• 멤브레인
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• 제14권3호
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• pp.207-217
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• 2004

본 연구에서는 복합막의 제조공법으로 가장 광범위하게 쓰이는 계면중합법을 이용하여 나노복합막을 제조하였다. Monomer의 농도 및 조성, curing 조건, 후처리 조건과 같은 복합막 제조조건과, 운전압력, 공급액의 농도와 같은 운전인자에 의한 막성능 변화를 조사하였고, 계면중합 과정중에 첨가제를 사용하여 막의 유효면적을 확대하여 투과유속을 증가시키고자 하였다. Monomer의 농도가 증가함에 따라 배제능은 일정하였지만 투과유속이 감소하였고, curing 온도가 증가함에 따라서는 오히려 안정적인 박막층의 형성이 저해되어서 배제능과 투과유속이 모두 감소하였고, curing 시간에 따른 막성능의 변화는 나타나지 않았다. Test solution의 농도가 올라감에 따라서 투과유속과 배제능 모두 감소하였으며, 운전압력이 증가함에 따라서는 배제능과 투과유속 모두 향상하는 경향을 보였다. 계면중합과정중에 사용하는 아민단량체(amine monomer) 중 방향족 다이아민(aromatic amine)인 MPD의 함량을 높임에 따라서 배제능은 증가하였지만 투과유속은 현저하게 떨어졌다. 첨가제의 농도에 따른 표면 거칠기 증가 경향은 MPD가 포함된 amine 조성일 때가 더 높았지만 투과유속은 piperazine만 단독으로 사용하였을 때보다 떨어졌다.

• 한국구조물진단유지관리공학회 논문집
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• 제26권1호
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• pp.1-9
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• 2022

제설제는 동절기 도로 위의 눈을 녹이기 위하여 사용되고 있으나, 서울과 같은 대도시에서 교통이 밀집한 도로 시설물의 열화를 촉진시키는 주요 요인 중의 하나이다. 도로 시설물의 합리적인 유지관리 전략을 수립하기 위하여 제설제에 노출된 도로 시설물의 환경분석이 필요하다. 본 연구는 서울시의 적설량 및 사용된 제설제량을 토대로 외래 염소농도를 계산하였다. 평균 표면 염소이온량을 구하고자 서울시의 5년간 기후환경 및 제설제 사용량을 이용하였으며, 주간선 및 보조간선율 17.5 ~ 30%, 제설제 노출 유효면적율 50 ~ 80% 수준에서 검토하였는데, 농축 속도는 0.073~ 0.077%/년, 최대 표면 염소이온량은 콘크리트 중량대비 2.2 ~ 2.31% 수준이었다. 본 연구결과는 염소이온 프로파일의 예측 또는 콘크리트 구체의 화학적 부식정도 등으로 종합적인 유지관리 대책을 수립하는데 활용될 수 있을 것으로 기대된다.

• 한국분말재료학회지
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• 제20권6호
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• pp.474-478
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• 2013

The most general photocatalyst, $TiO_2$ and $WO_3$, are acknowledged to be ineffective in range of visible light. Therefore, many efforts have been directed at improving their activity such as: band-gap narrowing with non-metal element doping and making composites with high specific surface area to effectively separate electrons and holes. In this paper, the method was introduced to prepare a photo-active catalyst to visible irradiation by making a mixture with $TiO_2$ and $WO_3$. In the $TiO_2-WO_3$ composite, $WO_3$ absorbs visible light creating excited electrons and holes while some of the excited electrons move to $TiO_2$ and the holes remain in $WO_3$. This charge separation reduces electron-hole recombination resulting in an enhancement of photocatalytic activity. Added Ag plays the role of electron acceptor, retarding the recombination rate of excited electrons and holes. In making a mixture of $TiO_2-WO_3$ composite, the mixing route affects the photocatalytic activity. The planetary ball-mill method is more effective than magnetic stirring route, owing to a more effective dispersion of aggregated powders. The volume ratio of $TiO_2(4)$ and $WO_3(6)$ shows the most effective photocatalytic activity in the range of visible light in the view point of effective separation of electrons and holes.

