• Title/Summary/Keyword: electrode polarization

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Analysis on Permittivity of Soil to Evaluate Pore Water Contamination

  • Oh Myoung-Hak;Kim Yong-Sung;Yoo Dong-Ju;Park Jun-Boum
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.249-252
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    • 2005
  • 저주파수에서 유전상수 측정시 100kHz 이하의 주파수 영역에서는 전극분극효과가 발생하므로 100kHz이상의 주파수에서 유전상수가 평가되어야 한다. 유전상수는 쌍극자모멘트의 수에 비례하기 때문에 흙의 유전상수는 체적함수비에 따른 선형적인 증가경향을 나타내었다. 용액에 이온성분이 존재하는 경우에는 수화작용에 의한 물분자의 배향분극 발현의 감소로 인하여 유전상수가 감소한다. 흙과 중금속 혼합시료의 경우 함수비가 큰 시료에서는 용액의 유전특성이 발현되지만, 함수비가 작은 경우에는 공간전하분극의 영향으로 유전상수가 10-20%정도 증가하는 경향을 나타내었다. 현장에서의 정확한 오염도 평가를 위해서는 토양의 함수비에 대한 평가가 반드시 수행되어야 한다.

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Theoretical and Practical Aspects of Pb-Sn Alloy Plating (Pb-Sn 합금도금의 이론 및 실제적 경향)

  • Paik, Young-Nam
    • Journal of Surface Science and Engineering
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    • v.12 no.3
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    • pp.161-166
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    • 1979
  • Theoretical and practical aspects are investigated for electrochemical behavious, plating processes and the structures of electrodeposit of Pb-Sn binary alloy plating through numerous literatures in this report. The anodic and cathodic electrode reaction mechanisms of Pb and Sn could co-deposit and make Pb-Sn alloy deposit from the results of cathode current density-cathode potential curves of Pb, Sn and Pb-Sn alloys in fluoborate solutions. The compositions of the best alloy plating solutions are obtained for the purpose of bearing, anticorrosion and solder plating. In general, the casting anodes of Pb-Sn alloys are used, but separated anodes of Pb and Sn pure metal are used in order to obtain the fine compositions of Pb-Sn alloy deposits. The electrodeposits of Pb-Sn alloy are in nonequilibrium state and saturated solid solutions. Thus, ${\beta}$-phase (Sn-phase) is precipitated by heat treatment. The texture and structure of the electrodeposit are associated with the surface energies of deposit lattice planes and with the cathode polarization. The electrodeposit of Pb-Sn alloy is shown as lamellar structure.

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Fomation and Properties of Multiple-Tone Spatial Light Modulator using Garnet Film with In-Plane Magnetization

  • Tsuzuki, A.;Uchida, H.;Takagi, H.;Lim, P.B.;Inoue, M.
    • Journal of Magnetics
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    • v.11 no.3
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    • pp.143-146
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    • 2006
  • We attempted to fabricate a new type of magneto optic spatial light modulator (MO-SLM) for multiple-tone modulation by using in-plane magnetization. In the MO-SLM, magnetic property of magneto-optical layer was modified to be suitable for multiple-tone expression by substituting Al in Bi:YIG film. At a driving current to 28 mA in an electrode of the fabricated MO-SLM, changes in brightness of pixels were observed using a polarization microscope.

Growth and characterization of Eu-doped bismuth titanate (BET) thin films deposited by sol-gel method

  • Kang Dong-Kyun;Kim Byong-Ho
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.05a
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    • pp.194-197
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    • 2006
  • Lead-free bismuth-layered perovskite ferroelectric europium-substituted $Bi_{4}Ti_{3}O_{12}(BTO)$ thin films have been successfully deposited on Pt/Ti/$SiO_2$/Si substrate by a sol-gel spin-coating process. $Bi(TMHD)_3,\;Eu(THMD)_3,\;Ti(OiPr)_4$ were used as the precursors, which were dissolved in 2-methoxyethanol. The thin films were annealed at various temperatures from $600^{\circ}\;to\;720^{\circ}C$ in oxygen ambient for 1 hr, which was followed by post-annealed for 1 hr after depositing a Pt electrode to enhance the electrical properties. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to analyze the crystallinity and surface morphology of layered perovskite phase, respectively. The remanent polarization value of the BET thin films annealed at $720^{\circ}C\;was\;25.95{\mu}C/cm^2$ at an applied voltage of 5 V.

