• Title/Summary/Keyword: electrode impedance

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Gated Conductivity Imaging using KHU Mark2 EIT System with Nano-web Fabric Electrode Interface (나노웹 섬유형 전극 인터페이스와 KHU Mark2 EIT 시스템을 이용한 생체신호 동기 도전율 영상법)

  • Kim, Tae-Eui;Kim, Hyun-Ji;Wi, Hun;Oh, Tong-In;Woo, Eung-Je
    • Journal of Biomedical Engineering Research
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    • v.33 no.1
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    • pp.39-46
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    • 2012
  • Electrical impedance tomography(EIT) can produce functional images with conductivity distributions associated with physiological events such as cardiac and respiratory cycles. EIT has been proposed as a clinical imaging tool for the detection of stroke and breast cancer, pulmonary function monitoring, cardiac imaging and other clinical applications. However EIT still suffers from technical challenges such as the electrode interface, hardware limitations, lack of animal or human trials, and interpretation of conductivity variations in reconstructed images. We improved the KHU Mark2 EIT system by introducing an EIT electrode interface consisting of nano-web fabric electrodes and by adding a synchronized biosignal measurement system for gated conductivity imaging. ECG and respiration signals are collected to analyze the relationship between the changes in conductivity images and cardiac activity or respiration. The biosignal measurement system provides a trigger to the EIT system to commence imaging and the EIT system produces an output trigger. This EIT acquisition time trigger signal will also allow us to operate the EIT system synchronously with other clinical devices. This type of biosignal gated conductivity imaging enables capture of fast cardiac events and may also improve images and the signal-to-noise ratio (SNR) by using signal averaging methods at the same point in cardiac or respiration cycles. As an example we monitored the beat by beat cardiac-related change of conductivity in the EIT images obtained at a common state over multiple respiration cycles. We showed that the gated conductivity imaging method reveals cardiac perfusion changes in the heart region of the EIT images on a canine animal model. These changes appear to have the expected timing relationship to the ECG and ventilator settings that were used to control respiration. As EIT is radiation free and displays high timing resolution its ability to reveal perfusion changes may be of use in intensive care units for continuous monitoring of cardiopulmonary function.

Synthesis and Characterisation of Mixed Conducting Perovskite Type Oxide and Its Electrochemical Application to Electrode Material for Solid Oxide Fuel Cell

  • Kim, Yu-Mi;Pyun, Su-Il;Lee, Gyoung-Ja;Kim, Ju-Sik
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.116-125
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    • 2007
  • This article is concerned with synthesis, characterisation and electrochemical application of the mixed conducting perovskite type oxide to electrode materials for solid oxide fuel cell. First, this review provides a comprehensive survey of the various synthetic methods such as solid state reaction, Pechini, glycine nitrate process and sol-gel methods for the preparation of perovskite type oxide powders. Subsequently, the electrical and microstructural properties of the mixed conducting oxides were discussed in detail. Finally, as electrochemical applications of the mixed conducting perovskite type oxides to electrode materials for solid oxide fuel cell, fundamentals of theoretical ac-impedance model for porous mixed conducting electrodes were introduced. Furthermore, the ac-impedance behaviour of porous and dense mixed conducting electrodes prepared by various synthetic methods was discussed.

Study on the surface reactions of carbon and graphite electrodes in sulfuric acid solution (황산 용액중의 분극시 나타나는 탄소전극들의 계면반응)

  • 오한준;김인기;이종호;이영훈
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.648-662
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    • 1996
  • Electrode surface reaction on glassy carbon and synthesized graphite (PVDF mixed graphite) in sulfuric acid solution is investigated by impedance spectroscopy at cyclic polarization. The redox peak, which may be due to the change of chemical adsorped functional group on electrode surface or oxidation and reduction of oxygen, is represented on glassy carbon and graphite electrode in potentio-dynamic current curve. The oxidation and reduction of these surface functional group on glassy carbon and PVDF mixed graphite have a major affect on the impedance spectrum and Faraday impedance parameter at cyclic polarization.

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Effects of Electrode and Matrix in the PAFC Performance (전극 및 메트릭스가 인산형 연료전지의 성능에 미치는 영향)

  • Kim, Dong-Jin;Song, Rak-Hyun;Lee, Byung-Rok;Kim, Chang-Soo;Shin, Dong-Ryul
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1873-1875
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    • 1999
  • The effects of electrode and matrix in the PAFC were investigated using AC-impedance spectroscopy. The performance of PAFC was determined by changing external electronic load. AC impedance measurement was carried out as functions of phosphoric acid impregnation temperature. operating temperature and matrix coating method using various cathodes ; 20%Pt/C, 20%Pt-Ni/C, 20%Pt-Co-Ni/C, 10%Pt-Fe-Co/C, and 20%Pt-Fe-Co/C From the analysis of measured impedance data, the interfacial resistance decreased with increasing operating temperature. and with decreasing impregnation temperature. As compared with the alloy catalysts, Pt catalyst showed a lower interfacial resistance. This consist with the cell performance.

