• Title/Summary/Keyword: effect of SDS

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Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer(II) (이산화규소/스티렌 코어-셀 합성에서 음이온 계면활성제의 영향(II))

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.1
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    • pp.74-79
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    • 2009
  • The inorganic-organic composite particles with core-shell structure were polymerized by using styrene and potassium persulfate (KPS) as a shell monomer and an initiator, respectively. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene composite particles polymerized in the presence of sodium dodecyl sulfate(SDS), polyoxyethylene alkylether sulfate (EU-S133D), and at none surfactant condition. We found that $SiO_2$ core / polystyrene(PS) shell structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration SDS and EU-Sl33D was $8.34{\times}10^{-2}mole/L$. The core-shell structure was confirmed by measuring the thermal decomposition of the polymer composite using thermogravimetric analyzer (TGA), and the morphology of the composite particles was characterized by transmission electron microscope (TEM).

Relationship Between Mass Transfer and Degradation of Sorbed Phenanthrene in Goethite Catalyzed Fenton-like Oxidation Using Non-ionic/anionic Surfactant (Phenanthrene 의 goethite 촉매에 의한 Fenton 산화에 있어서 음이온/비이온 계면활성제의 영향)

  • Kim, Jeong-Hwan;Choi, Won-Ho;Kim, Jung-Hwan;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.2B
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    • pp.207-212
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    • 2009
  • Surfactants were used as representative anionic and non ionic surfactants to investigate the effect of mass transfer on the mineral-catalyzed Fenton-like oxidation of sorbed phenanthrene. Mass transfer of phenanthrene on the oxide surface or interlayer between aqueous and solid phases was generated by surfactant addition. Apparent solubility of phenanthrene was increased as surfactant concentration increasesd. In tests using Tween 80, oxidation of phenanthrene decreased as apparent solubility increased. High apparent solubility was not responsible for oxidation of sorbed phenanthrene in the sand due to the surfactant acted as a scavenger of degradation. In tests with SDS, $H_{2}O_{2}$ decomposition rate in Fenton-like oxidation was decreased by complexation between goethite and SDS. However, in tests using 32 mM of SDS, efficiency of phenanthrene treatment increased compared to the test without SDS addition. Therefore, suitable amount of SDS addition could provide optimum condition for phenanthrene oxidation on the oxide surface or interlayer between aqueous and solid phase, and decrease $H_{2}O_{2}$ decomposition, and as a result, phenanthrene removal efficiency can be improved.

Removal of Aqueous Iron Ion by Micellar Enhanced Ceramic Microfiltration Adding Surfactant (계면활성제를 첨가한 미셀 형성 세라믹 정밀여과에 의한 용존 철 이온 제거)

  • Park, Jin Yong;Yu, Byeong Gwon
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.190-194
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    • 2009
  • In this study sodium dodecyl sulfate (SDS), which was anionic surfactant, was added for forming micelles to remove iron ion that could be contained with small amount in industrial water. Then aggregates binding between iron ions and micelles were rejected by a ceramic microfiltration membrane. As result of SDS concentration effect on removal rates of iron and SDS in modified iron solution, the removal rate of iron was the highest value of 92.26% and the removal rate of SDS was 61.10% a little higher than the result of calcium ion at 8 mM which was CMC (Critical micelle concentration) of SDS. As final resistance of membrane fouling $R_f$ increased the more at the higher SDS concentration, it showed the highest value at 4 mM and the lowest at 10 mM of SDS. The final permeate flux $J_{180}$ had the highest value and the largest total permeate volume could be finally acquired at SDS 10 mM. In case of CMC 8 mM, low $R_f$ was shown as same as that of 10 mM until 80 minutes of operation, and tended to increase dramatically to 120 minutes and increase slowly again until 180 minutes.

Studies on the Detergency of Oily Soils (Part II) (유성오염의 세척성에 관한 연구(제2보) -유화와 롤링업에 의한 액체유성오염의 세척성-)

  • 김영희;정두진
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.2
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    • pp.356-365
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    • 1995
  • study was made to investigate the emulsification and rolling-up between liquid oily soils and surfactant and its effect on the detergency. Samples used were triolein as a triglyceride, oleic acid as a free fatty acid and sodium dodecyl sUJfate(SDS) as a surfactant. The results were as follows: 1. The spontaneous emulsification occurred in the system of oleic acid alone and mixture of triolein and oleic acid contacted with 0.5% SDS solution, but it did not occurred in a case of triolein alone. 2. The stability of emulsification increased with the increase of SDS concentration. And the stability of emulsification and (-) t value increased in the order of triolein < mixture of triolein and oleic and< oleic acid. 3. The rolling-up mechanism of model oily soils easily occurred in the order of triolein< mixture of triolein and oleic acid< oleic acid, and facilitated with the increase of SDS concentration. On the other hand, the complex formation was already observed in the system of oleic and 0.5% SDS solution. 4. As compared with the detergency of triolein, the detergency of oleic acid was very high. And the detergency of mixed soil was improved with increasing ratio of oleic acid in the mixture.

