficiency Electrolytic Cell by Superposing Pulsed Corona Discharge in Water)

  • 이재용;김진규;정성진;박승록;문재덕
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제50권2호
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    • pp.79-85
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    • 2001
  • A conventional electrolyzing cell has been made by an ion exchange membrane inbetween parallel plate electrodes. A low dc voltage is applied to the electrodes for electrolyzing and the efficiency is remained in low. in this study, a novel electrolyzing cell with a pair of slit-type third electrodes installed inbetween parallel plate electrodes has been proposed and investigated experimentally. And pulse power wa supplied to between each electrodes. This slit type of third electrodes can concentrate the strong electric fields at the every its edges to accelerate the electrolyzing powers, and to generate oxygen bubble discharges for generating oxidants. And moreover the slits eliminate the space charge limiting action and the temperature of the water by leaking out through the slits from electrolyzing region to outside of the main electrode region. As a result, it was found that a strong electorzed water of pH 2.8 and pH 10.5 and oxidants dissolved water of 1 [ppm] in acidic water were obtained with a tap water fed at the electric current of 2 [A], which however were several times higher oxidant and ion concentration quantity compared with the conventional cell.

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에너지절약형 동(Cu)전해채취 및 전류밀도의 영향 (The effects of current density and nickel content on copper electrowinning by energy saving system)

  • 이후인;이재천;박진태;김민석;손정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.386-387
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    • 2006
  • This study is about the recycling technology of scrap a PCB(printed circuit board) produced in home appliances or automobile industry. And we develop the recycling technology of cooper (Cu)which is contained to leaching solution. In stead of electrolytic collecting in existing sulphuric atmosphere, we apply process using the ammonia solution which is used in economizing energy. So m the process of electrolyzing scrap a PCB through the leaching and separation, we examine the effect of the nickel contained to the solution and the cooper degree of purity which is changed according to current density.

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수중 방전과 공간전하제어에 의한 효과적인 산화성물질 발생특성 (Effective Oxidant Generation and Ion Precipitation Characteristics of Electrolyzing Cell by Discharge and Space Charge Control)

  • 김진규;이대희;문재덕
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 학술대회 논문집 전문대학교육위원
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    • pp.9-12
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    • 2000
  • A new type electrolyzing cell with slits on parallel plate electrodes and wire-to-cylinder type electrode system has been proposed instead of the conventional parallel plate type. An investigation was carried out on the effect of the number and size of slits on ion precipitation and oxidant generation characteristics, evidenced by eliminated space charge limiting action and by elevated electric fields in active interelectrode spacing. And it is also studied on the effect of the diameter of wire electrode to ion precipitation and oxidant generation characteristics. With electrode with 48 slits, very oxidants generation water of 3.1 [ppmm] and 19.0 [ppmm] in positive electrode side were obtained with tap water and 0.1 [wt%] NaCl dissolved tap waterfed. In addition, with wire-to-cylinder type electrode system, it is found that oxidant contained water of 0.48 [ppmm] and 5.46 [ppmm] in positive electrode side were obtained with tap water and 0.1 [wt%] NaCl dissolved tap water fed for the case of discharge electrode diameter of 0.5 [$mm{\phi}$]. Consequently, very high ion precipitation and dense oxidant generation characteristics can be realized by having slits on the electrodes of conventional cell as these slits increase the electric fields and decrease the space charge limiting actions in interelectrode spacing.

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The effect of process parameters on copper powder particle size and shape produced by electrolysis method

  • Boz, Mustafa;Hasheminiasari, Masood
    • Steel and Composite Structures
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    • 제15권2호
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    • pp.151-162
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    • 2013
  • In this study, an electrolyzing device for the production of metal powders was designed and fabricated. The production of copper powders was performed using a variety of current densities, anode-cathode distances and power removal times. The effect of these parameters on powder particle size and shape was determined. Particle size was measured using a laser diffraction unit while the powder shape was determined by SEM. Experimental results show that an increase in current density leads to a decrease in powder particle size. In addition particle shape changed from globular dendritic to acicular dendritic with increasing the current density. Distance between the cathode and anode also showed a similar influence on powder particle size and shape. An increase in time of powder removal led to an increase in powder particle size, as the shape changed from acicular dendritic to globular dendritic.

염화마그네슘의 용융염전해 연구 (Fused Salt Electrolysis of Magnesium Chloride)

  • 이후인
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.546-547
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    • 2007
  • Magnesium is widely used as a lightweight alloy for car engine components and case of cellular phone. Extraction technologies of magnesium are divided to fused salt electrolysis process and thermal reduction process. In this study, electrolysis magnesium is prepared by fused salt electrolysis process with magnesium chloride. We compared two kinds of mixed salt at 7V. As a result, 47% of current efficiency was obtained by electrolyzing KCl/NaCl/$MgCl_2$ mixed salt bath at $760^{\circ}C$, and purity of the prepared magnesium was over 98%. With this study, we can scale up fused salt electrolysis device and accumulate basic data which will be needed for designing an electrolysis cell.

