• 제목/요약/키워드: electric oxidization

검색결과 16건 처리시간 0.028초

유압구동재의 마찰에 미치는 전류의 영향 (Effect of Electric Current on Friction of Hydraulic Members)

  • 전성재;강인혁;류미라;조연상;박흥식
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2002년도 춘계학술대회 논문집
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    • pp.16-21
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    • 2002
  • Generally, Oxidization film are generated by friction and wear in lubricant oil. It is effect that the heat and pressure act on contact area. Because the electrons movement progress the oxidization, if the electrons movement be regulated, the thickness of oxidization film can be regulated and friction characteristics can be improved. But electronic current can deteriorate friction characteristics, so various characteristics must be investigated on transforming of electronic current. Therefor, using the Norton equation, short current were transformed between ball and disk. Also, an experiment was carried out using ball on disk type tester. So, we studied up on effect of current for friction characteristics.

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윤활하에서의 마찰 특성에 미치는 전류의 영향 (Effect of Electric Current on Friction of Hydraulic Members)

  • 전성재;강인혁;류미라;조연상;박홍식
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 제35회 춘계학술대회
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    • pp.150-155
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    • 2002
  • Generally, Oxidization film are generated by friction and wear in lubricant oil. It is effect that the heat and pressure act on contact area. Because the electrons movement progress the oxidization, if the electrons movement be regulated, the thickness of oxidization film can be regulated and friction characteristics can be improved. But electronic current can deteriorate friction characteristics, so various characteristics must be investigated on transforming of electronic current. Therefor, using the Norton equation, short current were transformed between ball and disk. Also, an experiment was carried out using ball on disk type tester. So, we studied up on effect of current for friction characteristics.

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기계구동 부재의 마찰특성에 미치는 전류의 영향 (Effect of Electric Current on Friction Characteristics of Machine Driving Elements)

  • 전성재;조연상;박흥식
    • Tribology and Lubricants
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    • 제18권5호
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    • pp.339-344
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    • 2002
  • Whenever moving surfaces of machine driving elements interact in air and lubricating oil, oxidization film on the surfaces are generated. It is effect to prevent friction and wear on contact area. Since the electronic current progress the oxidization of metal, if the electronic flow be regulated, the thickness of oxidization film can be regulated and friction characteristics can be improved. But the electronic current can deteriorate friction characteristics, so various characteristics must be investigated on transforming of electronic current. Therefor, using the Norton equation in this study, short current were transformed between frictional materials using ball on disk type tester. It was studied on effect of electronic current for friction characteristics.

전해법에 의한 구리함유 시안의 분해특성 (Characteristics of Copper-catalyzed Cyanide Decomposition by Electrolysis)

  • 이진영;윤호성;김성돈;김철주;김준수;한춘;오종기
    • 자원리싸이클링
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    • 제13권1호
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    • pp.28-38
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    • 2004
  • 시안 함유 도금폐수의 재활용이 가능한 전기적 산화법에 의한 수용액상의 시안 성분 분해특성을 규명하기 위한 실험을 수행하였다. 전해산화에 의한 유리시안 분해실험 결과, 전류효율과 분해속도를 고려할 때 전압 5V, 구리촉매량 Cu/CN 몰비 0.05가 적정조건이었으며, 이때의 전류효율은 26%, 분해속도는 5.6 mM/min 이었으며 적정수준 이상의 전압과 구리첨가는 분해속도를 소폭 상승시키나 전류효율은 증가하지 않았다. 지지전해질의 증가는 전류밀도의 증가로 분해속도를 소폭 증가시키나 전류효율은 크게 감소하였다. 초기 유리시안 농도실험 결과, 과산화수소 산화와 유사한 결과를 나타내어 시안농도 증가시 분해속도 및 전류효율이 동시에 증가하므로 고농도 시안일수록 적절한 공정으로 판단된다. 각 변수가 총괄 반응속도에 미치는 영향을 확인하기 위하여 In($C_{CN}$ /$C_{CNo}$ )와 시간과의 관계로부터 계산한 총괄 반응속도 상수는 $1.6∼7.3${\times}$10^{-3}$ $min^{-1}$ 이었으며 시안농도에 대하여 1차 반응식을 만족하였다.

Prediction of expansion of electric arc furnace oxidizing slag mortar using MNLR and BPN

  • Kuo, Wen-Ten;Juang, Chuen-Ul
    • Computers and Concrete
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    • 제20권1호
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    • pp.111-118
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    • 2017
  • The present study established prediction models based on multiple nonlinear regressions (MNLRs) and backpropagation neural networks (BPNs) for the expansion of cement mortar caused by oxidization slag that was used as a replacement of the aggregate. The data used for the models were obtained from actual laboratory tests on specimens that were produced with water/cement ratios of 0.485 or 1.5, within which 0%, 10%, 20%, 30%, 40%, or 50% of the cement had been replaced by oxidization slag from electric-arc furnaces; the samples underwent high-temperature curing at either $80^{\circ}C$ or $100^{\circ}C$ for 1-4 days. The varied mixing ratios, curing conditions, and water/cement ratios were all used as input parameters for the expansion prediction models, which were subsequently evaluated based on their performance levels. Models of both the MNLR and BPN groups exhibited $R^2$ values greater than 0.8, indicating the effectiveness of both models. However, the BPN models were found to be the most accurate models.

