• 제목/요약/키워드: electrode area

검색결과 964건 처리시간 0.095초

Simultaneous Determination of Diffusion Coefficient and Concentration by Chronoamperometry at a Microdisk Electrode

  • Jung, Yong-Ju;Kwak, Juh-Youn
    • Bulletin of the Korean Chemical Society
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    • 제15권3호
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    • pp.209-213
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    • 1994
  • Two unknown values among three electrochemical values, i.e. electrode area, diffusion coefficient, and concentration, are simultaneously obtained by nonlinear regression analysis of a single chronoamperometric faradaic current curve at a microdisk electrode. The approach is an analytical application of the semi-empirical equation presented by Shoup and Szabo for the chronoamperometric response at a disk electrode. To demonstrate the usefulness and accuracy of this approach, the chronoamperometric current at a platinum disk electrode of 50 ${\mu}m$ radius in solutions of $Ru(NH_3)_6^{3+},\;ferrocene,\;Fe(CN)_6^{3-},\;and\;C_{60}$, were analyzed.

K2CO3 처리된 Coal Tar Pitch 활성탄 전극의 결정성 및 EDLC 성능 (Structural Characterization and EDLC-Electrode Performance of Coal-Tar-Pitch Activated Carbon Using K2CO3 Treatment)

  • 최푸름;정지철;임연수;김명수
    • 한국재료학회지
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    • 제26권9호
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    • pp.460-467
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    • 2016
  • Activated carbons (ACs) have been used as EDLC (electric double-layer capacitor) electrode materials due to their high specific area, stability, and ecological advantages. In order to prepare ACs with high density and crystallinity, coal tar pitch (CTP) was activated by $K_2CO_3$ and the textural and electrochemical properties of the obtained ACs were investigated. Although the CTP ACs formed by $K_2CO_3$ activation had much smaller specific surface area and pore volume than did the CTP ACs formed by KOH activation, their volumetric specific capacitance (F/cc) levels as electrode materials for EDLC were comparable due to their higher density and micro-crystallinity. Structural characterization and EDLC-electrode performance were studied with different activation conditions of $CTP/K_2CO_3$ ratio, activation temperature, and activation period.

정전분무 방전극을 이용한 습식 전기집진장치의 미세먼지 집진효율 평가 (Evaluation of Particle Collection Efficiency in a Wet Electrostatic Precipitator Using an Electrosprayed Discharge Electrode)

  • 김홍직;김종현;김종호
    • 한국대기환경학회지
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    • 제31권6호
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    • pp.530-537
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    • 2015
  • The wet electrostatic precipitator (wet ESP) is an effective control device which removes submicron particles reentrained in a collection plate and water soluble gas. However, its collection efficiency decreases, as its operation is subject to water-induced distortion of the collection electrode. In order to make up for the limitation, we modified the wet ESP system by installing electrosprayed discharge electrodes. The modified wet ESP system can wash both the collection plate and discharge electrode. As a result, we were able to fabricate a compact wet ESP with a small specific collecting area ($0.18m^2(m^3/min)$) that can accomplish a high collection efficiency of fine particles (97.1%). In addition, the device obtained a relatively low specific corona power of approximately $10W/(m^3/min)$.

다양한 양극산화 공정조건에 따른 롤 금형 표면에 형성되는 나노포어 형상에 대한 연구 (Investigation of Nanopore Shape Formed on an Aluminum Roll Mold with Various Anodizing Conditions)

  • 류인곤;한의돈;김병희;서영호
    • 한국생산제조학회지
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    • 제26권2호
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    • pp.166-171
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    • 2017
  • This study analyzes the effect of anodizing conditions on nanopore formation on a cylindrical aluminum roll. In general, a nanopore is formed at the center of a concave base-pattern. Occasionally, multiple nanopores are formed on a single base-pattern. However, to control the diameter and interpore distance precisely, single nanopores are required. In this study, the ratio of the number of single nanopores to the total number of nanopores was investigated by varying anodizing conditions such as electrode area, electrolyte concentration, and rotation speed of the roll mold. The areal ratio of the counter-electrode to the working electrode (aluminum), electrolyte concentration, and the roll-mold rotation speed were varied from 0.4% to 42%, 0.07 M to 0.3 M, and 5 rpm to 75 rpm, respectively. The experimental results showed that the single-nanopore ratio increased with increasing counter-electrode area and electrolyte concentration. However, the rotation speed had no significant effect on nanopore shape.

28W(T5) 형광등 구동용 압전트랜스포머의 전기적 특성 (Electrical Characteristics of Piezoelectric Transformer for Driving A 28W Fluorescent Lamp)

  • 류주현;황상모;윤광희;김종선;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.847-851
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    • 2000
  • In this study, contour-vibration-mode Pb($Ni_{1/2}$,$W_{1/2}$)$O_3$-Pb(Zr,Ti)$O_3$ piezoelectric transformers for driving a 28W(T5) fluorescent lamp were fabricated to the modified filter structure with ring and dot electrodes which has been developed for application in 455kHz AM radios. The piezoelectric transformers were fabricated to the size of $31.5$\times$31.5$\times$2.5$mm^3$ with the variations of ring/dot electrode area ratio. Driving of piezoelectric transformer was carried out with input region for the ring electrode and output region for the dot electrode. The electrical properties and characteristic temperature rises caused by the vibration were measured at various load resistances. A 28 W fluorescent lamp, T5, was successfully driven by the fabricated transformer. The transformer with ring/dot electrode area ratio of 1.83 exhibited the best properties in terms of output power, efficiency and characteristic temperature rise, 30.95 W, 97.57% and8.3$^{\circ}C$ respectively.

