• Title/Summary/Keyword: electrical conduction

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Defect Structure and Electrical Conduction Mechanism of Yttrium Sesquioxide (산화이트륨의 결함구조 및 전기전도 메카니즘)

  • Kim, Keu-Hong;Park, Sung-Ho;Choi, Jae-Shi
    • Journal of the Korean Chemical Society
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    • v.28 no.3
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    • pp.149-154
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    • 1984
  • The electrical conductivity of p-type yttrium sesquioxide has been measured as a function of temperature and of oxygen partial pressure at temperatures from 650 to 1050$^{\circ}C$C and oxygen partial pressures from $1 {\times}10^{-5}\;to\;2{\times}10^{-1}$atm. Plots of log conductivity vs. 1/T at constant oxygen partial pressures are found to be linear with low-and high-temperature dependences of conductivity. The high-temperature dependence of conductivity shows two different defect structures. The plots of log conductivity vs. log $Po_2$ are found to be linear at $Po_2$'s of $10^{-5}\;to\;10^{-1}$ atm. The electrical conductivity dependences on $Po_2$ are found to be ${{\sigma}{\propto}Po_2}^{1/6}$at $850{\sim}950^{\circ}C,\;{{\sigma}{\propto}Po_2}^{3/16}$ at $950{\sim}1050^{\circ}C\;and\;{{\sigma}{\propto}Po_2}^{1/7.5}{\sim}{{\sigma}{\propto}Po_2}^{1/8.3}\;at\;650{\sim}800^{\circ}C$, respectively. The defect structures are$O_i{''}$ at $850{\sim}950^{\circ}C$ and $V_M{'''}$ at $950{\sim}1050^{\circ}C$. The electron hole is main carrier type, however, ionic contribution is found at lower temperature portion.

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Electrical Stability of Zn-Pr-Co-Cr-Dy Oxides-based Varistor Ceramics (Zn-Pr-Co-Cr-Dy 산화물계 바리스터 세라믹스의 전기적 안정성)

  • 남춘우;박종아;김명준;류정선
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1067-1072
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    • 2003
  • The electrical stability of the varistor ceramics composed of Zn-Pr-Co-Cr-Dy oxides-based varistors was investigated at 0.0∼2.0 mol% Dy$_2$O$_3$ content under DC accelerated aging stress. The ceramic density was increased up to 0.5 mol% Dy$_2$O$_3$ whereas further addition of Dy$_2$O$_3$ decreased sintered ceramic density. The density sailently affected the stability due to the variation of conduction path. The nonlinearity of varistor ceramics was greatly improved above 45 in the nonlinear exponent and below nearly 1.0 ${\mu}$A by incorporating Dy$_2$O$_3$. Under 0.95 V$\_$1mA/150$^{\circ}C$/24 h stress state, the varistor ceramics doped with 0.5 mol% Dy$_2$O$_3$ exhibited the highest electrical stability, in which the variation rates of varistor voltage, nonlinear exponent, and leakage current were -0.9%, -14.4%, and +483.3%, respectively. The variation rates of relative permittivity and dissipation factor were +7.1% and +315.4%, respectively. The varistors with further addition of Dy$_2$O$_3$ exhibited very unstable state resulting in the thermal runaway due to low density.

Tracking Propagation Mechanism on the Surface of Polyvinyl-Chloride-Sheathed Flat Cord based on Electric Field Analysis and Gas Discharge Physics (전계해석과 기체방전 이론을 기반으로 한 Polyvinyl-Chloride-Sheathed Flat Cord 표면의 트래킹 진전 메커니즘)

  • Lim, Dong-Young;Park, Herie;Jee, Seung-Wook
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.30-38
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    • 2019
  • Tracking, which is one of the main causes of electrical fires, is perceived as a physical phenomenon of electrical discharge. Hence tracking should be explained based on electric field analysis, conduction path by electron generation, and gas discharge physics. However, few papers have considered these details. This paper proposes a tracking mechanism including their effects on tracking progress. In order to prove this mechanism, a tracking experiment, an electric field analysis for the carbonization evolution model, and an explanation of the tracking process by gas discharge physics were conducted. From the tracking experiment, the current waveforms were measured at each stage of the tracking progress from corona discharge to tracking breakdown. The electric field analysis was carried out in order to determine the electric field on the surface of a dry-band and the high electric field region for electron generation during the generation and progress of carbonization. In this paper, the proposed tracking mechanism consisted of six stages including electron avalanche by corona discharge, accumulation of positive ions, expansion of electron avalanche, secondary electron emission avalanche, streamer, and tracking by conductive path. The pulse current waveforms measured in the tracking experiment can be explained by the proposed tracking mechanism. The results of this study will be used as the technical data to detect tracking phenomenon, which is the cause of electric fire, and to improve the proof tracking index.

