• Title/Summary/Keyword: electric oxidization

Search Result 16, Processing Time 0.019 seconds

Effect of Electric Current on Friction of Hydraulic Members (유압구동재의 마찰에 미치는 전류의 영향)

  • 전성재;강인혁;류미라;조연상;박흥식
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
    • /
    • 2002.04a
    • /
    • pp.16-21
    • /
    • 2002
  • Generally, Oxidization film are generated by friction and wear in lubricant oil. It is effect that the heat and pressure act on contact area. Because the electrons movement progress the oxidization, if the electrons movement be regulated, the thickness of oxidization film can be regulated and friction characteristics can be improved. But electronic current can deteriorate friction characteristics, so various characteristics must be investigated on transforming of electronic current. Therefor, using the Norton equation, short current were transformed between ball and disk. Also, an experiment was carried out using ball on disk type tester. So, we studied up on effect of current for friction characteristics.

  • PDF

Effect of Electric Current on Friction of Hydraulic Members (윤활하에서의 마찰 특성에 미치는 전류의 영향)

  • Jeon, Seong-Jae;Gang, In-Hyeok;Ryu, Mi-Ra;Jo, Yeon-Sang;Park, Hong-Sik
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 2002.05a
    • /
    • pp.150-155
    • /
    • 2002
  • Generally, Oxidization film are generated by friction and wear in lubricant oil. It is effect that the heat and pressure act on contact area. Because the electrons movement progress the oxidization, if the electrons movement be regulated, the thickness of oxidization film can be regulated and friction characteristics can be improved. But electronic current can deteriorate friction characteristics, so various characteristics must be investigated on transforming of electronic current. Therefor, using the Norton equation, short current were transformed between ball and disk. Also, an experiment was carried out using ball on disk type tester. So, we studied up on effect of current for friction characteristics.

  • PDF

Effect of Electric Current on Friction Characteristics of Machine Driving Elements (기계구동 부재의 마찰특성에 미치는 전류의 영향)

  • Jun, Sung-Jae;Cho, Yon-Sang;Park, Heung-Sik
    • Tribology and Lubricants
    • /
    • v.18 no.5
    • /
    • pp.339-344
    • /
    • 2002
  • Whenever moving surfaces of machine driving elements interact in air and lubricating oil, oxidization film on the surfaces are generated. It is effect to prevent friction and wear on contact area. Since the electronic current progress the oxidization of metal, if the electronic flow be regulated, the thickness of oxidization film can be regulated and friction characteristics can be improved. But the electronic current can deteriorate friction characteristics, so various characteristics must be investigated on transforming of electronic current. Therefor, using the Norton equation in this study, short current were transformed between frictional materials using ball on disk type tester. It was studied on effect of electronic current for friction characteristics.

Characteristics of Copper-catalyzed Cyanide Decomposition by Electrolysis (전해법에 의한 구리함유 시안의 분해특성)

  • Lee Jin-Yeung;Yoon Ho-Sung;Kim Sung-Don;Kim Chul-Joo;Kim Joon-Soo;Han Choon;Oh Jong-Kee
    • Resources Recycling
    • /
    • v.13 no.1
    • /
    • pp.28-38
    • /
    • 2004
  • The characteristics of cyanide decomposition in aqueous phase by electric oxidization have been explored in an effort to develop a process to recycle waste water. Considering current efficiency and voltage, the free cyanide decomposition experiment by electric oxidization indicated that 5 V of voltage and copper catalytic Cu/CN mole ratio 0.05 was the most appropriate condition, where current efficiency was 26%, and decomposition speed was 5.6 mM/min. High voltage and excess copper addition increased decomposition speed a little bit but not current efficiency. The experiment of free cyanide density change proves that high density cyanide is preferred because speed and current efficiency increase with density. Also, the overall decomposition reaction could be represented by the first order with respcect to cyanide with the rate constant of $1.6∼7.3${\times}$10^{-3}$ $min^{-1}$ The mass transfer coefficient of electric oxidization of cyanide came out as $2.42${\times}$10^{-5}$ $min^{-1}$ Furthermore, the Damkohler number was calculated as 5.7 in case of 7 V and it was found that the mass transfer stage was the rate determining step.

Prediction of expansion of electric arc furnace oxidizing slag mortar using MNLR and BPN

  • Kuo, Wen-Ten;Juang, Chuen-Ul
    • Computers and Concrete
    • /
    • v.20 no.1
    • /
    • pp.111-118
    • /
    • 2017
  • The present study established prediction models based on multiple nonlinear regressions (MNLRs) and backpropagation neural networks (BPNs) for the expansion of cement mortar caused by oxidization slag that was used as a replacement of the aggregate. The data used for the models were obtained from actual laboratory tests on specimens that were produced with water/cement ratios of 0.485 or 1.5, within which 0%, 10%, 20%, 30%, 40%, or 50% of the cement had been replaced by oxidization slag from electric-arc furnaces; the samples underwent high-temperature curing at either $80^{\circ}C$ or $100^{\circ}C$ for 1-4 days. The varied mixing ratios, curing conditions, and water/cement ratios were all used as input parameters for the expansion prediction models, which were subsequently evaluated based on their performance levels. Models of both the MNLR and BPN groups exhibited $R^2$ values greater than 0.8, indicating the effectiveness of both models. However, the BPN models were found to be the most accurate models.

