• Journal of Electrochemical Science and Technology
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• 제8권4호
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• pp.274-281
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• 2017

This paper describes the simple fabrication of an electrode modified with electrochemically reduced graphene oxide (ERGO) for the simultaneous electrocatalytic detection of dopamine (DA), ascorbic acid (AA), and uric acid (UA). ERGO was formed on a glassy carbon (GC) electrode by the reduction of graphene oxide (GO) using linear sweep voltammetry. The ERGO/GC electrode was formed by subjecting a GO solution ($1mg\;mL^{-1}$ in 0.25 M NaCl) to a linear scan from 0 V to -1.4 V at a scan rate of $20mVs^{-1}$. The ERGO/GC electrode was characterized by Raman spectroscopy, Fourier transform infrared spectroscopy, contact angle measurements, electrochemical impedance spectroscopy, and cyclic voltammetry. The electrochemical performance of the ERGO/GC electrode with respect to the detection of DA, AA, and UA in 0.1 M PBS (pH 7.4) was investigated by differential pulse voltammetry (DPV) and amperometry. The ERGO/GC electrode exhibited three well-separated voltammetric peaks and increased oxidation currents during the DPV measurements, thus allowing for the simultaneous and individual detection of DA, AA, and UA. The detection limits for DA, AA, and UA were found to be 0.46, 77, and $0.31{\mu}M$ respectively, using the amperometric i-t curve technique, with the S/N ratio being 3.

• 한국세라믹학회지
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• 제37권3호
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• pp.263-270
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• 2000

The Pt/copper oxide/n-Si electrodes were fabricated by depositing copper oxide thin film of 500${\AA}$ and very thin Pt layer on the n-type (100) Si substrate. hotoelectrochemical properties and stability profiles of the electrodes were investigated as a function of deposition time of Pt layer. As the deposition time of Pt layer increased up to 10 seconds, the photocurrent and quantum efficiency were increased and then decreased with further depositing time. The better cell stability was observed for the electrode with longer deposition time. The improvements in above photoelectrochemical properties indicate that Pt layer acts as a catalyst layer at electrode/electrolyte interface as well as a protective layer. The decreasing tendency of the photocurrent and efficiency for the electrode with Pt layer deposited above 20 seconds was explained as an increases in probbility of electron-hole pair recombination and also the absorbing photon loss at electrode surface due to the excessive thickness of Pt layer. The results were confirmed by impedance spectroscopy, mutiple cycle voltammograms and microstructural analyses.

• Bulletin of the Korean Chemical Society
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• 제28권10호
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• pp.1729-1734
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• 2007

The electrochemical behaviors of estrone in the presence of various surfactants were examined with great details. It is found that a cationic surfactant, cetyltrimethylammonium bromide (CTAB), obviously facilitates the electro-oxidation of estrone at carbon paste electrode (CPE) from the significant peak current enhancement and the negative shift of peak potential. Additionally, chronocoulometry and electrochemical impedance spectroscopy (EIS) were also used for further investigation of the electrode process of estrone, indicating that low concentration of CTAB exhibits excellent enhancement effects on the electrochemical oxidation of estrone, greatly enhances the diffusion coefficient and the electron transfer rate. Based on this, an electrochemical method was proposed for the determination of estrone. The oxidation peak current is proportional to the concentration of estrone in the ranges over 9.0 × 10?8 - 8.0 × 10?6 mol/L, and a low detection limit of 4.0 × 10?8 mol/L was obtained for 180s accumulation at open circuit (S/N = 3). Finally, this proposed method was demonstrated using estrone tablets with good satisfaction.

• 전자공학회논문지A
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• 제29A권8호
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• pp.41-48
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• 1992

The characteristics of traveling-wave electrodes for high-frequency electroptic integrated devices are described from the view point of improvement of phase-matching based on the conformal mapping method. Specific calculations of the characteristic impedance, effective microwave index, and eletrode loss for asymmetric coplanar strip(ACPS) and coplanar waveguide(CPW) electrode structures are presented as a function of the geometric electrode parameters including the electrode thickness and buffer layer thickness. 5-10(x10S0-6Tm) thick Au-ACPS electrodes were successfully fabricated by electroplating and ECR etcher. The improvement of modulation bandwidth can be theoretically observed from the combination of electrode and buffer layer thickness.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2002년도 추계학술대회
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• pp.273-277
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• 2002

In the electrode fabrication of unit cell, we found that optimal the electrochemical characteristics were obtained with at 90 wt.% of activated carbon(BP-20), 5 wt.% of conducting agent(Ppy, Super P) and 5 wt.% of P(VdF-co-HFP)/PVP mixed binder. The electrochemical characteristics of unit cell with Ppy improver were as follows : 37.6 F/g of specific capacitance, 0.98 $\Omega$ of AC-ESR, 2.92 Wh/kg and 6.05 Wh/L of energy density, and 754 W/kg and 1,562 W/L of power density. It was confirmed that internal resistance were reduced due to the increase of electrical conductivity and filling density by the introduction of conductivity agent, and content of conducting agent was suitable in the range of 4~6 wt.%. According to the impedance measurement of the electrode with conductivity agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance(AC-ESR), fast charge transfer rate at interface between electrode and electrolyte, and low RC time constant.

