• Title/Summary/Keyword: effective compound

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Chemical Reactivity of N-Iodopyridinium Dichlorodate as a Lubricant Additive (潤滑添加劑로서의 N-Iodopyridinium Dichlorodate의 화학반응성)

  • Moon Tak Jin;Kwon Oh Seung
    • Journal of the Korean Chemical Society
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    • v.19 no.1
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    • pp.43-49
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    • 1975
  • Small amounts of iodine compound in mineral oils are usually effective in reducing friction of metallic surfaces. Such improvement in frictional behaviour of wear characteristics was explained by the formation of a diiodide layer lattice structure at the metallic contact surfaces. The lubrication mechanism, however, by which organoiodine compounds functions is not based on the formation of such lattice structure iodide. It was tested and shown, by a static surface chemical reactivity test, wear and EP tests, and a hot wire method, that compound such as N-iodopyridinium dichlorodate, a double charge transfer complex, reacted with metals as an interhalogen compound and that the resultant thin film product reduced appreciable the friction of metallic surfaces, more than compounds such as methyl iodide, diiodomethane, and iodoform. These results suggest that the action of iodine, included in organoiodine compounds, is not that of a classical layer structure iodide, and an entirely new mechanism may be derived from a further studies on charge transfer complex compounds of organoiodine compounds.

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Assessment of Best Available Technology of Wastewater Treatment Facilities in Petrochemical Basic Compound Manufacturing and Plastics and Synthetic Resins Manufacturing (석유화학계 기초화합물 제조시설과 합성수지 및 기타 플라스틱물질 제조시설의 폐수처리시설 BAT평가)

  • Kim, Youngnoh;Lim, Byungjin;Kwon, Osang
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.59-65
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    • 2006
  • The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for petrochemical basic compound manufacturing (PBCM) and plastics and synthetic resins manufacturing (PSRM) industry. Wastewater discharged from the each category contains high concentration of COD and toluene. Eighteen sites were surveyed and wastewater qualities were analyzed. Six and two different technologies were applied to the PBCM and PSRM industry for the end-of-pipe treatment process, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options: typical activated-sludge process + sand filtration + activated carbon adsorption (PBCM) and wet oxidation + chemical precipitation + typical activated-sludge process + chemical precipitation (PSRM) were selected as the BAT for each industry.

Effects on the Performance of Velocity Compound Supersonic Impulse Turbine with the Rotor Overlaps (속도 복합형 초음속 충동형 터빈의 로터 블레이드 오버랩이 성능특성에 미치는 영향)

  • Cho, Jong-Jae;Kim, Kui-Soon;Jeong, Eun-Hwan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.43-48
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    • 2010
  • Present study was conducted numerical analysis for velocity compound supersonic impulse turbine with the rotor overlaps, and the performance characteristics were analyzed through the numerical results. Tip overlap was more effective than hub overlap through the analysis. a case, overlap applied the hub and tip of the rotor, has the largest improvement for the turbine performance in parametric study cases. In case of overlap for the 2nd stage rotor, however, improvement of the turbine performance was not visibly large. Because, power generated in the 2nd stage was 22~23% of whole generated turbine power.

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Effects of newly synthesized benzimidazole derivatives on gastric H^+/K^+$ ATPase

  • Cheon, Hyae-Gyeong;Yum, Eul-Kgun;Kim, Sung-Soo
    • Archives of Pharmacal Research
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    • v.19 no.2
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    • pp.126-131
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    • 1996
  • The effects of various synthetic benzimidazole derivatives on gastric H^+/K^+$ATPase activity in vitro were examined. The results showed that the effects of substituents on the benzimidazole ring were not significant. However, replacement of sulfoxide connecting two ring systems to sulfide resulted in a completely inactive compound in vitro, suggesting the essential role of sulfoxide group in the inhibition. In addition, compounds with 5 or 6-membered oxacyclic substituents attached to the pyridine ring displayed the most effective inhibitory activity. Among these derivatives, AU-47 was the most potent, and detailed mechanistic studies with the compound were carried out. AU-47 inhibited gastricH^+/K^+$ATPase in a concentration and time dependent manner with 50% inhibition at $6\muM$. The presence of sulfhydryl reducing agents or substrate analogue protected H^+/K^+$ATPase from the inactivation. The inhibition by AU-47 was potentiated by acid pretreatment of the compound, suggesting the structural conversion of AU-47 into a more active intermediate which was favored in acidic condition. Consistent with in vitro results, AU-47 inhibited in vivo gastric acid secretion. The results suggest that AU47 is a relevant candidate for the development of new antiulcer agent.

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Modified temporalis tendon transfer extended with periosteum for facial paralysis patients

  • Kwon, Byeong Soo;Sun, Hook;Kim, Jin Woo
    • Archives of Craniofacial Surgery
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    • v.21 no.6
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    • pp.351-356
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    • 2020
  • Background: We have devised a novel surgical method, termed as temporalis muscle tendonperiosteum (T-P) compound surgical method, by modifying pre-existing techniques. Our method is characterized by elevation of temporalis muscle tendon and the periosteum of the mandibular ramus as a single compound. Here, we describe the concept and clinical outcomes of our method. Methods: We conducted both a cadaveric study and a clinical study. First, we used four human cadavers (two males and two females) to confirm the anatomy of the temporalis muscle tendon and availability of sufficient length extension through the elevation of the T-P compound. Moreover, we obtained measurements of the mouth angle and the philtrum angle from a total of six patients (two males and four females) and compared them between preoperatively and postoperatively. Results: The mean length of the periosteal portion was measured as 2.43± 0.15 cm (range, 2.2-2.6 cm). There was an improvement in the mouth angle postoperatively as compared with preoperatively (7.2°± 3.0° vs. 14.5°± 4.7°, respectively). Moreover, there was also an improvement in the philtrum angle postoperatively as compared with preoperatively (7.2°± 3.4° vs. 17.2°± 6.5°, respectively). Conclusion: Our method is a simple, minimally-invasive modality that is effective in achieving good clinical outcomes. Its advantages include an ability to achieve a firm extension of the temporalis muscle tendon as well as a lack of requirement for a donor site that may cause complications.

