• Title/Summary/Keyword: electrolysis

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Electrical Properties of Carbon film for Application of New Light Source (신광원 카본의 전기적 특성)

  • Lee, Sang-Heon;Choi, Young-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.226-227
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    • 2005
  • The carbon film was deposited by the electrolysis of methanol solution. From investigations of the Raman spectroscopy and the FTIR spectroscopy, the carbon film deposited by the electrolysis was identified the hydrogenated carbon film with the porous structure. The carbon film deposited by electrolysis of methanol was identified as the hydrogenated carbon film with porous structure.

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Electrical Properties of Carbon film for Application of New Light Source (신광원 적용을 위한 카본 박막의 특성)

  • Lee, Sang-Heon;Choi, Young-Sung;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.346-347
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    • 2005
  • The carbon film was deposited by the electrolysis of methanol solution. From investigations of the Raman spectroscopy and the FTIR spectroscopy, the carbon film deposited by the electrolysis was identified the hydrogenated carbon film with the porous structure. The carbon film deposited by electrolysis of methanol was identified as the hydrogenated carbon film with porous structure.

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Investigation of Simple Electrochemical Conditions for Generation of Ozonized Water

  • Tanaka, Mutsumi;Kim, Han-Joo;Kim, Tae-Il;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.135-140
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    • 2008
  • An electrochemical generation of ozonized water was investigated by using ${\beta}-PbO_2$ as an anode and tap water as an anolyte. According to the potentiometric ozone detection which utilizes potential differences arisen from a chemical reaction of ozone and iodide, increasing tendency of ozone concentration on electrolysis time could be observed to show the maximum value of 8 ppm at an electrolysis time of 10 min. Ozone could be generated promptly even at an electrolysis time of 10 sec., suggesting great advantages of this electrochemical process in terms of simplicity and readiness that might be applied directly to practical uses including medical and/ or food industries. Influences of electrolysis on the properties and surface conditions of a $PbO_2$ electrode were also discussed from the results of cyclic voltammetry, scanning electron microscope, and X-ray diffractometer.

The effect electrolysis conditiong on the composition and the preferred orientation of Co-Fe-Cr alloy electrodeposits (Co-Fe-Cr 합금도금층의 조성 및 우선방위에 미치는 전해조건의 영향)

  • 예길촌;문근호
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.393-399
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    • 1998
  • The composition and the properred orientation of Co-Fe-Cr alloy electrodeposits were invesigated according to the electrolysis conditions using sulface bath. The current efficiency and the cathode overpotential decrased noticeably with the increase of Cr content in the bath. As the D.C. current density increased increased, the Cr content in the alloy increasd, while Co content decreased and Fe content remained constant, In the pulse current electrolysis, the Cr content of the alloy increased with the mean current density and off-time and then its content increased mord more noticeably with the peak current density than that of D.C. electrolysis. The preferred orientation of the alloy changed from (220)+(111) to (220) with decreasing cathode overpotential.

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A Study on the Characteristics of Compounding Electrolytic Machining in micro-cutting (전해복합에 의한 미세절삭가공 특성연구)

  • Son, M.K.;Son, S.M.;Ahn, J.H.
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.502-506
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    • 2001
  • This paper presents a new method for cutting steel with a diamond tool using electrolysis. The electrolysis is adopted in the diamond cutting to prevent the high chemical activity between a diamond tool and an iron-based workpiece. The basic principle of the method is to oxdize a thin substrate of the workpiece by electrolysis ahead of the diamond tool which cuts the oxidized layer. A desired shape can be obtained by repeating this process. The cutting force is reduced because the diamond tool removes only the weakened material by electroysis. The reduction of the cutting force suppresses the excessive wear of the diamond tool. The oxidization penetrates several micrometers in depth along the previously formed shape. The corrosion rates depend on current density and make suggestions on the optimum cutting conditions.