RCD 접점형태에 따른 산화특성 분석 (The Analysis of Oxidization Characteristics according to the shapes of RCD contacts)

  • 김동우;김향곤;길형준;한운기;최충석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.576-577
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    • 2005
  • In this paper, the oxidization characteristics were analyzed according to the shapes of Residual Current Protective Device(RCD) contacts. RCD is an electrical safety device specially designed to immediately switch the electricity off when electric leakage is detected at a level harmful to a person using electrical equipment. The shapes of RCD contacts are a little bit different according to the models. When RCD is turned on, stationary and moving contact do not fit together. So, it can cause the increase of contact resistance. To discover the deterioration characteristics of RCD contacts by switching repetition, the contacts were analyzed by stereo microscope, Scanning Electron Microscope(SEM) and Energy Dispersive X-ray Spectrometer(EDS).

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리튬이온전지의 유기용매분해에 따른 SEI film 형성과 전기화학적 거동에 관한 연구 (A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior)

  • 김민성;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.545-549
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    • 2001
  • We have produced electrolyte solution out of 1.15M $LiPF_6$ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M $LiPF_6$ DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M $LiPF_6$ EC/DEC(1/2 by vol%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC,DMC and EMC brought the de-decomposition peak of salt anion of $PF_6$ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. $Li/Li^+$). In addition, a kinetics current peak, in which intercalation of Lt is proceeded at 750mV, 450mV(vs. $Li/Li^+$), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance($R_{ct}$) according to the electric potential of $Li^+$ intercalation at 750mV(vs. $Li/Li^+$), which was the same as the resistance ($R_f$) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance($R_p$) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

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리튬이온전지의 유기용매분해에 따른 SEI film형성과 전기화학적 거동에 관한 연구 (A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior)

  • 김민성;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.545-549
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    • 2001
  • We have produced electrolyte solution out of 1.15M LiPF$\sub$6/ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M LiPF$\sub$6/DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M LiPF$\sub$6/ EC/DEC(1/2 by vo%%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC, DMC and EMC brought the de-decomposition peak of salt anion of PF$\sub$6/$\^$-/ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. Li/Li$\^$+/\`). In addition, a kinetics current peak, in which intercalation of Li$\^$+/ is proceeded at 750mv, 450mv(vs. Li/Li$\^$+/), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance(R$\sub$ct/) according to the electric potential of Li$\^$+/ intercalation at 750mv(vs. Li/Li$\^$+/), which was the same as the resistance (R$\sub$f/) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance(R$\sub$p/) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

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유한요소법에 의한 VCB 접속부의 대전류에 대한 전열해석 (Electro-thermal analysis of contacts and connections in VCB under high electric current by finite element methods)

  • 강우종;허훈;강경록
    • 대한기계학회논문집A
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    • 제22권4호
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    • pp.715-722
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    • 1998
  • A large electric system of a vacuum circuit breaker(VCB) has been studied for the electro-thermal analysis by finite element methods. Since the heat generation in VCB causes not only energy loss but deterioration of the VCB system with oxidization of parts, the overheating of the system must be prevented. For the analysis, a finite element formulation is derived for both electric analysis and thermal analysis that are coupled together. Two sets of formulations are uncoupled after finite dimensional approximation. First, the electric potential is obtained for the entire field and scaled to the given electric current. The electric field obtained is then used to calculate the heat generation in the VCB system including contacts and connections for the calculation of the temperature distribution in the entire domain. The finite element analysis is carried out to study the effect of shapes and locations of contacts and connections. From the results, the existing VCB has been modified to enhance its capacity with reduction of heat generation and temperature elevation.

유기 전기 luminescence 다이오드 특성 (A Characterization on Organic Electro-luminescence)

  • 이한성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 학술대회 논문집 전문대학교육위원
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    • pp.165-169
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    • 2007
  • Organic EL has been expected to adopt to a new styles of technology that make flat display after Tang & Vanslyke made food electric luminescence device in late 1980s. Their studies based on multi layer structure that consists of emitting layer and carrier transporting layer using proper organic material. In this study we made multi layer device using $Eu(TTA)_3(phen)$ as a luminescence material by PVD and investigate luminous properties of each device. But oxidization of organic layer by ITO, energy walls in both pole interface, contaminations of ITO surface, importance of protecting membrane, diffusive dimming of light to cathode organic layer, these causes of degradations are common facts of a macromolecule and micromolecule. We think these degradation caused by the impact of heat and electro-chemical factor, bulk effect and interface phenomenon, and raise a question.

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