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Square Wave Voltammetric Determination of Indole-3-acetic Acid Based on the Enhancement Effect of Anionic Surfactant at the Carbon Paste Electrode

  • Zhang, Sheng-Hui;Wu, Kang-Bing
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1321-1325
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    • 2004
  • Sodium dodecyl sulfate (SDS), an anionic surfactant, can strongly adsorb at the surface of a carbon paste electrode (CPE) via the hydrophobic interaction. In pH 3.0 $Na_2HPO_4$-citric acid buffer (Mcllvaine buffer) and in the presence of SDS, the cationic indole-3-acetic acid (IAA, $pK_a$ = 4.75) was highly accumulated at the CPE surface through the electrostatic interaction between the negative-charged head group of SDS and cationic IAA, compared with that in the absence of SDS. Hence, the oxidation peak current of IAA increases greatly and the oxidation peak potential shifts towards more negative direction. The experimental parameters, such as pH, varieties of surfactants, concentration of SDS, and scan rate were optimized for IAA determination. The oxidation peak current is proportional to the concentration of IAA over the range from $5\;{\times}\;10^{-8}$ mol/L to $2\;{\times}\;10^{-6}$ mol/L. The detection limit is $2\;{\times}\;10^{-8}$ mol/L after 3 min of accumulation. This new voltammetric method was successfully used to detect IAA in some plant leaves.

Establishment of optimal decellularization conditions using porcine placenta

  • Son, Ji Hyung;Kim, Dae-Jung;Lee, Dong-Mok;Seo, Byoung Boo
    • Journal of Animal Reproduction and Biotechnology
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    • v.36 no.4
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    • pp.253-260
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    • 2021
  • Organ transplantation is currently the most fundamental treatment for organ failure, but there is a shortage of organ supply compared to those in need. Regenerative medicine has recently developed a decellularization technique that overcomes the limitations of conventional organ transplantation and attempts to reconstruct damaged tissues or organs to their normal state. Several decellularization methods have been suggested. In this experiment, the decellularization methods were used to find effective decellularization methods for humanlike porcine placenta. The optimal conditions for decellular support are low DNA content and high glycos amino glycans (GAGs) and collagen content. In order to satisfy this condition, SDS and Triton X-100 and SDS + Triton X-100 were used as the detergent used for decellularization in this experiment. The contents were compared according to the decellularization time (0, 12, 24, 48 and 72 hours), and the concentrations of SDS (0.2, 0.5, 0.7 and 1.0%) were mixed in 1.0% Triton X-100 to analyze the contents. When decellularized using SDS and Triton X-100, respectively, it was confirmed that the contents of DNA and GAGs were opposite to each other. And decellularization treatment for 24 hours at 0.5% SDS was able to obtain an effective decellular support. If decellularization studies of various detergents can be obtained an effective decellular support, and furthermore, cell culture experiments can confirm the effect on the cells.

Electrophoretic Mobility to Monitor Protein-Surfacant Interactions

  • Hong, Soon-Taek
    • Preventive Nutrition and Food Science
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    • v.3 no.2
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    • pp.143-151
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    • 1998
  • Protein -surfactant interactions have been investigate by measuring ζ-potential of $\beta$-lactoglobulin-coated emulsion droplets and $\beta$-lactoglobulin in solution in the rpesenceof surfactant, with particular emphasis on the effect of protein heat treatment(7$0^{\circ}C$, 30min). When ionic surfactant (SDS or DATEM) is added to the protein solution, the ζ-potential of the mixture is found to increase with increasing surfactant concentration, indicating surfactant binding to the protein molecules. For heat-denatured protein,it has been observed that the ζ-potential tends to be lower than that of the native protein. The effect of surfactant on emulsions is rather complicated .With SDS, small amounts of surfactant addition induce a sharp increase in zeta potential arising from the specific interaction of surfactant with protein. With further surfacant addition, there is a gradual reductio in the ζ-potential, presumably caused by the displacement of adsorped protein (and protein-surfactant complex) from the emulsion droplet surfac by the excess of SDS molecules. At even higher surfactant concentrations, the measured zeta potential appears to increase slightly, possibly due to the formation of a surfactant measured zeta potential appears to increase slightly, possibly due to the formation of surfactant micellar structure at the oil droplet surface. This behaviour contrastswith the results of the corresponding systems containing the anionic emulsifier DATEM, in which the ζ-potential of the system is found to increase continuously with R, particularly at very low surfactant concentration. Overall, such behaviour is consisten with a combination of complexation and competitive displacement between surfactant and protein occurring at the oil-water interface. In addition, it has also been found that above the CMC, there is a time-dependent increase in the negative ζ-potential of emulsion droplets in solutions of SDS, possibly due to the solublization of oil droplets into surfactant micelles in the aqueous bulk phase.

