• Title/Summary/Keyword: electrode impedance

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Grounding Characteristics Analysis of the Stainless-steel Plate Grounding Electrode for Distribution Poles (배전전주용 스테인리스강판 접지전극의 접지 특성분석)

  • Kim, Kyung-Chul;Lee, Kyu-Jin;Kim, Min-Sung;Jung, Ji-Won
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.8
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    • pp.94-100
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    • 2010
  • Grounding system insures a reference potential point for electric devices and also provides a low impedance path for fault currents or transient currents in the earth. The ground impedance as function of frequency is necessary for determining its performance since fault currents could contain a wide range of frequencies. In this paper, the grounding resistance, grounding impedance and transient grounding impedance are measured by using 3-point fall-of-potential method in order to analyse grounding characteristics of the stainless-steel plate grounding electrode. An equivalent transfer function model of the grounding impedance and transient grounding impedance are identified from the measured values by using ARMA method and evaluated by comparing conventional grounding impedances.

Electrochemical Oxidation of Ethanol at Nickel Hydroxide Electrodes in Alkaline Media Studied by Electrochemical Impedance Spectroscopy

  • Kim, Jae-Woo;Park, Su-Moon
    • Journal of the Korean Electrochemical Society
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    • v.8 no.3
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    • pp.117-124
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    • 2005
  • Electrochemical oxidation of ethanol at nickel electrodes has been studied in 1 M KOH solution containing 0.20M ethanol using electrochemical impedance spectroscopy. Equivalent circuits have been worked out by simulating the impedance data, and the results were used to model the oxidation of ethanol as well as the passivation of the electrode. The maximum rate of oxidation of $Ni(OH)_2$ to NiOOH was observed at about 0.37V vs. Ag/AgCl reference electrode, while the maximum rate of ethanol oxidation at the Ni electrode was observed at about 0.42V, The charge-transfer resistance for oxidation of the electrode itself became smaller in the presence of ethanol than in its absence. These results suggest that the $\beta-Ni(OH)_2/\beta-NiOOH$ redox couple is acting as an effective electron transfer mediator far ethanol oxidation. The kinetic parameters also were obtained by the experimental and simulated results.

AC Impedance Study of Oxygen Electrode in Phosphoric Acid Fuel Cell (교류 임피던스법에 의한 인산형 연료전지의 산소전극 특성 연구)

  • Song Rak-Hyun;Kim Chang-Soo;Shin Dong-Ryul
    • Journal of the Korean Electrochemical Society
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    • v.3 no.4
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    • pp.191-195
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    • 2000
  • Electrochemical properties of the oxygen electrode in phosphoric acid fuel cell have been studied using AC impedance method as a function of applied potential, operating temperature and teflon content in the electrode. The oxygen electrode reaction in the $105wt.\%$ phosphoric acid is characterized by a parallel resistive component, $R_p$ and a capacitive component, $C_p$ with serial electrolyte resistance, $R_s$. The conductivity of the phosphoric acid is found to be 0.31-0.47 S/cm in the range of $130\;to\;190^{\circ}C$ from the measured impedance. The increase of applied potential and temperature produced the decreased RP and the increased $C_p$, which means the increase of the oxygen electrode reaction rate. The single cells with the cathode of various teflon contents were tested, and the cathode with $40wt.\%$ teflon showed good performance, which is considered to be related to an optimized impedance behavior.

Relative Comparison of Cathode Polarizations in Solid Oxide Fuel Cells Using the Spreading Concept in AC 2 Point Impedance Spectroscopy

  • Lee, Byung-Kook;Kim, Eui-Hyun;Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.163-167
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    • 2013
  • A modified two-point impedance spectroscopy technique exploits the geometric constriction between an electrolyte and a cathode with an emphasis on semispherical-shaped electrolytes. The spatial limitation in the electrolyte/electrode interface leads to local amplification of the electrochemical reaction occurring in the corresponding electrolyte/electrode region. The modified impedance spectroscopy was applied to electrical monitoring of a YSZ ($Y_2O_3$-stabilized $ZrO_2$)/SSC ($Sm_{0.5}Sr_{0.5}CoO_3$) system. The resolved bulk and interfacial component was numerically analyzed in combination with an equivalent circuit model. The effectiveness of the "spreading resistance" concept is validated by analysis of the electrode polarization in the cathode materials of solid oxide fuel cells.

