• Title/Summary/Keyword: electrolyzing

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A High Efficiency Electrolytic Cell by Superposing Pulsed Corona Discharge in Water (수중 펄스코로나 방전을 중첩한 고효율 강전해수 발생장치)

  • 이재용;김진규;정성진;박승록;문재덕
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.2
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    • pp.79-85
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    • 2001
  • A conventional electrolyzing cell has been made by an ion exchange membrane inbetween parallel plate electrodes. A low dc voltage is applied to the electrodes for electrolyzing and the efficiency is remained in low. in this study, a novel electrolyzing cell with a pair of slit-type third electrodes installed inbetween parallel plate electrodes has been proposed and investigated experimentally. And pulse power wa supplied to between each electrodes. This slit type of third electrodes can concentrate the strong electric fields at the every its edges to accelerate the electrolyzing powers, and to generate oxygen bubble discharges for generating oxidants. And moreover the slits eliminate the space charge limiting action and the temperature of the water by leaking out through the slits from electrolyzing region to outside of the main electrode region. As a result, it was found that a strong electorzed water of pH 2.8 and pH 10.5 and oxidants dissolved water of 1 [ppm] in acidic water were obtained with a tap water fed at the electric current of 2 [A], which however were several times higher oxidant and ion concentration quantity compared with the conventional cell.

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The effects of current density and nickel content on copper electrowinning by energy saving system (에너지절약형 동(Cu)전해채취 및 전류밀도의 영향)

  • Lee, Hoo-In;Lee, Jae-Chun;Park, Jin-Tae;Kim, Min-Seuk;Sohn, Jeong-Soo;Koyama, Kazuya
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.386-387
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    • 2006
  • This study is about the recycling technology of scrap a PCB(printed circuit board) produced in home appliances or automobile industry. And we develop the recycling technology of cooper (Cu)which is contained to leaching solution. In stead of electrolytic collecting in existing sulphuric atmosphere, we apply process using the ammonia solution which is used in economizing energy. So m the process of electrolyzing scrap a PCB through the leaching and separation, we examine the effect of the nickel contained to the solution and the cooper degree of purity which is changed according to current density.

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Effective Oxidant Generation and Ion Precipitation Characteristics of Electrolyzing Cell by Discharge and Space Charge Control (수중 방전과 공간전하제어에 의한 효과적인 산화성물질 발생특성)

  • Kim, Jin-Gyu;Lee, Dae-Hee;Moon, Jae-Duk
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.9-12
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    • 2000
  • A new type electrolyzing cell with slits on parallel plate electrodes and wire-to-cylinder type electrode system has been proposed instead of the conventional parallel plate type. An investigation was carried out on the effect of the number and size of slits on ion precipitation and oxidant generation characteristics, evidenced by eliminated space charge limiting action and by elevated electric fields in active interelectrode spacing. And it is also studied on the effect of the diameter of wire electrode to ion precipitation and oxidant generation characteristics. With electrode with 48 slits, very oxidants generation water of 3.1 [ppmm] and 19.0 [ppmm] in positive electrode side were obtained with tap water and 0.1 [wt%] NaCl dissolved tap waterfed. In addition, with wire-to-cylinder type electrode system, it is found that oxidant contained water of 0.48 [ppmm] and 5.46 [ppmm] in positive electrode side were obtained with tap water and 0.1 [wt%] NaCl dissolved tap water fed for the case of discharge electrode diameter of 0.5 [$mm{\phi}$]. Consequently, very high ion precipitation and dense oxidant generation characteristics can be realized by having slits on the electrodes of conventional cell as these slits increase the electric fields and decrease the space charge limiting actions in interelectrode spacing.

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The effect of process parameters on copper powder particle size and shape produced by electrolysis method

  • Boz, Mustafa;Hasheminiasari, Masood
    • Steel and Composite Structures
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    • v.15 no.2
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    • pp.151-162
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    • 2013
  • In this study, an electrolyzing device for the production of metal powders was designed and fabricated. The production of copper powders was performed using a variety of current densities, anode-cathode distances and power removal times. The effect of these parameters on powder particle size and shape was determined. Particle size was measured using a laser diffraction unit while the powder shape was determined by SEM. Experimental results show that an increase in current density leads to a decrease in powder particle size. In addition particle shape changed from globular dendritic to acicular dendritic with increasing the current density. Distance between the cathode and anode also showed a similar influence on powder particle size and shape. An increase in time of powder removal led to an increase in powder particle size, as the shape changed from acicular dendritic to globular dendritic.

Fused Salt Electrolysis of Magnesium Chloride (염화마그네슘의 용융염전해 연구)

  • Lee, Hoo-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.546-547
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    • 2007
  • Magnesium is widely used as a lightweight alloy for car engine components and case of cellular phone. Extraction technologies of magnesium are divided to fused salt electrolysis process and thermal reduction process. In this study, electrolysis magnesium is prepared by fused salt electrolysis process with magnesium chloride. We compared two kinds of mixed salt at 7V. As a result, 47% of current efficiency was obtained by electrolyzing KCl/NaCl/$MgCl_2$ mixed salt bath at $760^{\circ}C$, and purity of the prepared magnesium was over 98%. With this study, we can scale up fused salt electrolysis device and accumulate basic data which will be needed for designing an electrolysis cell.

