• Title/Summary/Keyword: electrode impedance

Search Result 688, Processing Time 0.023 seconds

Fuel Cell Performance by the Impedance Method (연료전지의 임피던스방법 적용 연구)

  • Kim, Gwi-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.06a
    • /
    • pp.510-511
    • /
    • 2008
  • Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for solid oxide fuel cell, by the way, Ni-YSZ materials are used as anode of high temperature widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(40vol%) was better excellent than the others.

  • PDF

A Study on the Impedance Characteristics and Mechanisms of Li Intecalation on the Tin Oxide-flyash Composite Electrodes (Tin Oxide-flyash Composite 전극의 리튬 이온 Intercalation 메카니즘과 임피던스 특성에 관한 연구)

  • Gu, Hal-Bon;Kim, Jong-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.11
    • /
    • pp.1224-1229
    • /
    • 2004
  • The purpose of this study is to research and develop tin oxide-flyash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry, AC impedance and charge/discharge cycling of SnO$_2$-flyash/SPE/Li cells. The first discharge capacity of SnO$_2$-flyash composite anode was 639 mAh/g. The discharge capacity of SnO$_2$-flyash composite anode was 563 and 472 mAh/g at 6th and 15th cycle, respectively. The SnO$_2$-flyash composite anode with PVDF-PMMA-PC-EC-LiClO$_4$ electrolyte showed good capacity with cycling.

Stability and Electrochemical Characteristics of Polyaniline Salt Films in 1 N HCl Solution

  • 조정환;오응주;요철현
    • Bulletin of the Korean Chemical Society
    • /
    • v.17 no.8
    • /
    • pp.715-719
    • /
    • 1996
  • Thin films of polyaniline (PANI) salts were in situ deposited on a Pt plate during either chemical polymerization or electrochemical polymerization. The oxidation states of the salt films were controlled by the applied DC potential. AC impedance of the Pt/PANI electrode were measured in monomer-free 1 N HCl solution in order to investigate the electrodic properties of the films at the following applied DC potentials: 0, 0.45 and 0.75 V vs. SCE. Very small differences in film conductivity according to its oxidation state were observed by analysis of the impedance spectra, the reasons of which are complicated by enriched water content in the film and possible decrease in the film thickness during the measurements. The electrochemical activity of the film/solution interface varied with its oxidation state. Stability of the film in 1 N HCl solution was also evaluated by impedance and cyclic voltammetry measurements.

Effect of Electrode Degradation on the Membrane Degradation in PEMFC (PEMFC에서 전극 열화가 전해질 막 열화에 미치는 영향)

  • Song, Jinhoon;Kim, Saehoon;Ahn, Byungki;Ko, Jaijoon;Park, Kwonpil
    • Korean Chemical Engineering Research
    • /
    • v.51 no.1
    • /
    • pp.68-72
    • /
    • 2013
  • Until a recent day, degradation of PEMFC MEA (membrane and electrode assembly) has been studied, separated with membrane degradation and electrode degradation, respectively. But membrane and electrode were degraded coincidentally at real PEMFC operation condition. During simultaneous degradation, there was interaction between membrane degradation and electrode degradation. The effect of electrode degradation on membrane degradation was studied in this work. We compared membrane degradation after electrode degradation and membrane degradation without electrode degradation. I-V performance, hydrogen crossover current, fluoride emission rate (FER), impedance and TEM were measured after and before degradation of MEA. Electrode degradation reduced active area of Pt catalyst, and then radical/$H_2O_2$ evolution rate decreased on Pt. Decrease of radical/$H_2O_2$ reduced the velocity of membrane degradation.

