• Title/Summary/Keyword: electrode impedance

Search Result 688, Processing Time 0.026 seconds

Electrochemical Properties of Platinized Counter Electrode on based Stainless Steel Sheet for Dye-Sensitized Solar Cells (SUS 기판을 이용한 염료감응형 태양전지용 백금 상대전극의 전기화학적 특성)

  • Park, Kyung-Hee;Kim, Tae-Young;Back, Hyung-Ryul;Gu, Hal-Bon;Kim, Seung-Jai;Cho, Sung-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.11a
    • /
    • pp.262-263
    • /
    • 2005
  • Pt counter electrode based on flexible metal for dye-sensitized solar cells(DSCs) has been investigated. Photovoltaic structures on lightweight substrates have several advantages over the heavy glass-based structures in both terrestrial and space applications. Cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of Pt counter electrode both FTO glass and SUS sheet substrate. The DSCs composed of the counter electrode based on a stainless steel substrate has obtained conversion efficiencies comparable to that based on the conducting glass. The counter electrode based on the stainless steel substrate has the merit of improving the fill factor and conversion efficiency of the DSCs by reducing its internal resistance.

  • PDF

Sputtered ZTO as a blocking layer at conducting glass and $TiO_2$ Interfaces in Dye-Sensitized Solar Cells (GZO/ZTO 투명전극을 이용한 DSSC의 광전 변환 효율 특성)

  • Park, Jaeho;Lee, Kyungju;Song, Sangwoo;Jo, Seulki;Moon, Byungmoo
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2011.11a
    • /
    • pp.53.2-53.2
    • /
    • 2011
  • Dye-sensitized solar cells(DSSCs) have been recognized as an alternative to the conventional p-n junction solar cells because of their simple fabrication process, low production cost, and transparency. A typical DSSC consists of a transparent conductive oxide (TCO) electrode, a dye-sensitized oxide semiconductor nanoparticle layer, liquid redox electrolyte, and a Pt-counter electrode. In dye-sensitized solar cells, charge recombination processes at interfaces between coducting glass, $TiO_2$, dye, and electrolyte play an important role in limiting the photon-to-electron conversion efficiency. A layer of ZTO thin film less than ~200nm in thickness, as a blocking layer, was deposited by DC magnetron sputtering method directly onto the anode electrode to be isolated from the electrolyte in dye-sensitized solar cells(DSCs). This is to prevent the electrons from back-transferring from the electrode to the electrolyte ($I^-/I_3^-$). The presented DSCs were fabricated with working electrode of Ga-doped ZnO glass coated with blocking ZTO layer, dye-attached nanoporous $TiO_2$ layer, gel electrolyte and counter electrode of Pt-deposited GZO glass. The effects of blocking layer were studied with respect to impedance and conversion efficiency of the cells.

  • PDF

Measurement of Body Fat by Impedance Technique (임피던스 방법을 이용한 체지방 측정)

  • Kim, Deok-Won;Song, Chul-Gyu;Hwang, Soo-Kwan
    • Journal of Biomedical Engineering Research
    • /
    • v.13 no.2
    • /
    • pp.133-140
    • /
    • 1992
  • Bioelectrical Impedance method for measuring human body composition is based upon the principle that the electrical conductivity of the fat-free mass (FFM) is far greater than that of the (at. Deter- mination o( impedance was nlade in 30 healthy and obese men aged $40.9{\pm}14.7$yr (mean${\pm}$SD) and 25 healthy and obese women aged $44.0{\pm}10.2$ yr. A commercial impedance body fat analyzer was used with a four electrode arrangement that introduced a painless constant current(ImA at 50 kHz) into the body. Linear relationships were found between impudence values and FFM(r=-0.786) and between weight and FFM(r=0.837). Signigicant increases in the correlation coefficients were ob served when the predicator Hta/z was regressed against FFM(r=0.912) where Ht Is height and Z Is impedance. A linear regression equation, FFM=0.586(Htf/z) +0.317(Weight) -1.674(r=0.977), was found. The correlation coefficient of % body fat between the impedance and infrared methods was 0.898. These data Indicate that the bioelectrical impedance technique is a reliable and valld approach for the estimation of human body composition. This method Is safe, noninvasivr, prouides rapld measure menu, requires little operator skill and subject cooperation, and Os portable. Finally measurement of percent body fat was made possible using both the regression equation and a developed impedance measuring device which measures impedance between wrist and ankle.