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The Study of Solderability according to Chemical Analysis in Plating Process (도금공정의 액 분석에 따른 Solderability 개선 연구)

  • 이준호
    • Journal of Surface Science and Engineering
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    • v.36 no.2
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    • pp.168-175
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    • 2003
  • The purpose of solder plating on chip external electrode is to provide a proper solderability to chips on PCB's. The quantitative or qualitative analysis of solderability has been performed by destructive methods, reflow or flow. Evidently, the solderability tends to depend on the grain structure which is varied with additives. Research on the feasibility of employing electrochemical techniques to characterize the solderability of electroplated tin - lead, with respect to the additives, was non destructively performed. The deposit morphology and the polarization behavior of electrolytes containing proprietary additives were evaluated to investigate the soldering degradation. The plated panels from synthetic electrolyte were analyzed according to % Sn, plating thickness, deposit appearance, grain structure, solderability and cyclic voltammetry.

Optimum Location of Electrode of Cathodic Protection System by using Boundary Element Method (BEM을 이용한 Cathode 방식 시스템에서 전극 위치 최적화)

  • Lee, Kwang-Ho;Chung, Koon-Seok;Baik, Dong-Chul;Cho, Yun-Hyun
    • Proceedings of the KIEE Conference
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    • 2000.07b
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    • pp.772-774
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    • 2000
  • The objective of a cathodic protection system (CP) is to protect the buried metallic structure against the corrosion caused by chemical reaction between the buried structure and the surrounding medium, such as soil. This paper presents a boundary element application to determine the optimal impressed current densities in a cathodic protection system. The potential within the electrolyte is described by the Laplace's equation with nonlinear boundary conditions which are enforced based on experimentally determined electrochemical polarization curves. The optimal impressed current densities are determined in order to minimize the power supply for protection. The solution is obtained by using the conjugate gradient method in which the governing equations and the protecting conditions are taken into account by the penalty function method. Numerical example are presented to demonstrate the practical applicability of the proposed method.

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Fuel Cell Performance by the Impedance Method (임피던스법을 적용한 연료전지 성능규명)

  • 김귀열;서장수;박용필;이준응
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.157-159
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    • 2001
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(47vo1%) was bettor excellent than the others.

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Fuel Cell Performance by the Impedance Method (임피던스법을 이용한 연료전지의 특성 연구)

  • 서장수;김귀열;명기환;이성일;김용주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.927-933
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    • 2000
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO3 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way , Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a results, the performance of Ni-YSZ anode(40vo1%) was better excellent than the others.

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A Study on the Corrosion Properties of Underwater Wet Arc Welds using the SM 41 (선체용 압연 강판의 습식 수중 아크 용접부의 부식특성에 관한 연구)

  • Kwak, H.H.;Kim, C.G.;Kim, M.N.;Hwang, S.H.
    • Journal of Power System Engineering
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    • v.10 no.4
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    • pp.111-118
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    • 2006
  • Underwater wet arc welds were experimentally performed on 11mm thick KR-RA steel plate using six different types of flux coated electrodes of 4.0mm diameter, KSKR, KSKT, USBL, JPUW, UWEA and UWEB. From analysis of bead appearance, detachability of weld slag, spatter occurrence and arc stability, JPUW gives the best result, and UWEB is superior to KSKR and KSKT. By experimental result of hardness distribution on the weld bonds, UWEB weld has the narrowest bond structure which is probable condition to get the best mechanical properties of weld. UWEB and JPUW welds have more even hardness distribution across weld deposit and base metal. Upon polarization test to measure the respondency of corrosion, the electrode of UWEB shows the most excellent degree due to the low open circuit potential difference.

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Opto-electrokinetic Technique for Microfluidic Manipulation of Microorganism (광-전기역학 기술을 이용한 미생물의 미세유체역학적 제어)

  • Kwon, Jae-Sung
    • Journal of the Korean Society of Visualization
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    • v.17 no.1
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    • pp.69-77
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    • 2019
  • This paper introduces microfluidic manipulation of microorganism by opto-electrokinetic technique, named rapid electrokinetic patterning (REP). REP is a hybrid method that utilizes the simultaneous application of a uniform electric field and a focused laser to manipulate various kinds and types of colloidal particles. Using the technique in preliminary experiments, we have successfully aggregated, translated, and trapped not only spherical polystyrene, latex, and magnetic particles but also ellipsoidal glass particles. Extending the manipulation target to cells, we attempted to manipulate saccharomyces cerevisiae (S. cerevisiae), the most commonly used microorganism for food fermentation and biomass production. As a result, S. cerevisiae were assembled and dynamically trapped by REP at arbitrary location on an electrode surface. It firmly establishes the usefulness of REP technique for development of a high-performance on-chip bioassay system.