• Bulletin of the Korean Chemical Society
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• 제32권1호
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• pp.105-108
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• 2011

The cycling behavior of $Li_4Ti_5O_{12}$ electrode in the ionic liquid (IL)-based electrolytes containing 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and a small amount of additive (vinylene carbonate, ethylene carbonate, fluoroethylene carbonate) was investigated. The $Li_4Ti_5O_{12}$ electrode in the IL electrolyte with an additive exhibited reversible cycling behavior with good capacity retention. Electrochemical impedance spectroscopy and FTIR studies revealed that an electrochemically stable solid electrolyte interphase was formed on the $Li_4Ti_5O_{12}$ electrode in the presence of vinylene carbonate and ethylene carbonate during cycling.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.358-359
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• 2006

Ru-C nano-composite films were prepared by MOCVD, and their microstructures and their electrode properties for oxygen gas sensors were investigated. Deposited films contained Ru particles of 5-20 nm in diameter dispersed in amorphous C matrix. The AC conductivities associating to the interface charge transfer between Ru-C composite electrode and YSZ electrolyte were 100-1000 times higher than that of conventional paste-Pt electrodes. The emf values of the oxygen gas concentration cell constructed from the nano-composite electrodes and YSZ electrolyte showed the Nernstian theoretical values at low temperatures around 500 K. The response time of the concentration cell was 900 s at 500 K.

• 멤브레인
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• 제9권4호
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• pp.230-239
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• 1999

운반체(감응물질)로 제 4급 인산염을 사용하여 PVC를 지지체로 하여 과염소산이온의 농도 $10^{-6}$ M까지 선형적인 이온선택성 전극을 제작하였다. 운반체의 화학적구조와 함량 가소제의 종류 및 막 두께에 따른 전극의 기울기 선형응답범위 및 한계측정농도 등 전극전위특성을 고려하여 최적의 과염소산 이온선택성 PVC막 전극을 제조한 다음 측정 가능한 pH 범위 선택계수 및 전극의 교류임피던스 특성을 비교 검토하였다 운반체로 tetraoctyl-phosphonium perchlorate(TOPP) tetraphenylphosphonium perchlorate(TPPP) 및 tetrabutylphosponium perchlorate (TBPP)_ 등의 제 4급 인산염의 과염소산 이온 치환체를 사용하였다 알킬기의 탄소고리 수가 증가할수록 전극특성은 TBPP$^P{ClO}_4$, 선형응답범위 $10^{-1}$\times$10^{-6}$ M 및 한계측정농도는 9.66$\times$$10^{-7}$ M 이었으며 시판되고 있는 Orion 전극특성보다 좋은 결과를 나타내었다 전극전위는 pH3~11범위에서 ph의 영향을 받지 않았으며 ${CIO}_4$ 에 대한 방해이온의 선택계수 서열은 ${SO}^2_4$ < F < Br < I 이었다 임피던스 측정결과 TOPP의 경우 등가회로는 용액저항 이중층용량과 벌크저항의 병렬 및 Warburg 임피던스의 직렬이었다 이 경우 용액저항은 거의 나타나지 않았고 확산에 의한 Warburg 임피던스는 크게 나타났으며 Warburg 계수는 1.32$\times$$10^74 $\Omega$ $\cdot$ ${cm}^2/s^{1/2}$이었다.

• 한국융합학회논문지
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• 제8권2호
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• pp.121-126
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• 2017

본 연구에서는 피부 등가모델을 통한 세포 내액과 세포 외액 성분의 생체임피던스 특성을 파악하기 위해 개발한 휴대용 소형 임피던스 측정시스템을 이용하여 4 전극법에 의한 비 침습 방식으로 다양한 주파수 대역에서 전신의 생체전기 임피던스를 측정실험을 수행하였다. 측정은 10명의 남성 피 실험자(평균 나이 $24{\pm}3.0$세, (BMI) $20.3kg/m^2$)를 대상으로 4주간 실시하였으며, 생체임피던스 다중주파수(1 kHz, 5 kHz, 50 kHz, 70 kHz, 100 kHz, 500 kHz)대역에서 측정하였다. 실험결과, 저주파 대역인 1 kHz 대역에서 임피던스가 가장 높게 측정되었고, 고주파 대역인 500 MHz에서 임피던스가 가장 낮게 측정되었다. 특히 50 kHz 대역이상에서 임피던스가 급속히 낮아짐을 실험을 통해서 확인하였다. 또한, 피부 등가회로모델을 통한 세포 내액과 세포 외액의 임피던스 특성을 파악하는 모의실험에서도 본 연구의 생체임피던스 측정시스템의 측정값과 유사한 특성이 얻어짐을 확인할 수 있었다.

• 전자공학회논문지
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• 제51권12호
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• pp.197-203
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• 2014

뇌격전류가 정보통신설비의 접지시스템에 유입되었을 때 발생하는 과도전위상승에 대한 해석은 접지시스템을 효과적으로 설계하기 위해서 요구되는 사항 중에 하나이다. 접지시스템의 성능은 보통 접지시스템의 전기적 특성을 나타내는 접지임피던스와 과도전위상승으로 평가된다. 뇌격전류의 입사점에 따른 접지임피던스를 계산하는 방법을 제안하였다. 뇌격전류가 수평접지전극의 중앙에 입사되는 경우 델타갭소스 모델을 이용하여 접지임피던스를 계산하였다. 디바이 모델(Debye Model)을 이용하여 주파수의존적인 토양 파라미터를 적용할 수 있는 프로그램을 제안하였다. 그 이유는 접지시스템의 성능을 분석하는 상용프로그램은 주파수 의존적인 토양 파라미터 특성을 적용할 수 없기 때문이다. 동일한 조건에서의 시뮬레이션 결과의 신뢰성을 확인하기 위해서 실험을 수행하였다. 마지막으로, 토양 파라미터의 주파수의존성을 반영한 접지임피던스를 이용하여 뇌격전류파형에 따른 수평접지전극의 과도전위상승을 분석하였다.