• 제목/요약/키워드: electrode impedance

검색결과 687건 처리시간 0.022초

고체산화물 연료전지의 공기극으로서 La1-xSrxMnO3 계의 합성 및 특성 (Synthesis and Properties of La1-xSrxMnO3 System as Air Electrode for Solid Oxide Fuel Cell)

  • 이유기;이영기
    • 한국재료학회지
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    • 제22권9호
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    • pp.470-475
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    • 2012
  • $La_{1-x}Sr_xMnO_3$(LSM,$0{\leq}x{\leq}0.5$) powders as the air electrode for solid oxide fuel cell were synthesized by a glycine-nitrate combustion process. The powders were then examined by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The as-formed powders were composed of very fine ash particles linked together in chains. X-ray maps of the LSM powders milled for 1.5 h showed that the metallic elements are homogeneously distributed inside each grain and in the different grains. The powder XRD patterns of the LSM with x < 0.3 showed a rhombohedral phase; the phase changes to the cubic phase at higher compositions($x{\geq}0.3$) calcined in air at $1200^{\circ}C$ for 4 h. Also, the SEM micrographs showed that the average grain size decreases as Sr content increases. Composite air electrodes made of 50/50 vol% of the resulting LSM powders and yttria stabilized zirconia(YSZ) powders were prepared by colloidal deposition technique. The electrodes were studied by ac impedance spectroscopy in order to improve the performance of a solid oxide fuel cell(SOFC). Reproducible impedance spectra were confirmed using the improved cell, which consisted of LSM-YSZ/YSZ. The composite electrode of LSM and YSZ was found to yield a lower cathodic resistivity than that of the non-composite one. Also, the addition of YSZ to the $La_{1-x}Sr_xMnO_3$ ($0.1{\leq}x{\leq}0.2$) electrode led to a pronounced, large decrease in the cathodic resistivity of the LSM-YSZ composite electrodes.

백금/니켈 전기 도금 상대전극을 사용한 염료 감응형 태양전지 광전 변환 효율 특성 (Photovoltaic Efficiency Characteristics of DSSC with Electroplated Pt/Ni Counter Electrode)

  • 황기섭;도석주;하기룡
    • 공업화학
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    • 제22권1호
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    • pp.98-103
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    • 2011
  • DSSC의 광전 효율 증대와 Pt 상대전극의 접착성 향상을 위하여 FTO (Fluorine-doped Tin Oxide) 유리면에 Ni underlayer를 전기 도금 후 Pt 층을 전기 도금하였다. Ni underlayer는 $10mA/cm^2$에서 2 min 동안 도금한 경우 Ni 층과 FTO 면사이의 접착성이 가장 우수하게 나타났으며, Ni underlayer를 $10mA/cm^2$에서 2 min, Pt 층을 $5mA/cm^2$에서 1 min 동안 전기 도금한 상대전극의 XRD 분석 결과 Ni 및 Pt의 금속 회절 peak들을 관찰 할 수 있었다. 이렇게 제조한 상대전극을 사용하여 DSSC의 impedance 측정 결과 75 ohm의 가장 낮은 저항을 나타냈으며, 광전 효율은 5.6%로서 가장 높은 값을 나타내었다.

생체 신호 측정을 위한 섬유전극의 형태에 따른 전기적 특성 분석 및 비교 (Analysis and comparison of textile electrode's electrical characteristics in several shapes for biopotential signals)

  • 이영재;이강휘;이정환;강다혜;조하경;조현승;이주현
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 학술대회 논문집 정보 및 제어부문
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    • pp.371-372
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    • 2008
  • Many kinds of electrodes have been developed in various forms and shapes for measurement of bio potential signal. Textile electrode has benefit of collect long tenn data monitoring because of it is non-consciousness, convenient and do not occur skin irritation. However, It is very difficult to acquire available data due to high impedance of electrode and unstable skin-electrode contact which generate motion artifact. Also snap button which usually used as mediator between textile and measurement device cause change of electrical characteristics. In this paper, we inflated textile electrode to stabilize contact and add conductive silver paste between textile and snap button to improve conductance. To compare the performance of two methods, flat or inflated and add conductive paste or not, four types of electrodes are tested on each impedance and SNR by ECG measurement. In result, the first type electrode which flat and non-conductive paste showed the worst performance and the last type electrode which is inflated shape and contain conductive paste show the best performance.

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간접접촉 심전도 측정용 전극의 주파수 특성 (Frequency Response of the electrode for Indirect-contact ECG)

  • 임용규
    • 대한의용생체공학회:의공학회지
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    • 제29권3호
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    • pp.249-253
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    • 2008
  • The indirect-contact ECG (IDC-ECG) was introduced by a prior study for daily non-intrusive measurements. To improve the signal quality and to extend the application area of IDC-ECG, close study of the frequency characteristics of the IDC-ECG is necessary. In this study, the frequency response of the active electrode for several sample clothes was measured under conditions of actual IDC-ECG measurement with human body. Higher gain in low frequency range than expected by prior study was observed. In addition to it, wide variation in gain according to the cloth type in the low frequency range was observed. Variation in gain caused by moisture variation in the clothes was also observed. This study shows that the parallel R-C connection is proper for electrode model and the resistive factor is influenced by moisture in the clothes. This study is the first that provides the frequency response of the electrode in the actual indirect-contact ECG measurement and it is expected that the results will be helpful to improve the indirect-contact ECG method.