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새로운 전극구조를 통한 수직배향 액정 셀의 투과특성 향상 (An improved electrode structure of the Patterned Vertical Aligned Liquid Crystal Cell for high transmittance)

  • 최용현;손정희;이기동
    • 한국정보통신학회논문지
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    • 제11권9호
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    • pp.1724-1728
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    • 2007
  • 본 논문에서는 PVA(Patterned Vertical Alignment)액정 셀의 광투과율 향상을 위한 새로운 전극 구조를 제안하였다. 제안한 전극 구조의 액정 디렉터의 분포 및 광투과율 계산은 상용 시뮬레이터인 'TechWiz LCD'를 사용하였다. 광 시야각을 위한 전극구조에 의해 투과율 감소를 발생시키는 부분에 대해 연구하여 그 부분의 액정 디렉터 분포를 변화시킬 수 있는 구조를 제안하였다. 그리고 기존 PVA모드와 제안한 구조를 사용한 PVA모드의 광투과율을 계산하여 비교하였다. 그 결과로부터 제안한 PVA액정 셀의 광투과율이 높아짐을 확인할 수 있었다.

아연-이온 전기화학 커패시터의 에너지 저장 성능향상을 위한 다공성 전극 제조 (Fabrication of Porous Electrodes for Zinc-Ion Supercapacitors with Improved Energy Storage Performance)

  • 안건형
    • 한국재료학회지
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    • 제29권8호
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    • pp.505-510
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    • 2019
  • Zn-ion supercapacitors (ZICs) show high energy densities with long cycling life for use in electronic devices. Porous Zn electrodes as anodes for ZICs are fabricated by chemical etching process using optimized conditions. The structures, morphologies, chemical bonding states, porous structure, and electrochemical behavior are examined. The optimized porous Zn electrode shows a root mean square of roughness of 173 nm and high surface area of $153{\mu}m^2$. As a result, ZIC using the optimized porous Zn electrode presents excellent electrochemical performance with high specific capacitance of $399F\;g^{-1}$ at current density of $0.5A\;g^{-1}$, high-rate performance ($79F\;g^{-1}$ at a current density of $10.0A\;g^{-1}$), and outstanding cycling stability (99 % after 1,500 cycles). The development of energy storage performance using synergistic effects of high roughness and high surface area is due to increased electroactive sites by surface functionalization of Zn electrode. Thus, our strategy will lead to a rational design and contribute to next-generation supercapacitors in the near future.

구현방식이 용이한 텍스타일 터치센서 개발 및 구조적 설계 (Development and Structural Design of Textile Touch Sensor Easily Implemented)

  • 김지선;박진희;김주용
    • 한국의류학회지
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    • 제45권1호
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    • pp.168-179
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    • 2021
  • This study presents and develops a textile type touch sensor structural design that is easy to implement. First, the design of the touch sensor circuit finds the size of the switch with the easiest finger contact and selects a structure with a long circuit with the lowest resistance value. An experiment is performed on a change in an electrostatic capacitance value that accompanies the distance on the electrode and the magnitude of the electrode area of the structure; however, the structure having the distance on the electrode and the large electrode area shows the best resistance change. The laundry assessment was conducted three times at a time and ten times at a time with an average standard deviation less than one ohm, with little change in resistance. Consequently, there were no problems with durability and performance for laundry. Finally, in the bending evaluation, the difference in resistance can be seen between 1-2 ohms and was developed as a smart wearable in the future; in addition, there was no problem as a difference in resistance can be seen between 1 and 2 ohms.

FFS 모드에서 Reverse Twist가 구동전압에 미치는 영향에 관한 연구 (Study on the Effect of the Operation Voltage according to the Reverse Twist for the fringe Field Switching (FFS) Mode)

  • 김미숙;정연학;신승민;김향율;김서윤;임영진;이승희
    • 한국전기전자재료학회논문지
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    • 제18권11호
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    • pp.1033-1037
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    • 2005
  • We have studied on the effect of the operation voltage according to the reverse twist for the different fringe field switching (FFS) structure. The FFS structure with a vertically patterned edge of the pixel electrode (VPP) has lower operation voltage comparing to the one with a horizontally patterned edge of the pixel electrode (HPP). The reason is like that the number of the pattern of the pixel edge for the VPP structure is one third comparing with the HPP structure and thus, there is small reverse twist area for the VPP structure. Actually, the reverse twist disturbs the twist of LC near adjacent active area, result that LCs near there have the unstable dynamics. That is, the operation voltage increases as the reverse twist area increases. Therefore, it is very important to design pixel electrode with a small reverse twist region for the FFS mode.

가교폴리에틸렌 지중케이블에서 화상계측을 이용한 수트리 열화현상 분석 (The Analysis of Water Tree Degradations in Underground Distribution Cables Using Image Measurement)

  • 김덕근;임장섭;이진;이준웅;김태성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.19-23
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    • 1998
  • Water tree degradations have been considered as one of the most important causes of failure in underground distribution cables with polymeric insulation. Water tree growth is a preliminary step in the sequence of electrical tree initiation and electrical breakdown of the insulation. In this paper, needle electrode is made use of the etching methods and the pellet type specimen is made to observe the water tree in succession. In previous methods are able to observe the tree degradations without cutting and dyeing. The water tree image is recorded on VTR with CCD camera. The tree length of X, Y axis direction and aging area(treeing area) are calculated with image measurement. As a result of this study, water tree is observed by non-destructive method. Electrical tree is initiated from needle electrode tip only but water tree is initiated from total area of water electrode. Electrical tree owing to water treeing is initiated at low electric field and grown with discontinuously. Namely, water tree is shown up a different characteristics of tree growth.

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