  • PDF

Measurement of Blood Flow Variation using Impedance Method (임피던스법을 이용한 혈류량 변화 측정)

  • Jeong Do-Un;Kang Seong-Chul;Jeon Gye-Rock
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2006.05a
    • /
    • pp.693-696
    • /
    • 2006
  • In this study, we made the system to measure variation of blood flow using bio-electrical impedance analysis method. The system, which could measure variation of impedance according to pressure change by artificial pressure, consists of pressure measurement and impedance measurement by 4-electrode method. Pressure measurement splits into semiconducting pressure sensor and electronic circuit for processing output signal. In addition, impedance measurement splits into constant current source circuit and lock-in amplifier for detection impedance signal. We experimented feature of impedance measurement using standard resistance to evaluate the system characteristic. As well as, we experimented to estimate variation of blood flow by measuring impedance and blood flow resistance ratio using mean arterial pressure and variation of blood flow with experimental group. As result of this study, blood flow resistance ratio and variation of blood flow were definitely in inverse proportion and were -0.96776 as correlation coefficient by correlation analysis.

  • PDF

Comparison of Ablation Performance between Octopus Multipurpose Electrode and Conventional Octopus Electrode

  • Sae-Jin Park;Jae Hyun Kim;Jeong Hee Yoon;Jeong Min Lee
    • Korean Journal of Radiology
    • /
    • v.24 no.2
    • /
    • pp.86-94
    • /
    • 2023
  • Objective: To compare Octopus multipurpose (MP) electrodes, which are capable of saline instillation and direct tissue temperature measurement, and conventional electrodes for radiofrequency ablation (RFA) in porcine livers in vivo. Materials and Methods: Sixteen pigs were used in this study. In the first experiment, RFA was performed in the liver for 6 minutes using Octopus MP electrodes (n = 15 ablation zones) and conventional electrodes (n = 12 ablation zones) to investigate the effect of saline instillation. The ablation energy, electrical impedance, and ablation volume of the two electrodes were compared. In the second experiment, RFA was performed near the gallbladder (GB) and colon using Octopus MP electrodes (n = 12 ablation zones for each) with direct tissue temperature monitoring and conventional electrodes (n = 11 ablation zones for each). RFA was discontinued when the temperature increased to > 60℃ in the Octopus MP electrode group, whereas RFA was performed for a total of 6 minutes in the conventional electrode group. Thermal injury was assessed and compared between the two groups by pathological examination. Results: In the first experiment, the ablation volume and total energy delivered in the Octopus MP electrode group were significantly larger than those in the conventional electrode group (15.7 ± 4.26 cm3 vs. 12.5 ± 2.14 cm3, p = 0.027; 5.48 ± 0.49 Kcal vs. 5.04 ± 0.49 Kcal, p = 0.029). In the second experiment, thermal injury to the GB and colon was less frequently noted in the Octopus MP electrode group than that in the conventional electrode group (16.7% [2/12] vs. 90.9% [10/11] for GB and 8.3% [1/12] vs. 90.9% [10/11] for colon, p < 0.001 for all). The total energy delivered around the GB (2.65 ± 1.07 Kcal vs. 5.04 ± 0.66 Kcal) and colon (2.58 ± 0.57 Kcal vs. 5.17 ± 0.90 Kcal) were significantly lower in the Octopus MP electrode group than that in the conventional electrode group (p < 0.001 for all). Conclusion: RFA using the Octopus MP electrodes induced a larger ablation volume and resulted in less thermal injury to the adjacent organs compared with conventional electrodes.

Electrosorption Behavior of $TiO_2$/Activated Carbon Composite for Capacitive Deionization (축전식 이온제거에 대한 $TiO_2$/Activated Carbon 화합물의 전기흡착 거동)

  • Lee, Jeong-Won;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Applied Chemistry for Engineering
    • /
    • v.21 no.3
    • /
    • pp.265-271
    • /
    • 2010
  • Desalination effects of capacitive deionization (CDI) process was studied using $TiO_2$/activated carbon electrode. In order to enhance the wettability of electrode and decrease a electrode resistance, $TiO_2$ was coated on activated carbon. By means of $TiO_2$ coating on activated carbon, electric double layer to adsorption content in CDI process was increased. It was identified from TEM, XRD, and XPS that the activated carbon based on $TiO_2$ composite was fabricated successfully by means of sol-gel method. As a results of cyclic voltammetry and impedance, it was identified that $TiO_2$/activated carbon electrode has more electric double later capacitance and less diffusion resistance than activated carbon. Also charge-discharge and ion conductivity profiles showed that the ion removal ratios of $TiO_2$/activated carbon electrode in NaCl electrolyte of $1000\;{\mu}S/cm$ more increased about 39% than that of activated carbon. In conclusion it was possible to identify that the carbon electrode coated $TiO_2$ as electrode material was more effective than raw carbon electrode.

