• 제목/요약/키워드: effect of SDS

검색결과 525건 처리시간 0.031초

이산화규소/스티렌 코어-셀 합성에서 음이온 계면활성제의 영향(II) (Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer(II))

  • 박근호
    • 한국응용과학기술학회지
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    • 제26권1호
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    • pp.74-79
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    • 2009
  • The inorganic-organic composite particles with core-shell structure were polymerized by using styrene and potassium persulfate (KPS) as a shell monomer and an initiator, respectively. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene composite particles polymerized in the presence of sodium dodecyl sulfate(SDS), polyoxyethylene alkylether sulfate (EU-S133D), and at none surfactant condition. We found that $SiO_2$ core / polystyrene(PS) shell structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration SDS and EU-Sl33D was $8.34{\times}10^{-2}mole/L$. The core-shell structure was confirmed by measuring the thermal decomposition of the polymer composite using thermogravimetric analyzer (TGA), and the morphology of the composite particles was characterized by transmission electron microscope (TEM).

Phenanthrene 의 goethite 촉매에 의한 Fenton 산화에 있어서 음이온/비이온 계면활성제의 영향 (Relationship Between Mass Transfer and Degradation of Sorbed Phenanthrene in Goethite Catalyzed Fenton-like Oxidation Using Non-ionic/anionic Surfactant)

  • 김정환;최원호;김정환;박주양
    • 대한토목학회논문집
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    • 제29권2B호
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    • pp.207-212
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    • 2009
  • 광물촉매에 의한 Fenton 산화에서 모래에 흡착된 phenanthrene을 대표적인 계면활성제인 SDS와 Tween 80을 사용하여 물질이동 영향을 조사하였다. 계면활성제 주입에 따라 액상과 고체상 사이 또는 산화물 표면으로 phenanthrene이 물질이동하였으며, 계면활성제 농도가 증가할수록 phenanthrene의 apparent solubility는 증가하는 경향을 나타내었다. Tween 80은 apparent solubility가 증가 하더라도, 계면활성제가 분해에 scavenger 작용을 하여 모래에 흡착된 phenanthrene 산화에는 영향을 주지 않았다. SDS를 주입하였을 때, Fenton-like 반응에서 SDS와 goethite가 착물을 형성하여 과산화수소 소모량을 지연시켰의며, 계면활성제를 주입 하지 않았을 때 보다 SDS 32 mM를 주입하였을 때 phenanthrene 처리효율이 증가하였다. 그러므로 최적농도의 SDS 주입은 액상과 고체상 사이 또는 산화물 표면에 phenanthrene 산화를 위한 적당한 조건을 제공 해주며, 과산화수소 소모량을 줄이고, phenanthrene 처리효율을 개선시킬 것이다.

계면활성제를 첨가한 미셀 형성 세라믹 정밀여과에 의한 용존 철 이온 제거 (Removal of Aqueous Iron Ion by Micellar Enhanced Ceramic Microfiltration Adding Surfactant)

  • 박진용;유병권
    • Korean Chemical Engineering Research
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    • 제47권2호
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    • pp.190-194
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    • 2009
  • 본 연구에서는 공업용수 중에 미량 함유될 수 있는 철 이온을 제거하기 위해 음이온 계면활성제 SDS를 주입하여 미셀을 형성한 후, 미셀과 철 이온이 결합된 응집체를 관형 세라믹 정밀여과막으로 배제하였다. 철 모사용액을 대상으로 SDS 농도가 철과 SDS 제거율에 미치는 영향을 알아본 결과, 철의 제거율은 SDS의 임계미셀농도(CMC)인 8.00 mM에서 가장 높은 92.26%를 나타내었고, SDS 제거율은 칼슘 이온 제거 결과보다 다소 높은 61.10%를 보였다. SDS의 농도가 증가함에 따라 최종 막오염에 의한 저항 $R_f$가 증가하여 4 mM일 때 가장 높은 값을 보이다가 10 mM에서 가장 낮은 값을 나타내었다. SDS 10 mM인 조건에서 최종 투과선속 $J_{180}$가 가장 큰 값을 나타냈었고, 결국 가장 높은 총여과부피를 얻을 수 있었다. CMC 8 mM의 경우 운전시간 80분까지는 10 mM과 동일하게 낮은 $R_f$ 값을 보이다가, 120분까지 급격하게 증가하다가 다시 180분까지 서서히 증가하는 경향을 보였다.