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Strength Property of Concrete Mixed Blast Furnace Slag Using Electrolysis Alkaline Aqueous as Mixed Water (전기분해 알칼리수를 배합수로 활용한 고로슬래그 혼입 콘크리트의 강도 특성)

  • Jeong, Su-Mi;Kim, Ju-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.135-136
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    • 2023
  • In this study, a concrete was prepared using an alkaline aqueous solution produced by electrolyzing potassium carbonate in order to improve the low initial strength of concrete using blast furnace slag. In order to confirm the increase in initial strength, the compressive strength of specimens was measured on the age of 7, 28 days. As a result, the blast furnace slag concrete using the electrolysis alkaline aqueous solution as the mixed water show high strength more than the blast furnace slag concrete using the general mixed water.

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A study on the power plant system combined with PEM fuel cell and the wasted hydrogen from the sea water electrolyzer of nuclear power plants (원자력 발전소의 해수전해설비 폐수소를 활용한 PEM 연료전지 발전 시스템에 관한 연구)

  • Choi, Jongwon;Lee, Juhyung;Cha, Sukwon;Kim, Minsoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.124.2-124.2
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    • 2010
  • Generally, a coolant of the nuclear power plant is manufactured by electrolyzing the sea water near the plant for making the sodium hypochlorite(NaOCl), which is used for sterilizing the bacteria and the shellfishes sticking to the drains or the pumps at the outlet of the cooling system due to $8-10^{\circ}C$ warmer temperature than the inlet sea water. During manufacturing the sodium hypochlorite, the hydrogen with the high purity is also produced at the anode side of the electrolyzer. This paper describes a novel power plant system combined with the polymer electrolyte membrane(PEM) fuel cell, the wasted hydrogen from the sea water electrolyzer and the wasted heat of the nuclear power plant. The present status over the exhausted hydrogen at twenty nuclear power plants in Korea was investigated in this study, from which an available power generation is estimated. Furthermore, the economic feasibility of the PEM fuel cell power plant is also evaluated by a current regulations over the power production and exchange using a renewable energy shown in Korea Power Exchange(KRX).

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Effect of Electrochemical Treatment on the Chlorine Generation Efficiency of Ballast Water in the Brackish Zone (기수지역 선박평형수의 염소 생성 효율에 미치는 전기화학 처리의 영향)

  • Choi, Yong-Sun;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.16-22
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    • 2019
  • Indirect oxidation using chlorine species oxidizing agents is often effective in wastewater treatment using an electrochemical oxidation process. When chlorine ions are contained in the wastewater, oxidizing agents of various chlorine species are produced during electrolysis. In a ballast water management system, it is also used to treat ballast water by electrolyzing seawater to produce a chlorine species oxidizer. However, ballast water in the brackish zone and some wastewater has a low chlorine ion concentration. Therefore, it is necessary to study the chlorine generation current efficiency at various chlorine concentration conditions. In this study, the chlorine generating current efficiency of a boron-doped diamond(BDD) electrode and insoluble electrodes are compared with various chloride ion concentrations. The results of this study show that the current efficiency of the BDD electrode is better than that of the insoluble electrodes. The chlorine generation current efficiency is better in the order of BDD, MMO(mixed metal oxide), $Ti/RuO_2$, and $Ti/IrO_2$ electrodes. In particular, when the concentration of sodium chloride is 10 g/L or less, the current efficiency of the BDD electrode is excellent.

Deduction of Emergency Stop Situation Factors for Water Electrolysis Facilities (수전해 설비에 대한 비상정지상황 발생 요인 도출)

  • HYEONKI KIM;TAEHUN KIM;KWANGWON RHIE;DOOHYOUN SEO;DONGMIN LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.722-727
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    • 2023
  • There are various types of hydrogen production methods, but among them, the alkaline water electrolysis method produces hydrogen by electrolyzing water, and unlike other methods, it can produce green hydrogen that does not emit pollutants and greenhouse gases. There are many different potential risk factors inherent in the water electrolysis process. So it is necessary to predict an emergency situation in advance and to safely manage and take countermeasures according to the emergency situation. Korea Gas Safety Corporation (KGS) CODE AH271 stipulates legal matters to secure safety, but it is not detalied. Thus it is necessary to take measures to safely control and manage it according to the situation in which an emergency stop is required. In this study, based on KGS CODE and HAZOP for alkaline water electrolysis facilities, factors that can cause emergency situations were derived and countermeasures were prepared.

Investigation on the Technology Trend in Electrolyzed Sterilizing Water by the Patent Analysis (특허분석을 통한 전해살균수의 기술 동향 연구)

  • Kang, Kyung-Seok;Kim, Tae-il;Lee, Ho-il;Han, Hye-jung;Park, Soo-gil;Kim, Han-ju;Han, Sam-Duck;Park, Kunyik;Rhee, Young-Woo
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.188-194
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    • 2010
  • The electrolyzed sterilizing water is useful functional aqueous solution, which is produced by electrolyzing aqueous solution. Electrolytic supplement such as salt or hydrochloric acid is added into tap water. Electrolyzed sterilizing water is classified as three types; strongly acidic electrolyzed water, weakly acidic electrolyzed water, and sodium hypochlorite water. In this study, preparation principles, advantages, and disadvantages of electrolyzed sterilizing water were analyzed. The technology trend in electrolyzed sterilizing water was analyzed based on patent application year, countries, main applicants, and each technologies.