High temperature electrical properties of Sr-and Mg-Doped LaAlO3 (억셉터(Sr, Mg)가 첨가된 LaAlO3의 고온 전도 특성)

  • Park, Ji Young;Park, Hee Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.187-191
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    • 2019
  • Perovskite-type oxides have consistently attracted considerable attention for their applications in high-temperature electrochemical devices, such as electrolytes and electrodes of solid oxide fuel cells, oxygen permeating membranes and sensors etc. Among them, the electrical conductivity of 10 % Sr and 10 % Mg doped $LaAlO_3$ (LSAM9191) was measured using impedance spectroscopy and 4-probe d.c. method. Below $550^{\circ}C$, the grain boundary resistance mostly determined the overall conductivity; however, it nearly disappeared above $800^{\circ}C$. Using the defect model and curve fitting, the ionic and electronic conductivity contributions were also separated. In the temperature region where the sample resistance is mostly determined by the grain volume property, LSAM9191 was an oxygen ion conductor at low $Po_2$ and a mixed conductor at high $Po_2$. With increasing temperature, the ionic conduction region only slightly increased. Thus, LSAM9191 is a promising material as an oxygen ion conductor at high temperature and in low $Po_2$.

A novel energy-efficient bridgeless boost AC to DC converter (효율을 고려한 새로운 AC/DC 컨버터)

  • Yoon, Kyoung-Kuk;Kim, Seong-Hwan;Kim, Deok-Ki
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.3
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    • pp.223-227
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    • 2016
  • Power supplies make the load compatible with its power source. DC power supplies are extensively used with most electrical and electronic appliances such as computers, television, and audio sets. The presence of non-linear loads results in a low power factor and higher harmonics in the power system. Several techniques for power-factor correction and harmonic reduction have been reported in the literature. This paper proposes a bridgeless boost converter that improves the power factor and reduces the harmonic content in input line currents as compared to full-bridge rectifiers. This bridgeless boost converter eliminates the need of a line-voltage bridge rectifier in conventional boost converter and thereby reduces conduction losses. The effectiveness of the proposed scheme is verified by computer simulations by using the PSIM software.

The Study of Induction Heating Apparatus with High Efficiency (고효율 유도가열 전열장치 개발에 관한 연구)

  • Cho, Hyun-Seob
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.9 no.2
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    • pp.185-189
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    • 2016
  • Energy-saving heat depending on the country's rise in oil prices up to the product development is regarded as pending issues. Therefore, in recent years, been a continuing research studies developed for increasing the economic efficiency and reliability achieved in effectively using the side of the energy for heating using electrical to address these problems and, in particular made active the technology developed for high performance and renal material becoming. This paper is to study the development of highly efficient induction heating device according to the excellent heat transfer characteristics for energy transfer. Induction heating is used as the phenomenon of electromagnetic induction, such as heat transfer conduction or convection of the existing methods are no different. Medium heat without beating is absorbed directly into the water column switched rapidly, have features that heats evenly. In addition, high-frequency induction heating in a variety of frame designs. Heating element heats only when utilized properly, it is possible to heat the focus.

Analysis and Design of a DC-Side Symmetrical Class-D ZCS Rectifier for the PFC of Lighting Applications

  • Ekkaravarodome, Chainarin;Thounthong, Phatiphat;Jirasereeamornkul, Kamon;Higuchi, Kohji
    • Journal of Power Electronics
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    • v.15 no.3
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    • pp.621-633
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    • 2015
  • This paper proposes the analysis and design of a DC-side symmetrical zero-current-switching (ZCS) Class-D current-source driven resonant rectifier to improve the low power-factor and high line current harmonic distortion of lighting applications. An analysis of the junction capacitance effect of Class-D ZCS rectifier diodes, which has a significant impact on line current harmonic distortion, is discussed in this paper. The design procedure is based on the principle of the symmetrical Class-D ZCS rectifier, which ensures more accurate results and provides a more systematic and feasible analysis methodology. Improvement in the power quality is achieved by using the output characteristics of the DC-side Class-D ZCS rectifier, which is inserted between the front-end bridge-rectifier and the bulk-filter capacitor. By using this symmetrical topology, the conduction angle of the bridge-rectifier diode current is increased and the low line harmonic distortion and power-factor near unity were naturally achieved. The peak and ripple values of the line current are also reduced, which allows for a reduced filter-inductor volume of the electromagnetic interference (EMI) filter. In addition, low-cost standard-recovery diodes can be employed as a bridge-rectifier. The validity of the theoretical analysis is confirmed by simulation and experimental results.