임피던스 측정을 이용한 세포의 변형성 분석용 미소유체 칩 (Microfluidic chip for characterization of mechanical property of cell by using impedance measurement)

  • 김동일;최은표;최성식;박정열;이상호;윤광석
    • 센서학회지
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    • 제18권1호
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    • pp.42-47
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    • 2009
  • In this paper we propose a microfluidic chip that measures the mechanical stiffness of cell membrane using impedance measurement. The microfluidic chip is composed of PDMS channel and a glass substrate with electrode. The proposed device uses patch-clamp technique to capture and deform a target cell and measures impedance of deformed cells. We demonstrated that the impedance increased after the membrane stretched and blocked the channel.

접지전류의 주파수에 따른 수직 접지전극 주변에서 전위간섭 영향 분석 (An Analysis of Potential Interference Effects in the Vicinity of Ground Rod Depending on Frequency of Ground Currents)

  • 이복희;조용승;최종혁;양순만
    • 조명전기설비학회논문지
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    • 제25권12호
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    • pp.88-93
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    • 2011
  • When the ground current is injected into the adjacent ground electrode, the potential interference is caused between ground electrodes, the ground potential interferences have been largely studied with power frequency fault currents. Many attempts to find the frequency-dependent grounding impedance report that the high frequency grounding impedance is very different with the ground resistance. This paper presents experimental data on the frequency-dependent potential interference effects in the vicinity of ground rod. The ground potential rises around the test ground rod of 4 or 6[m] were measured and discussed. As a result, the ground potential rises and potential interference factor are decreased with decreasing the grounding impedance. It was found that the lowering of grounding impedance is critical to reduce the ground potential interference effects.

전위강하법에 의한 접지임피던스 측정 시 오차요인 분석 (Analysis of error factors of the Fall-of-potential test method in measurements of grounding impedance)

  • 전병욱;이수봉;정동철;이복희;안창환
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2008년도 춘계학술대회 논문집
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    • pp.313-316
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    • 2008
  • This paper presents the error factors of Fall-of-potential test method used in measurements of the grounding-system impedance. This test methods inherently can introduce two possible errors in the measurements of grounding-system impedance: (1) ground mutual resistance due to current flow through ground from the ground electrode to the current probe, (2) ac mutual coupling between the current test lead and the potential test lead. The errors of ground mutual resistances and ac mutual coupling are expressed by the equation in calculating grounding impedance. These equations were calculated by Matlab that is commercial tool using mathematical calculation. The results of calculation were applied to correct grounding impedance.

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Platinum and carbon nano tube addition in carbon black counter electrode for dye-sensitized solar cells

  • Lee, Su Young;Kim, Sang Ho
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.229-230
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    • 2012
  • Platinum (Pt) has been commonly used as a counter electrode material in dye-sensitized solar cells, because it has high catalytic activity and electric conductivity as well as chemical inertness with iodide electrolyte. However, Pt is too expensive to be commercialized. Therefore, in the present study, carbon black counter electrode with Pt and carbon nano tube (CNT) was investigated. The power conversion efficiency with Pt added carbon black electrode was lower than hat of pure Pt electrode which was 6.47 %. By adding 3 wt% Pt to the carbon black counter electrode, the power conversion efficiency was maximized at 5.88 %. On them, additional adding of 1 wt % CNT, the power conversion efficiency (${\eta}$)wasincreasedupto6.21%. The reason of power conversion efficiency improvement with a proper amount of Pt and CNT was examined by comparing the impedance properties measured using EIS.

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Y2O3가 도핑된 SrZrO3-금속전극계의 전기전도 특성 (Electrical Conduction in Y2O3-doped SrZrO3-metal Electrode System)

  • 백현덕;이풍헌
    • 한국세라믹학회지
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    • 제39권4호
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    • pp.367-376
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    • 2002
  • $SrZr_{1-x}Y_xO_{3-\delta}$(x=0.05, 0.10)-금속전극 계에서 임피던스법과 d.c.법으로 전기전도도를 측정함으로써 고체전해질 및 전극전도도를 고찰하였다. 고체전해질과 anode를 통한 전기전도도는 $P_W^{1/2}$(PW는 수증기분압)에 의존하여 증가함을 보였다. Cathode 전도도는 $P_{O2}^{1/4}$에 비례함을 보였으며, 수증기분압 증가와 함께 감소하여 고체전해질내의 전자 결함의 농도와 함께 증가하는 것을 알 수 있었다. 수소분위기에서는 수증기의 첨가가 anode와 cathode 두 방향의 전극반응 속도 모두를 촉진하였다. 도펀트 첨가량이 5%에서 10%로 증가될 때 anode와 고체전해질의 전기전도도가 3배 이상 크게 증가하여 유효 산소이온공공의 농도가 급격히 증가함을 알 수 있었다. Pt와 Ag전극을 통한 cathode 전도도의 활성화에너지가 거의 같은 값을 나타냈으며 이는 cathode반응의 속도가 금속전극이 아니라 고체전해질표면에서 일어나는 반응에 의하여 결정되는 것으로 해석되었다.