Development of Bioelectric Impedance Measurement System Using Multi-Frequency Applying Method

  • Kim, J.H.;Jang, W.Y.;Kim, S.S.;Son, J.M.;Park, G.C.;Kim, Y.J.;Jeon, G.R.
    • Journal of Sensor Science and Technology
    • /
    • v.23 no.6
    • /
    • pp.368-376
    • /
    • 2014
  • In order to measure the segmental impedance of the body, a bioelectrical impedance measurement system (BIMS) using multi-frequency applying method and two-electrode method was implemented in this study. The BIMS was composed of constant current source, automatic gain control, and multi-frequency generation units. Three experiments were performed using the BIMS and a commercial impedance analyzer (CIA). First, in order to evaluate the performance of the BIMS, four RC circuits connected with a resistor and capacitor in serial and/or parallel were composed. Bioelectrical impedance (BI) was measured by applying multi-frequencies -5, 10, 50, 100, 150, 200, 300, 400, and 500 KHz - to each circuit. BI values measured by the BIMS were in good agreement with those obtained by the CIA for four RC circuits. Second, after measuring BI at each frequency by applying multi-frequency to the left and right forearm and the popliteal region of the body, BI values measured by the BIMS were compared to those acquired by the CIA. Third, when the distance between electrodes was changed to 1, 3, 5, 7, 9, 11, 13, and 15 cm, BI by the BIMS was also compared to BI from the CIA. In addition, BI of extracellular fluid (ECF) was measured at each frequency ranging from 10 to 500 KHz. BI of intracellular fluid (ICF) was calculated by subtracting BI of ECF measured at 500 kHZ from BI measured at seven frequencies ranging from 50 to 500 KHz. BI of ICF and ECF decreased as the frequency increased. BI of ICF sharply decreased at frequencies above 300 KHz.

Comparative Analysis on Ground Impedance for a Carbon Block and a Copper Rod (탄소블록과 동봉의 접지임피던스 비교 분석)

  • Seo, Jae-Suk;Park, Hee-Chul;Kil, Gyung-Suk;Oh, Jae-Geun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.6
    • /
    • pp.472-477
    • /
    • 2013
  • This paper carried out the comparative analysis on ground impedance of a carbon block and a copper rod. Two types of grounding electrode were compared ; a carbon block (L : 1 m, ${\Phi}$ : 245 mm) buried at a depth of 0.8 m and a three-linked copper rod (L : 1 m, ${\Phi}$ : 10 mm) of equilateral triangles with 1 m spacing. Ground impedance depending on applied current source was evaluated by the application of a sine wave current with 60 Hz ~ 3.5 MHz, a fast-rise pulse with rising time of 200 ns, a standard lightning impulse of $8/20{\mu}s$ and a 600 Hz square wave. Ground impedance for both electrodes were almost the same value below 100 kHz, and increased rapidly afterwards. The maximum ground impedance appeared $400{\Omega}$ at around 1.5 MHz. Ground impedance of the carbon block was lower at the square wave and was higher at fast-rise pulse than that of the copper rod. Also, ground impedance as ages showed no difference for the last 8 months. From the results, it is likely that ground performance for both electrodes shows no difference against commercial frequency and lightning impulse current, while the copper rod shows better performance against a fast-rise pulse with rise-time of a few hundred ns.

Implementation of Impedance Method to Estimate Blood Flow Variation with Cuff Pressure Change (커프 압력 조절에 따른 혈류량 변화 평가를 위한 임피던스법의 구현)

  • Jeong, Do-Un;Bae, Jin-Woo;Shon, Jung-Man;Yae, Su-Yung;Choi, Byeong-Cheol;Nam, Ki-Gon;Kim, Cheol-Han;Jeon, Gye-Rok
    • Journal of Sensor Science and Technology
    • /
    • v.13 no.6
    • /
    • pp.462-472
    • /
    • 2004
  • In this study, we measured the blood flow on arm by non-invasive method and implemented a system to measure variation of the blood flow by estimating bio-electrical impedance and arterial pressure according to cuff pressure. The implemented system measured impedance variation according to pressure variation applied by artificial cuff pressure on the measuring position. The system consisted of pressure measuring part and impedance measuring part using 4-electrode method. Pressure measuring part was composed of semiconductor pressure sensor and electronic circuit for signal processing of sensor output signal. In addition, impedance measuring part was composed of constant current source circuit and lock-in amplifier for detecting impedance signal. We conducted experiments of impedance measuring part using standard resistance for performance evaluation of the implemented system. In addition we experimented to estimate variation of the blood flow by measuring impedances of the experimental group. We estimated ratio of the blood flow resistance using mean arterial pressure and variation of the blood flow. As a result the ratio of the blood flow resistance and variation of blood flow were in an inverse relationship with each other and the correlation coefficient was -0.96776.