유성오염의 세척성에 관한 연구(제2보) -유화와 롤링업에 의한 액체유성오염의 세척성- (Studies on the Detergency of Oily Soils (Part II))

  • 김영희;정두진
    • 한국의류학회지
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    • 제19권2호
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    • pp.356-365
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    • 1995
  • study was made to investigate the emulsification and rolling-up between liquid oily soils and surfactant and its effect on the detergency. Samples used were triolein as a triglyceride, oleic acid as a free fatty acid and sodium dodecyl sUJfate(SDS) as a surfactant. The results were as follows: 1. The spontaneous emulsification occurred in the system of oleic acid alone and mixture of triolein and oleic acid contacted with 0.5% SDS solution, but it did not occurred in a case of triolein alone. 2. The stability of emulsification increased with the increase of SDS concentration. And the stability of emulsification and (-) t value increased in the order of triolein < mixture of triolein and oleic and< oleic acid. 3. The rolling-up mechanism of model oily soils easily occurred in the order of triolein< mixture of triolein and oleic acid< oleic acid, and facilitated with the increase of SDS concentration. On the other hand, the complex formation was already observed in the system of oleic and 0.5% SDS solution. 4. As compared with the detergency of triolein, the detergency of oleic acid was very high. And the detergency of mixed soil was improved with increasing ratio of oleic acid in the mixture.

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Square Wave Voltammetric Determination of Indole-3-acetic Acid Based on the Enhancement Effect of Anionic Surfactant at the Carbon Paste Electrode

  • Zhang, Sheng-Hui;Wu, Kang-Bing
    • Bulletin of the Korean Chemical Society
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    • 제25권9호
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    • pp.1321-1325
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    • 2004
  • Sodium dodecyl sulfate (SDS), an anionic surfactant, can strongly adsorb at the surface of a carbon paste electrode (CPE) via the hydrophobic interaction. In pH 3.0 $Na_2HPO_4$-citric acid buffer (Mcllvaine buffer) and in the presence of SDS, the cationic indole-3-acetic acid (IAA, $pK_a$ = 4.75) was highly accumulated at the CPE surface through the electrostatic interaction between the negative-charged head group of SDS and cationic IAA, compared with that in the absence of SDS. Hence, the oxidation peak current of IAA increases greatly and the oxidation peak potential shifts towards more negative direction. The experimental parameters, such as pH, varieties of surfactants, concentration of SDS, and scan rate were optimized for IAA determination. The oxidation peak current is proportional to the concentration of IAA over the range from $5\;{\times}\;10^{-8}$ mol/L to $2\;{\times}\;10^{-6}$ mol/L. The detection limit is $2\;{\times}\;10^{-8}$ mol/L after 3 min of accumulation. This new voltammetric method was successfully used to detect IAA in some plant leaves.