The Analysis of Oxidization Characteristics according to the shapes of RCD contacts (RCD 접점형태에 따른 산화특성 분석)

  • Kim, Dong-Woo;Kim, Hyang-Kon;Gil, Hyoung-Jun;Han, Woon-Kim;Choi, Chung-Seog
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.576-577
    • /
    • 2005
  • In this paper, the oxidization characteristics were analyzed according to the shapes of Residual Current Protective Device(RCD) contacts. RCD is an electrical safety device specially designed to immediately switch the electricity off when electric leakage is detected at a level harmful to a person using electrical equipment. The shapes of RCD contacts are a little bit different according to the models. When RCD is turned on, stationary and moving contact do not fit together. So, it can cause the increase of contact resistance. To discover the deterioration characteristics of RCD contacts by switching repetition, the contacts were analyzed by stereo microscope, Scanning Electron Microscope(SEM) and Energy Dispersive X-ray Spectrometer(EDS).

  • PDF

A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior (리튬이온전지의 유기용매분해에 따른 SEI film 형성과 전기화학적 거동에 관한 연구)

  • Kim, Min-Seong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11b
    • /
    • pp.545-549
    • /
    • 2001
  • We have produced electrolyte solution out of 1.15M $LiPF_6$ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M $LiPF_6$ DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M $LiPF_6$ EC/DEC(1/2 by vol%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC,DMC and EMC brought the de-decomposition peak of salt anion of $PF_6$ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. $Li/Li^+$). In addition, a kinetics current peak, in which intercalation of Lt is proceeded at 750mV, 450mV(vs. $Li/Li^+$), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance($R_{ct}$) according to the electric potential of $Li^+$ intercalation at 750mV(vs. $Li/Li^+$), which was the same as the resistance ($R_f$) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance($R_p$) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

  • PDF

A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior (리튬이온전지의 유기용매분해에 따른 SEI film형성과 전기화학적 거동에 관한 연구)

  • 김민성;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11a
    • /
    • pp.545-549
    • /
    • 2001
  • We have produced electrolyte solution out of 1.15M LiPF$\sub$6/ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M LiPF$\sub$6/DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M LiPF$\sub$6/ EC/DEC(1/2 by vo%%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC, DMC and EMC brought the de-decomposition peak of salt anion of PF$\sub$6/$\^$-/ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. Li/Li$\^$+/\`). In addition, a kinetics current peak, in which intercalation of Li$\^$+/ is proceeded at 750mv, 450mv(vs. Li/Li$\^$+/), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance(R$\sub$ct/) according to the electric potential of Li$\^$+/ intercalation at 750mv(vs. Li/Li$\^$+/), which was the same as the resistance (R$\sub$f/) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance(R$\sub$p/) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

  • PDF

Electro-thermal analysis of contacts and connections in VCB under high electric current by finite element methods (유한요소법에 의한 VCB 접속부의 대전류에 대한 전열해석)

  • Kang, Woo-Jong;Huh, Hoon;Kang, Kyeong-Rok
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.22 no.4
    • /
    • pp.715-722
    • /
    • 1998
  • A large electric system of a vacuum circuit breaker(VCB) has been studied for the electro-thermal analysis by finite element methods. Since the heat generation in VCB causes not only energy loss but deterioration of the VCB system with oxidization of parts, the overheating of the system must be prevented. For the analysis, a finite element formulation is derived for both electric analysis and thermal analysis that are coupled together. Two sets of formulations are uncoupled after finite dimensional approximation. First, the electric potential is obtained for the entire field and scaled to the given electric current. The electric field obtained is then used to calculate the heat generation in the VCB system including contacts and connections for the calculation of the temperature distribution in the entire domain. The finite element analysis is carried out to study the effect of shapes and locations of contacts and connections. From the results, the existing VCB has been modified to enhance its capacity with reduction of heat generation and temperature elevation.

A Characterization on Organic Electro-luminescence (유기 전기 luminescence 다이오드 특성)

  • Lee, Han-Seong
    • Proceedings of the KIEE Conference
    • /
    • 2007.11c
    • /
    • pp.165-169
    • /
    • 2007
  • Organic EL has been expected to adopt to a new styles of technology that make flat display after Tang & Vanslyke made food electric luminescence device in late 1980s. Their studies based on multi layer structure that consists of emitting layer and carrier transporting layer using proper organic material. In this study we made multi layer device using $Eu(TTA)_3(phen)$ as a luminescence material by PVD and investigate luminous properties of each device. But oxidization of organic layer by ITO, energy walls in both pole interface, contaminations of ITO surface, importance of protecting membrane, diffusive dimming of light to cathode organic layer, these causes of degradations are common facts of a macromolecule and micromolecule. We think these degradation caused by the impact of heat and electro-chemical factor, bulk effect and interface phenomenon, and raise a question.

  • PDF