The Economic Evaluation of the Renewable Energy Projects using the Geske Model (게스케(Geske) 모델을 이용한 신재생에너지사업의 경제성 분석)

  • Jaehun Sim
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.45 no.4
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    • pp.31-41
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    • 2022
  • As the environmental impacts of fossil fuel energy sources increase, the South Korean government has tried to change non-environmental-friendly enery sources to environmental-friendly energy sources in order to mitigate environmental effects, which lead to global warming and air pollution. With both a limited budget and limited time, it is essential to accurately evaluate the economic and environmental effects of renewable energy projects for the efficient and effective operation of renewable energy plants. Although the traditional economic evaluation methods are not ideal for evaluating the economic impacts of renewable energy projects, they can still be used for this purpose. Renewable energy projects involve many risks due to various uncertainties. For this reason, this study utilizes a real option method, the Geske compound model, to evaluate the renewable energy projects on Jeju Island in terms of economic and environmental values. This study has developed an economic evaluation model based on the Geske compound model to investigate the influences of flexibility and uncertainty factors on the evaluation process. This study further conducts a sensitivity analysis to examine how two uncertainty factors (namely, investment cost and wind energy production) influence the economic and environmental value of renewable energy projects.

CAttNet: A Compound Attention Network for Depth Estimation of Light Field Images

  • Dingkang Hua;Qian Zhang;Wan Liao;Bin Wang;Tao Yan
    • Journal of Information Processing Systems
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    • v.19 no.4
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    • pp.483-497
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    • 2023
  • Depth estimation is one of the most complicated and difficult problems to deal with in the light field. In this paper, a compound attention convolutional neural network (CAttNet) is proposed to extract depth maps from light field images. To make more effective use of the sub-aperture images (SAIs) of light field and reduce the redundancy in SAIs, we use a compound attention mechanism to weigh the channel and space of the feature map after extracting the primary features, so it can more efficiently select the required view and the important area within the view. We modified various layers of feature extraction to make it more efficient and useful to extract features without adding parameters. By exploring the characteristics of light field, we increased the network depth and optimized the network structure to reduce the adverse impact of this change. CAttNet can efficiently utilize different SAIs correlations and features to generate a high-quality light field depth map. The experimental results show that CAttNet has advantages in both accuracy and time.

A Study on the Performance Evaluation of Form Using the Aluminum Alloy Frame Reinforced Panel (Aluminum 합금재 Frame을 이용한 벽체거푸집공법의 성능평가에 관한 연구)

  • 안재철;오상균;강병희
    • Journal of the Korea Institute of Building Construction
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    • v.1 no.1
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    • pp.135-142
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    • 2001
  • This study is for the investigation of form using the aluminum-compound metal frame(Aluminum frame reinforced panel : AFR panel) which is improved in the capacity in the wall-concrete structure in steal of using the existing form which has problems such as, excessive exposure of cement, the loss of labor when it is constructed or disjointed, and it's economical efficiency compared with that of EURO Form. AFR panel passes the KS F 8006 test, and as a result of field test, it's displacement is satisfied with Specification. And using AFR panel is more economical than that of EURO Form because saving labor cost which plays a major part in cost saving in formwork is more effective in retrenching total cost than increment of material cost.

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A Study on Natural Dyeing(2) - Dyeing of modified cotton fabric with Amur cork tree - (천연염색에 관한 연구(2) - 개질 면에 대한 황벽염색 -)

  • 김혜인;박수민
    • Textile Coloration and Finishing
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    • v.13 no.3
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    • pp.172-179
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    • 2001
  • In order to improve dye uptime and wash fastness on dyeing of cotton fabrics with Amur cork tree, twitter ionic groups, acid groups, hydrophobic groups or cross linkage were introduced into cotton fabrics. Results obtained were as follows, 1 The optimum modification of cotton fabrics was carbosy methylation in the water solution containing 15% sodium chloroacetate and 15% sodium hydroxide and then introducing hydrophobic groups by treating in the solution containing $30m\ell$ DMSO and $3m\ell$ 2,4-TDI 2. Numbers of carbon, diisocyanate group than monoisocyanate group and aromatic compound than aliphatic compound in introduced hydrophobic groups were effective. 3. The dye uptake and wash fastness wore enhanced significantly by treating only with 2,4-TDI. 4. The wash fastness seems to correlate to the degree of swelling of the fabric during washing and also depend on the Interaction between dyes and acid groups as well as hydrophobic groups.

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A Study on the Synthesis of Dinitramide Salts (디니트라미드 염의 합성)

  • Chung, Kyoo-hyun;Sim, Hyun-ho
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.155-157
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    • 1998
  • Dinitramide salts may be useful as effective solid oxidizers because of higher oxygen content than nitrate salts. 3-Nitramino-propanoate was given by base treatement in the retro-Michael reaction of N-nitro-4-azaheptanedioate, which was prepared by nitration of 4-azaheptanedioate using $HNO_3$-TFAA(trifiluoroacetic anhydride)-$Br_2$. The nitramino compound was treated wile $NO_2BF_4$ to give dinitramino compound which was subsequently reacted with bases to give dinitramide salts.

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