Enhanced Electrochromic Switching Performance in Nickel Hydroxide Thin Film by Ultra-Thin Ni Metal (니켈금속 박막에서 수산화 니켈 박막의 전기변색속도 개선)

  • Kim, Woo-Seong;Seong, Jeong-Sub
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.2
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    • pp.163-167
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    • 2002
  • Improved optical switching property of electrochromic nickel hydroxide/nickel glass thin film is reported. Nickel metal film was deposited on glass by e-beam evaporation before following electrochemical redox cycling to form nickel hydroxide for electrochromic activation. Without ITO (indium tin oxide) layer as electrical conductor, this electrode showed more rapid coloration rate than nickel hydroxide film on ITO substrate in the change of the electric voltage and optical transmittance. XPS analysis confirmed the existence of ultra-thin nickel metal layer (${\sim}10{\AA}$) between electrochemically grown nickel hydroxide and the glass substrate. It is concluded that the remained nickel metal nano-layer attribute to the conduction layer and the enhanced response time.

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Electrical Characteristics of Ambipolar Thin Film Transistor Depending on Gate Insulators (게이트 절연특성에 의존하는 양방향성 박막 트랜지스터의 동작특성)

  • Oh, Teresa
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.18 no.5
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    • pp.1149-1154
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    • 2014
  • To observe the tunneling phenomenon of oxide semiconductor transistor, The Indium-gallum-zinc-oxide thin film transistors deposited on SiOC as a gate insulator was prepared. The interface characteristics between a dielectric and channel were changed in according to the properties of SiOC dielectric materials. The transfer characteristics of a drain-source current ($I_{DS}$) and gate-source voltage ($V_{GS}$) showed the ambipolar or unipolar features according to the Schottky or Ohmic contacts. The ambipolar transfer characteristics was obtained at a transistor with Schottky contact in a range of ${\pm}1V$ bias voltage. However, the unipolar transfer characteristics was shown in a transistor with Ohmic contact by the electron trapping conduction. Moreover, it was improved the on/off switching in a ambipolar transistor by the tunneling phenomenon.

Effect of Hydrogen Treatment on Anatase TiO2 Nanotube Arrays for Photoelectrochemical Water Splitting

  • Kim, Hyun Sik;Kang, Soon Hyung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2067-2072
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    • 2013
  • Hydrogen ($H_2$) treatment using a two-step $TiO_2$ nanotube (TONT) film was performed under various annealing temperatures from $350^{\circ}C$ to $550^{\circ}C$ and significantly influenced the extent of hydrogen treatment in the film. Compared with pure TONT films, the hydrogen-treated TONT (H:TONT) film showed substantial improvement of material features from structural, optical and electronic aspects. In particular, the extent of enhancement was remarkable with increasing annealing temperature. Light absorption by the H:TONT film extended toward the visible region, which was attributable to the formation of sub-band-gap states between the conduction and valence bands, resulting from oxygen vacancies due to the $H_2$ treatment. This increased donor concentration about 1.5 times higher and improved electrical conductivity of the TONT films. Based on these analyses and results, photoelectrochemical (PEC) performance was evaluated and showed that the H:TONT film prepared at $550^{\circ}C$ exhibited optimal PEC performance. Approximately twice higher photocurrent density of 0.967 $mA/cm^2$ at 0.32 V vs. NHE was achieved for the H:TONT film ($550^{\circ}C$) versus 0.43 $mA/cm^2$ for the pure TONT film. Moreover, the solar-to-hydrogen efficiency (STH, ${\eta}$) of the H:TONT film was 0.95%, whereas a 0.52% STH efficiency was acquired for the TONT film. These results demonstrate that hydrogen treatment of TONT film is a simple and effective tool to enhance PEC performance with modifying the properties of the original material.