• 환경위생공학
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• 제8권1호
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• pp.67-80
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• 1993

This survey was carried out to take the status of seawater intrusion into groundwater wells located in the eastern area of Chejudo, to get the elementary data which may evaluate the level of would-be groundwater contamination, and to perform effective the effort that will supply the clear water for the residents. The sampling sites were northeastern districts of Haengwon, Handong, and Sangdo, southeastern districts of Susan, Nansan, and Samdal, and northwestern districts, as reference, of Aewol, Keumnung, Panpo, Kosan, Shindo, and Bosung. We collected the samples from the public tap water by month, and analysed electrical conductivity, sodium(Na), potassium(K), magnesium(Mg), calcium(Ca), bicarbonate($HC0_{3^-}$), and items of the criteria as drinking water. In the northeastern districts we also added the sampling sites to survey the fluctuations of dissolved solids according to distance from seashore, including two private boreholes and one public tap water of Dukchun. The result is as follows 1) In the northeastern district, the concentration of chloride ion showed large fluctations from 40mg/l to 100mg/l, but suitable for the criteria of drinking water. It was thought that the drought influenced. 2) In the Sangdo of the northeastern districts, similar tendancy to Hangwon and Handong was showed only in the concentration of chloride ion, but different tendancy was showed in chloride-bicarbonate ratio, calcium-magnesium ratio, and sodium adsorption ratio(SAR). Considering these facts, it was not thought that seawater intruded. 3) The components of Na and Cl showed rapid slope in the northeastern districts above 3km from seashore. 4) In the northwestern districts as reference, the concentration of chloride ion fluctuated slightly according to the sampling sites and dates, and the concentration of nitrate-nitrogen in some sites exceeded the criteria of drinking water. These were thought that the surface contaminants rather than the intrusion of seawater influenced mainly the groundwater, considering the correlation(r=0.732) of chloride ion and nitrate-nitrogen. 5) Then we must consider the regional characteristies of soil profile in order to prevent the contamination of groundwater, and moniter also the movement of main components within the sol1 profile, not only the research of the intrusion of seawater.

• 한국해안·해양공학회논문집
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• 제26권2호
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• pp.103-111
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• 2014

크기가 작은 다수의 부이들이 원형으로 배열되어 있을 때 부이를 통한 추출 파워를 포텐셜이론 통하여 살펴보았다. 부이의 크기와 배열 간격이 수심과 파장 그리고 설치면적의 반경에 비하여 작다는 가정 아래에서 다수부이로 채워진 수면에서의 경계조건식을 유도하고 이를 포함한 경계치문제를 고유함수전개법을 이용하여 해석하였다. 추출 파워와 입사파 에너지의 비인 취득 폭을 packing ratio, 배열 반경, 그리고 PTO 감쇠계수를 바꿔가면서 살펴보았다. 또한 다수의 소형 부이를 원형 배열하였을 때 추출된 파력이 같은 잠긴 체적을 갖는 대형 단일 부이보다 효율적임을 계산을 통하여 밝혔다.

• 한국지리정보학회지
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• 제4권1호
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• pp.18-26
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• 2001

본 연구에서는 Landsat TM을 이용하여 연안해역의 수질을 모니터링하기 위해 현장에서 조사된 수중광학 측정자료를 Landsat TM 밴드에 적용하여 Landsat TM 밴드비율 알고리듬을 구성하였다. 수중광학 측정장치인 PRR(profiling reflectance radiometer)을 이용하여 획득된 수중 광 반사도를 Landsat TM 밴드 폭으로 보정한 후 현장에서 실측된 피그먼트와 통계적으로 분석하여 관계식을 도출하였다. 수중 광 반사도를 TM 밴드 1과 밴드 2 의 비율에 의한 알고리듬으로 구성하여 $Y=3.8352{\times}(R(band\;1)/R(band\;2))^{-2.1978}$ ($R^2$=0.7069)과 같은 관계식을 도출하였고, 밴드 1과 밴드 3의 비율에 의한 반사도와 피그먼트의 관계는 $Y=23.288{\times}(R(band\;1)/R(band\;3))^{-1.5243}$ ($R^2$=0.8062) 이다. 수면 위로 올라오는 광량과 TM의 레이디언스 값을 각각 구하여 대기효과 중의 Rayleigh 산란과 Mie 산란에 의한 대기중의 잡음비율을 파악하였으며, 연안해역의 조사지점에서 80% 이상의 대기잡음이 있음을 제시하였다. 본 연구에서 도출된 수중 광 알고리듬을 Landsat TM에서 수신된 영상신호에 적용하여 시화호와 연안해역의 수질을 정량적으로 분석하기 위해서는 수중 구성 성분들의 수중 광학 특성을 고려한 수중 알고리듬의 보정과 대기중의 잡음을 효율적으로 제거할 수 있는 대기보정기법의 적용이 요구된다.