Impedance Analysis of Resistance Anomaly of $BaTiO_3$ based PTC thermistor

  • Chun, Myoung-Pyo;Myoung, Seong-Jae;Nam, Joong-Hee;Cho, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2009.06a
    • /
    • pp.182-182
    • /
    • 2009
  • The effect of Re-oxidation on the PTCR properties of Sm-doped barium titanate ceramics was investigated by means of impedance spectroscopy. Electrical properties such as resistance vs. temperature, I-V curve were measured and microstructure was observed with SEM photography. Sample was fabricated with thick film process such as tape casting of green sheet, screen printing of electrode pattern, stacking, firing in reduced atmosphere and re-oxidation, etc. As the temperature of re-oxidation increases, resistance jump as a function of temperature enhances but resistance at room temperature increases. These behavior of resistance as a function of temperature, dependent on the re-oxidation condition, is analyzed with Cole-Cole impedance plot and is shown to be related with the degree of oxidation of grain boundary regardless of grain core during re-oxidation process of sample.

  • PDF

A Model of a Simplified Mammography Geometry for Breast Cancer Imaging with EIT (전기임피던스 단층촬영법을 위한 단순화된 매모그래피 구조의 모델)

  • Choi, Myoung-Hwan
    • Journal of Industrial Technology
    • /
    • v.26 no.B
    • /
    • pp.221-226
    • /
    • 2006
  • Electrical impedance tomography (EIT) is a technique for determining the electrical conductivity and permittivity distribution within the interior of a body from measurements made on its surface. One recent application area of the EIT is the detection of breast cancer by imaging the conductivity and permittivity distribution inside the breast. The present "gold standard" for breast cancer detection is X-ray mammography, and it is desirable that EIT and X-ray mammography use the same geometry. This paper presents a forward model of a simplified mammography geometry for EIT imaging. The mammography geometry is modeled as a rectangular box with electrode arrays on the top and bottom planes. A forward model for the electrical impedance imaging problem is derived for a homogeneous conductivity distribution and Validated by experiment using a phantom tank.

  • PDF

Electrochemical Impedance Analysis of Polyaniline-Film on Platinum Electrodes (백금 전극에 입힌 폴리아닐린의 전기화학적 임피던스)

  • Chon, Jung-Kyoon;Min, Byoung Hoon
    • Journal of the Korean Chemical Society
    • /
    • v.39 no.9
    • /
    • pp.722-727
    • /
    • 1995
  • The electrochemical impedance spectra of polyaniline film prepared by cyclic voltammetry have been investigated in 0.1 M aqueous sulfuric acid solution. Charge transfer resistances were rather low at the oxidized states in agreement with the conductive behavior reported at these potentials. The corresponding exchange current densities were very high. Large values of capacitance associated with the polymer have been found which vary as a function of the electrode potentials. An equivalent electrical circuit has been deduced from the impedance data. It was therefore possible to obtain the parameters of the ionic mass transport within the film.

  • PDF

The transient grounding impedance measurment of large grid grounding electrodes (대규모 그리드 접지전극의 과도접지임피던스의 측정)

  • Jeon, Byung-Wook;Lee, Su-Bong;Li, Feng;Lee, Seung-Ju;Jung, Dong-Cheol;Lee, Bok-Hee
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
    • /
    • 2008.10a
    • /
    • pp.69-72
    • /
    • 2008
  • This paper presents the transient and conventional grounding impedance behaviors of large grid grounding system associated with the injection point of impulse current The measurement methods consider two possible errors in the grounding-system impedances: (1) ground mutual resistance due to current flow through ground from the ground electrode to be measured to the current auxiliary, (2) ac mutual coupling between the current test lead and the potential test lead The test circuit was set to reduce the error factors. The transient grounding impedance depends on the rise time and injection point of impulse current It is effective that grounding conductor is connected to the center of the large grid grounding system.

  • PDF