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전기분해 알칼리수를 배합수로 활용한 고로슬래그 혼입 콘크리트의 강도 특성 (Strength Property of Concrete Mixed Blast Furnace Slag Using Electrolysis Alkaline Aqueous as Mixed Water)

  • 정수미;김주성;박선규
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.135-136
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    • 2023
  • In this study, a concrete was prepared using an alkaline aqueous solution produced by electrolyzing potassium carbonate in order to improve the low initial strength of concrete using blast furnace slag. In order to confirm the increase in initial strength, the compressive strength of specimens was measured on the age of 7, 28 days. As a result, the blast furnace slag concrete using the electrolysis alkaline aqueous solution as the mixed water show high strength more than the blast furnace slag concrete using the general mixed water.

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원자력 발전소의 해수전해설비 폐수소를 활용한 PEM 연료전지 발전 시스템에 관한 연구 (A study on the power plant system combined with PEM fuel cell and the wasted hydrogen from the sea water electrolyzer of nuclear power plants)

  • 최종원;이주형;차석원;김민수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.124.2-124.2
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    • 2010
  • Generally, a coolant of the nuclear power plant is manufactured by electrolyzing the sea water near the plant for making the sodium hypochlorite(NaOCl), which is used for sterilizing the bacteria and the shellfishes sticking to the drains or the pumps at the outlet of the cooling system due to $8-10^{\circ}C$ warmer temperature than the inlet sea water. During manufacturing the sodium hypochlorite, the hydrogen with the high purity is also produced at the anode side of the electrolyzer. This paper describes a novel power plant system combined with the polymer electrolyte membrane(PEM) fuel cell, the wasted hydrogen from the sea water electrolyzer and the wasted heat of the nuclear power plant. The present status over the exhausted hydrogen at twenty nuclear power plants in Korea was investigated in this study, from which an available power generation is estimated. Furthermore, the economic feasibility of the PEM fuel cell power plant is also evaluated by a current regulations over the power production and exchange using a renewable energy shown in Korea Power Exchange(KRX).

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기수지역 선박평형수의 염소 생성 효율에 미치는 전기화학 처리의 영향 (Effect of Electrochemical Treatment on the Chlorine Generation Efficiency of Ballast Water in the Brackish Zone)

  • 최용선;이유기
    • 한국재료학회지
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    • 제29권1호
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    • pp.16-22
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    • 2019
  • Indirect oxidation using chlorine species oxidizing agents is often effective in wastewater treatment using an electrochemical oxidation process. When chlorine ions are contained in the wastewater, oxidizing agents of various chlorine species are produced during electrolysis. In a ballast water management system, it is also used to treat ballast water by electrolyzing seawater to produce a chlorine species oxidizer. However, ballast water in the brackish zone and some wastewater has a low chlorine ion concentration. Therefore, it is necessary to study the chlorine generation current efficiency at various chlorine concentration conditions. In this study, the chlorine generating current efficiency of a boron-doped diamond(BDD) electrode and insoluble electrodes are compared with various chloride ion concentrations. The results of this study show that the current efficiency of the BDD electrode is better than that of the insoluble electrodes. The chlorine generation current efficiency is better in the order of BDD, MMO(mixed metal oxide), $Ti/RuO_2$, and $Ti/IrO_2$ electrodes. In particular, when the concentration of sodium chloride is 10 g/L or less, the current efficiency of the BDD electrode is excellent.

수전해 설비에 대한 비상정지상황 발생 요인 도출 (Deduction of Emergency Stop Situation Factors for Water Electrolysis Facilities)

  • 김현기;김태훈;이광원;서두현;이동민
    • 한국수소및신에너지학회논문집
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    • 제34권6호
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    • pp.722-727
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    • 2023
  • There are various types of hydrogen production methods, but among them, the alkaline water electrolysis method produces hydrogen by electrolyzing water, and unlike other methods, it can produce green hydrogen that does not emit pollutants and greenhouse gases. There are many different potential risk factors inherent in the water electrolysis process. So it is necessary to predict an emergency situation in advance and to safely manage and take countermeasures according to the emergency situation. Korea Gas Safety Corporation (KGS) CODE AH271 stipulates legal matters to secure safety, but it is not detalied. Thus it is necessary to take measures to safely control and manage it according to the situation in which an emergency stop is required. In this study, based on KGS CODE and HAZOP for alkaline water electrolysis facilities, factors that can cause emergency situations were derived and countermeasures were prepared.

특허분석을 통한 전해살균수의 기술 동향 연구 (Investigation on the Technology Trend in Electrolyzed Sterilizing Water by the Patent Analysis)

  • 강경석;김태일;이호일;한혜정;박수길;김한주;한삼덕;박근익;이영우
    • 공업화학
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    • 제21권2호
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    • pp.188-194
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    • 2010
  • 전해살균수는 수도물에 식염이나 염산 등의 전해보조제를 첨가시킨 수용액을 전기분해하여 유용한 기능을 갖게 한 수용액이다. 전해살균수는 살균을 목적으로 한 식품위생관리에 사용되는 것으로, 강산성전해수, 미산성전해수 및 차아염소산나트륨수로 나눌 수 있다. 본 연구에서는 살균효과를 지닌 전해살균수의 제조원리, 장단점 분석과 함께 연도별, 국가별, 출원인별, 기술종류별로 기술동향 특허분석을 하였다.