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A Novel Application of Advanced Treatment in Livestock Wastewater by Electrolysis (전기분해공법을 이용한 축산폐수의 고도처리에 관한 연구)

  • Chung Soon-Hyung
    • Journal of environmental and Sanitary engineering
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    • v.19 no.3 s.53
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    • pp.31-39
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    • 2004
  • In order to reduce the pollution load from the livestock farms and to improve the water quality of the effluent in livestock wastewater, the electrolysis system is introduced. For the selection of optimal electrode, various combination of electrodes such as carbon, Al and Fe were examined. In this study, electrode material, electrolyte concentration, electrode distance, current density, and pH value were found to have significant effect on both pollutant removal efficiency and current efficiency in electrochemical oxidation process. After electrolysis for 90 min with carbon/Al, it was observed that COD, T-N, T-P and $NH_4^+-N$ of livestock waste-water were removed with $80\%,\;61\%,\;81\%\;and\;87\%$, respectively.

Model development for chlorine generation using electrolysis (전기분해에 의한 잔류염소 생성 예측 모델 개발)

  • Sohn, Jinsik;Lee, Sunjae;Shin, Chorong
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.3
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    • pp.331-337
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    • 2009
  • Electrolysis produces hypochlorous acid by using a small quantity of NaCl as electrolyte. This process maximizes the stabilization of drinking water through the control of chlorine residual concentration. This study investigated free chlorine generation by an electrolytic method using $Ti/IrO_2$ and stainless steel. The generation of free chlorine was increased with increasing hydraulic retention time, voltage, chlorine ion concentration and the number of electrodes. However, the change of pH did not affect the generation of free chlorine. There was no significant difference on the behavior of chlorine concentration between electrolytic method and NaOCl injection. In this study, the concentration of free chlorine predicted model based on power functional model was developed various under conditions. Electrolysis free chlorine generation model can be effective tool in the estimation of free chlorine generation.

Inactivation of Seawater Zooplankton Aretemia sp. using Physical and Chemical Processes (물리·화학적 공정을 이용한 해수 동물성 플랑크톤 Aretemia sp.의 소독)

  • Zheng, Cheng;Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.24 no.9
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    • pp.1181-1188
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    • 2015
  • In this study, we discussed about the application of the single physical and chemical treatment processes and the physical-chemical complex treatment processes on the inactivation of Artemia sp. in order to satisfy the USCG Phase II (United States Coast Guard). The results showed that initial disinfection rate of ultrasonic process in single batch process is higher than that of electrolysis. However, the inactivation rate showed slower than electrolysis. The inactivation rate of Artemia sp. on the single continuous treatment process ranked in the following order: homogenizer > electrolysis > ultrasonic process. Inactivation rate of Artemia sp. in continuous homogenizer-electrolysis complex process was reached at 100% immediately. A synergistic effect of ultrasonic-electrolytic complex process was found to be a small. The order of processes in a complex process did not affect the disinfection performance.

A Study on the Design of Electrolysis Power Using Inverter (인버터를 이용한 전기분해전원 설계에 과한 연구)

  • 이정민;목형수;최규하;최동규
    • Proceedings of the KIPE Conference
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    • 1998.11a
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    • pp.55-59
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    • 1998
  • By this time, Diode Rectifier or SCR has been used to gain DC Voltage for Electrolysis Power. Generally DC Voltage is produced from rectifier shall be transformed before rectifier using step-down transformer to obtain adaptable DC Voltage, rectifier output. In the same way, rectifier using SCR shall obtain output voltage after step-down voltage through transformer and control of the SCR firing angle. Transformer shall be used for this two methods to adjust the voltage. But the size and weight of the transformer are increased in accordance with the increase of capacity, and the hardships are accompanied in workspace or transportation. Besides, only the value of input voltage is possible to be regulated, and the expectation of current control is almost impossible during Electrolysis. This study has conducted Design and Simulation to reduce the size and weight of transformer and to be enable voltage and current control of Electrolysis power through high-speed switching using Inverter, Electronics device.

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Performance change according to the catalyst intrusion rate in the MEA for the PEM water electrolysis (고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화)

  • Kim, Hong-Youl
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.254-256
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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