Leg Motion Monitoring using Bio-impedance Signal (생체 임피던스 신호를 이용한 하지동작 모니터링)

  • 송철규;변용훈;윤대영;김거식;임정모;전희천;권승범;이정훈;이명권
    • Proceedings of the IEEK Conference
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    • 2003.07c
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    • pp.2891-2894
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    • 2003
  • This paper describes the possibility of analyzing gait pattern from the variation of the lower leg electrical impedance. This impedance is measured by the four-electrode method. Two current electrodes are applied to the thigh and foot., and two potential electrodes are applied to the lateral aspect. medial aspect, and posterior position of lower leg. We found the optimal electrode position for knee and ankle joint movements based on high correlation coefficient, least Interference, and maximum magnitude of impedance change. From such features of the lower leg impedance, it has been made clear that different movement patterns exhibit different impedance patterns and impedance level.

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Analysis of Lower Leg Movement Using Bio-impedance Technique (바이오 임피던스를 이용한 하지 운동분석)

  • Song, C.G.;Song, C.H.;Lee, M.G.;Kim, S.C.;Kim, J.C.;Seo, J.H.
    • Proceedings of the KIEE Conference
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    • 2002.11c
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    • pp.414-417
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    • 2002
  • This paper describes the possibility of analyzing gait pattern from the variation of the lower leg electrical impedance. This impedance is measured by the four-electrode method. Two current electrodes are applied to the thigh and foot., and two potential electrodes are applied to the lateral aspect, medial aspect, and posterior position of lower leg. We found the optimal electrode position for knee and ankle joint movements based on high correlation coefficient, least interference, and maximum magnitude of impedance change. From such features of the lower leg impedance, it has been made clear that different movement patterns exhibit different impedance patterns and impedance level.

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AC Complex Impedance Study on the Resistive Humidity Sensors with Ammonium Salt-Containing Polyelectrolyte using a Different Electrode Pattern

  • Cha, Jae-Ryung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2781-2786
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    • 2013
  • We examined the effect of electrode fingers and gaps of coplanar interdigitated electrode (IDE) structures to characterize the ammonium salt-containing polyelectrolyte film of resistance-based humidity sensors. IDEs designed for this purpose were flexible gold electrodes deposited on a polyimide substrate using a printing process because the geometry presents a potential for tunable sensitivity over other electrode designs. The basic design of the sensors consisted of IDEs with a different number of electrode fingers such as 3, 4, and 5 and gap sizes of 310, 360, 410, and $460{\mu}m$. Details of the AC complex impedance characteristics such as the Nyquist plot, Bode plot, and activation energy based on electrode construction were investigated.

Calculation of Electric Potential Rise of Horizontal Grounding Electrode Caused by Lightning Stroke Currents (뇌격전류에 의한 수평접지극의 전위상승 계산)

  • Lee, Bok-Hee;Cho, Sung-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.12
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    • pp.81-86
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    • 2013
  • An electric potential rise of the grounding electrode developed by the lightning stroke currents should be calculated for the purpose of effective protection of electrical and electronic equipment. In this paper, the electromagnetic model was applied to calculate the harmonic impedance of grounding electrode. Also the empirical equation related to the permittivity and resistivity of soil was used. The lightning current waveforms, which are expressed by the Heidler's equation, were used in order to calculate accurately transient electric potential rises. The transient voltage was obtained by using the simulated harmonic impedance and the lightning current in frequency domain. Finally, the transient voltages of horizontal grounding electrode(10m) under lightning stroke currents were calculated by IFFT(Inverse Fast Fourier Transform).

Relative Measurement of Differential Electrode Impedance for Contact Monitoring in a Biopotential Amplifier

  • Yoo, Sun-K.
    • International Journal of Control, Automation, and Systems
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    • v.5 no.5
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    • pp.601-605
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    • 2007
  • In this paper, we propose a simple and relative electrode contact monitoring method. By exploiting the power line interference, which is regarded as one of the worst noise sources for bio-potential measurement, the relative difference in electrode impedance can be measured without a current or voltage source. Substantial benefits, including no extra circuit components, no degradation of the body potential driving circuit, and no electrical safety problem, can be achieved using this method. Furthermore, this method can be applied to multi-channel isolated bio-potential measurement systems and home health care devices under a steady measuring environment.

Study on Electrochemical Performance of Solid-State-Electrode on Steel bar in Chloride Solution (염화물 수용액 중의 철근에 대한 고체전극의 전기화학적 성능 연구)

  • Park, Dong-Jin;Park, Jang-Hyun;Lee, Han-Seung;Subbiah, Karthick
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.147-148
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    • 2018
  • In order to compare the electrochemical performance with that of Calomel Electrode, MnO2 solid-state-electrode was fabricated and its potential and impedance were measured in chloride aqueous solution. As a result, the SCPS without chloride ions showed a potential of -200 mV or more and an impedance over 2000 Ωcm, but the potential below -600 mV and the impedance below -200 Ωcm showed as the chloride concentration in the solution increased. It is considered electrochemical studies on the corrosion of rebar are necessary for the MOE, which shows the same tendency as SCE and exhibits electrochemical performance, over the Mortar level in the future.

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