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A Study on the Impedance Model and Driving Performance for the Electrical Discharge Type External Electrode Fluorescent Lamp (전계방전형 외부전극 형광램프의 모델과 구동특성)

  • Kim, Cherl-Jin;Yoo, Byeong-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.7
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    • pp.1181-1186
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    • 2008
  • A impedance model simulating the electrical characteristics of the External Electrode fluorescent lamp operated at high frequency is proposed. The model is constructed from a two parameter equation which is derived based on a set of two measurements. This is a readily constructed and computer simulator oriented model which is suitable for a preliminary design of electronic ballasts. Simulated and experimental results are used to verify the analytical discussions, and moreover, an electronic ballast design example using the proposed model is presented to further demonstrate its application.

Effects of the composition and the pressing rate of electrode on the internal resistance and the battery characteristic (전극 조성 및 압착율에 의한 내부저항과 전지특성)

  • 정재국;진봉수;문성인;윤문수;남효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.421-424
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    • 2000
  • We have examined the impedance characteristics and the rate characteristics of LPB. As results, the impedance of LPB decreased with increased pressing rate of electrodes, adding amounts of PVdF and VGCF. And the rate characteristics of LPB increased with the a increase of pressure-rate, PVdF and VGCF contents. The rate characteristics of LPB was improved by pressing of electrode and adding of VGCF content. And specific capacity of anode was increased with adding amounts of PVdF. Higher pressing rate of electrodes, higher adding amounts of PVdF and VGCF was necessitated good rate characteristics for lithium polymer battery.

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Measurements of Cardiac and Respiratory Signals using Impedance Method (임피던스 방법에 의한 심장 및 호흡 신호의 측정)

  • Kim, Hyung-Joong;Shim, Jae-Ok;Jang, Jae-Myeong
    • Proceedings of the KOSOMBE Conference
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    • v.1993 no.11
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    • pp.183-186
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    • 1993
  • We have developed a bioimpedance measurement system for impedance cardiography and pneumography. The system injects 50kHz, $200mA_{p-p}$ curreng into the thorax and measures the voltage changes using body surface electrodes. We used the four-electrode method for tile measurement of cardiac singnals and two-electrode method for respiratory signals. We developed a Microsoft Windows program for the acquisition, display, storage, and processing of impedance signals.

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Fabrication of Ti/IrO2/Ta2O5 Electrode with High Electrochemical Activity and Long Lifetime (전기화학적 활성과 내구성이 높은 Ti/IrO2/Ta2O5 전극 제조)

  • Kim, Da-eun;Yoo, Jaemin;Lee, Yongho;Pak, Daewon
    • Journal of Korean Society on Water Environment
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    • v.33 no.1
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    • pp.34-39
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    • 2017
  • Under a corrosive environment, electrodes that are applied in the water-treatment system need not only very high electrochemical activity for fast reactions, but also high durability for cost saving. Therefore, the fabrication condition of iridium electrodes was examined to produce a more durable iridium electrode in this study. Tantalum was selected as a binder to enhance the durability of the iridium electrode. Investigation of the weight ratio between the catalyst and the binder to improve electrochemical activity was performed. Also, to compare the effect of the different coating amounts of the catalyst, the results of CV (Cyclic Voltammetry) and EIS (Electrochemical Impedance Spectroscopy) were discussed. Furthermore, an ALT(Accelerated Lifetime Test) was designed and applied to the electrodes to determine the conditions for highly durable electrode fabrication.

High Performance of Nano-sized LiFePO4 Positive Electrode Using Etched Al Current Collector

  • Lee, Gil-Won;Ryu, Ji-Heon;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.157-162
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    • 2010
  • The electrodes comprising nano-sized $LiFePO_4$, carbon black and binder are prepared with two different Al current collectors. One is the generally used normal Al foil and the other is the chemically etched Al foil. Surface characteristics of each Al foil and electrochemical performance of the cathodes using each foil are investigated. The electrode from the etched Al foil exhibits better physical and electrochemical properties as compared to those of the normal Al foil because the etched Al foil has rough surface with sub-micron pores which improve the adhesion between the electrode materials and the substrate. The electrode on the etched Al foil has such a strong peel strength that the impedance is smaller than that of normal one. Indeed the $LiFePO_4$ electrode from the etched Al foil exhibits a better rate capability and remains intact even after storage for 1 week at the charged state at the elevated temperature $60^{\circ}C$.

Generation of a High Voltage Pulse of 50 ns Pulse Duration using a Helical Blumlein Pulse Forming Line (나선형 블룸라인 PFL을 이용한 50 ns 펄스폭의 고전압 펄스 발생)

  • Roh, Youngsu;Jin, Yun-Sik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.6
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    • pp.786-791
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    • 2013
  • A high voltage pulse generator based on the Blumlein pulse forming line (PFL) was fabricated to produce a voltage pulse whose peak value is ~300 kV and pulse duration is ~50 ns. Three cylindrical electrodes, such as inner, middle, and outer electrodes, are concentrically placed to make a compact PFL. To increase the pulse duration of the output pulse without any change of the size of the generator, the middle electrode is replaced by a helical strip electrode. To determine the radius of the helical electrode, the impedance of the helical Blumlein PFL is calculated using an approximate formula where the dispersive property of the helical Blumlein PFL is not considered. The dependence of the impedance on the frequency is computed by a commercial program. The number of turns in the helical electrode is decided to provide a demanded pulse duration. The experimental result shows that the helical Blumlein PFL is capable of making a high voltage pulse of ~50 ns pulse duration.