• 한국재료학회지
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• 제22권5호
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• pp.237-242
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• 2012

We report on the NO gas sensing properties of Al-doped zinc oxide-carbon nanotube (ZnO-CNT) wire-like layered composites fabricated by coaxially coating Al-doped ZnO thin films on randomly oriented single-walled carbon nanotubes. We were able to wrap thin ZnO layers around the CNTs using the pulsed laser deposition method, forming wire-like nanostructures of ZnO-CNT. Microstructural observations revealed an ultrathin wire-like structure with a diameter of several tens of nm. Gas sensors based on ZnO-CNT wire-like layered composites were found to exhibit a novel sensing capability that originated from the genuine characteristics of the composites. Specifically, it was observed by measured gas sensing characteristics that the gas sensors based on ZnO-CNT layered composites showed a very high sensitivity of above 1,500% for NO gas in dry air at an optimal operating temperature of $200^{\circ}C$; the sensors also showed a low NO gas detection limit at a sub-ppm level in dry air. The enhanced gas sensing properties of the ZnO-CNT wire-like layered composites are ascribed to a catalytic effect of Al elements on the surface reaction and an increase in the effective surface reaction area of the active ZnO layer due to the coating of CNT templates with a higher surface-to-volume ratio structure. These results suggest that ZnO-CNT composites made of ultrathin Al-doped ZnO layers uniformly coated around carbon nanotubes can be promising materials for use in practical high-performance NO gas sensors.

• 천문학회보
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• 제41권2호
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• pp.54.2-54.2
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• 2016

We present a machine learning approach to estimating stellar atmospheric parameters, effective temperature (Teff), surface gravity (log g), and metallicity ([Fe/H]) for stars observed during the course of the Sloan Digital Sky Survey (SDSS). For training a neural network, we randomly sampled the SDSS data with stellar parameters available from SEGUE Stellar Parameter Pipeline (SSPP) to cover the parameter space as wide as possible. We selected stars that are not included in the training sample as validation sample to determine the accuracy and precision of each parameter. We also divided the training and validation samples into four groups that cover signal-to-noise ratio (S/N) of 10-20, 20-30, 30-50, and over 50 to assess the effect of S/N on the parameter estimation. We find from the comparison of the network-driven parameters with the SSPP ones the range of the uncertainties of 73~123 K in Teff, 0.18~0.42 dex in log g, and 0.12~0.25 dex in [Fe/H], respectively, depending on the S/N range adopted. We conclude that these precisions are high enough to study the chemical and kinematic properties of the Galactic disk and halo stars, and we will attempt to apply this technique to Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST), which plans to obtain about 8 million stellar spectra, in order to estimate stellar parameters.

• 한국세라믹학회지
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• 제22권5호
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• pp.76-84
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• 1985

Mechanical property enhancing mechanisms of $Al_2O_3-ZrO_2$ two phase ceramic composites were studied for several compositions of different $ZrO_2$/$Al_2O_3$ ratio. Microstructural analysis of $Al_2O_3-ZrO_3$(pure) composites indicated that pre-existing microcrack due to larger $ZrO_2$ particle at grain boundary extended along alumina grain boundaries within process zone. Microcracks also nucleated when very small $ZrO_2$ particles at the grain boundaries transformed to monoclinic phase at near of main crack tip. These types of microcracks could contribute to the toughening achieved by creating additional crack surface area during crack propagation. Microstructural analyses also showed that the average grain size and abnormal grain size of $Al_2O_3$ were decreased with increasing $ZrO_2$ vol% in $Al_2O_3$ matrix. As a result it could be concluded as follows In TEX>$Al_2O_3-ZrO_3$(pure) system 1. Microcrack nucleation (stress-induced microcracking) and extension was effective mechanism for absorpiton of fracture energy 2, More narrow distribution and smaller grain size of $Al_2O_3$ due to $ZrO_2$particles mainly contributed to main-tatin the strength and hardness.

• Journal of Chest Surgery
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• 제21권1호
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• pp.10-16
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• 1988

Ten patients with tetralogy of Fallot were studied angiocardiographically before a modified Blalock-Taussig shunt and again 25*3.2 months after the previous shunt. All of ten patients had patent previous shunt at the time of follow up examination. Pre-and postoperative diameters of left and right pulmonary artery and descending aorta were measured and pulmonary artery index [the sum of the crossectional areas of the right and left pulmonary arteries standardized by the body surface area] was calculated. The ratio of mean diameter of left and right pulmonary arteries to the diameter of the descending aorta [LPA+RPA/2xDA] was increased postoperatively by 0.20*0.068 [p=0.020]. Mean PAI [pulmonary artery index] increased from 283.8*178.4 mm/m2 BSA to 345.8~144.5 mm/m2 BSA after shunt operation [p=0.019]. This results suggested that the modified Blalock-Taussig shunt was effective to help growth of the pulmonary arteries in most cases of the study populations but the ones with the PAI>233mm*/m* BSA appeared less benefited by Blalock Taussig shunt. Calculation of PAI could be an aid to making a decision whether to perform a one stage corrective surgical procedure or a palliative shunt procedure in the patient with small pulmonary arteries.