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Surprisingly, traditional purple bamboo salt, unlike other salts does not induce hypertension in rats

  • Kim, Young-Sick;Lee, Eun-Hee;Kim, Hyung-Min
    • CELLMED
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    • v.3 no.2
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    • pp.16.1-16.5
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    • 2013
  • Hypertension induces many of the social costs related by cardiovascular diseases. Sodium is known as a crucial factor in inducing type I hypertension. In traditional Korean medicine, bamboo salt (BS) has been used in the attenuation of salts toxic coldness and nowadays it has shown various therapeutic effects. It contains mostly sodium chloride (about 91.7% of BS); however, the effect of BS on hypertension is still not completely understood. Thus, we investigated the effect of BS on blood pressure for the first time. Two group of BS, sun-dried salt (SDS), NaCl, or distilled water (DW, vehicle control) was administrated orally for 8 weeks. Although BS had no effect on body weight and food intake, it increased water intake (p < 0.05). The BS groups, in terms of blood pressure, was similar to the DW group; whereas the SDS and NaCl groups showed significantly increased blood pressure levels (p < 0.05). BS also decreased sodium-chloride cotransporter (NCC) mRNA expression, unlike SDS or NaCl. These observations indicate that BS may be a promising strategy for the prevention of various diseases including salt-related diseases.

The Effects of Herb Aroma Components on the Reduction of Depression - Focused on University Students -

  • Lee, Min-Hee;Koh, Jae-Won;ChoJo, Tae-Dong
    • Journal of Environmental Science International
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    • v.20 no.4
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    • pp.435-442
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    • 2011
  • In this study, to investigate the effects of herb aroma components, the BDI test was performed with the 124 students of the Youngdong University and the subjects whose score was 16 or higher were selected and allocated to the herb-extracted aroma-treated group and the non-treated group, 27 and 10 students for each group. The BDI and SDS tests were carried out at each stage (before and after the treatment, 10 days later and 30 days later). The result showed that the pre-treatment BDI test result was significantly different from all those of the post-treatment test, and the tests after 10 days and 30 days in the aroma-treated group. In the SDS test, the pre-treatment test result was significantly different from the results of the post-treatment test and the test after 10 days, while it was not significantly different from the result of the test after 30 days. Additionally, to verify whether the change within the group is larger than that by natural recovery or not, ANCOVA was performed with respect to the difference in the pre-treatment test score between the groups depending on whether the treatment was given or not, having the SDS pre-treatment score as the covariate, and the result showed that the post-treatment test scores were significantly different. Thus, it was verified that, if the SDS test score is considered as the depression indicator, the effect of aromatherapy was greater than the change by natural recovery. The difference in the post-treatment test score was analyzed depending on whether the treatment was given or not, having the BDI pre-treatment test score as the control variable, and the result showed that the post-treatment test scores were not significantly different. Based on such a theoretical verification, it is assumed that the nature-friendly treatment method using herb aroma components can be a great help in suppressing depression. Therefore, it is expected that herb aroma components can provide systematic therapeutic effect on the suppression of depression.

Asynchronous Ranging Method using Estimated Frequency Differences in Wireless Sensor Networks (무선 센서망에서의 주파수 차이 추정 비동기 Ranging 방식)

  • Nam, Yoon-Seok;Huh, Jae-Doo
    • The KIPS Transactions:PartC
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    • v.15C no.1
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    • pp.31-36
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    • 2008
  • The clock frequency difference of sensor nodes is one of main parameters in TOF estimation and affect to degrade ranging algorithms to estimate positions of mobile nodes in wireless sensor networks. The specification of IEEE802.15.4a describes asynchronous TWR and SDS-TWR insensitive to frequency difference without any additional network synchronization. But the TWR and SDS-TWR can not eliminate sufficiently the effect of frequency difference of node pair, packet processing delay and its difference. Especially use of low cost oscillator with wide range offset, sensor node with different hardware and software can make the positioning errors worse. We propose an estimation method of frequency differences, and apply the measured frequency differences to TWR and SDS-TWR. We evaluate the performance of the proposed algorithm with simulation, and make certain that the proposed method enhances the performance of existing algorithms with positioning errors less than 25 cm.