Establishment of optimal decellularization conditions using porcine placenta

  • Son, Ji Hyung;Kim, Dae-Jung;Lee, Dong-Mok;Seo, Byoung Boo
    • 한국동물생명공학회지
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    • 제36권4호
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    • pp.253-260
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    • 2021
  • Organ transplantation is currently the most fundamental treatment for organ failure, but there is a shortage of organ supply compared to those in need. Regenerative medicine has recently developed a decellularization technique that overcomes the limitations of conventional organ transplantation and attempts to reconstruct damaged tissues or organs to their normal state. Several decellularization methods have been suggested. In this experiment, the decellularization methods were used to find effective decellularization methods for humanlike porcine placenta. The optimal conditions for decellular support are low DNA content and high glycos amino glycans (GAGs) and collagen content. In order to satisfy this condition, SDS and Triton X-100 and SDS + Triton X-100 were used as the detergent used for decellularization in this experiment. The contents were compared according to the decellularization time (0, 12, 24, 48 and 72 hours), and the concentrations of SDS (0.2, 0.5, 0.7 and 1.0%) were mixed in 1.0% Triton X-100 to analyze the contents. When decellularized using SDS and Triton X-100, respectively, it was confirmed that the contents of DNA and GAGs were opposite to each other. And decellularization treatment for 24 hours at 0.5% SDS was able to obtain an effective decellular support. If decellularization studies of various detergents can be obtained an effective decellular support, and furthermore, cell culture experiments can confirm the effect on the cells.

Electrophoretic Mobility to Monitor Protein-Surfacant Interactions

  • Hong, Soon-Taek
    • Preventive Nutrition and Food Science
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    • 제3권2호
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    • pp.143-151
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    • 1998
  • Protein -surfactant interactions have been investigate by measuring ζ-potential of $\beta$-lactoglobulin-coated emulsion droplets and $\beta$-lactoglobulin in solution in the rpesenceof surfactant, with particular emphasis on the effect of protein heat treatment(7$0^{\circ}C$, 30min). When ionic surfactant (SDS or DATEM) is added to the protein solution, the ζ-potential of the mixture is found to increase with increasing surfactant concentration, indicating surfactant binding to the protein molecules. For heat-denatured protein,it has been observed that the ζ-potential tends to be lower than that of the native protein. The effect of surfactant on emulsions is rather complicated .With SDS, small amounts of surfactant addition induce a sharp increase in zeta potential arising from the specific interaction of surfactant with protein. With further surfacant addition, there is a gradual reductio in the ζ-potential, presumably caused by the displacement of adsorped protein (and protein-surfactant complex) from the emulsion droplet surfac by the excess of SDS molecules. At even higher surfactant concentrations, the measured zeta potential appears to increase slightly, possibly due to the formation of a surfactant measured zeta potential appears to increase slightly, possibly due to the formation of surfactant micellar structure at the oil droplet surface. This behaviour contrastswith the results of the corresponding systems containing the anionic emulsifier DATEM, in which the ζ-potential of the system is found to increase continuously with R, particularly at very low surfactant concentration. Overall, such behaviour is consisten with a combination of complexation and competitive displacement between surfactant and protein occurring at the oil-water interface. In addition, it has also been found that above the CMC, there is a time-dependent increase in the negative ζ-potential of emulsion droplets in solutions of SDS, possibly due to the solublization of oil droplets into surfactant micelles in the aqueous bulk phase.

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Surprisingly, traditional purple bamboo salt, unlike other salts does not induce hypertension in rats

  • Kim, Young-Sick;Lee, Eun-Hee;Kim, Hyung-Min
    • 셀메드
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    • 제3권2호
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    • pp.16.1-16.5
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    • 2013
  • Hypertension induces many of the social costs related by cardiovascular diseases. Sodium is known as a crucial factor in inducing type I hypertension. In traditional Korean medicine, bamboo salt (BS) has been used in the attenuation of salts toxic coldness and nowadays it has shown various therapeutic effects. It contains mostly sodium chloride (about 91.7% of BS); however, the effect of BS on hypertension is still not completely understood. Thus, we investigated the effect of BS on blood pressure for the first time. Two group of BS, sun-dried salt (SDS), NaCl, or distilled water (DW, vehicle control) was administrated orally for 8 weeks. Although BS had no effect on body weight and food intake, it increased water intake (p < 0.05). The BS groups, in terms of blood pressure, was similar to the DW group; whereas the SDS and NaCl groups showed significantly increased blood pressure levels (p < 0.05). BS also decreased sodium-chloride cotransporter (NCC) mRNA expression, unlike SDS or NaCl. These observations indicate that BS may be a promising strategy for the prevention of various diseases including salt-related diseases.

The Effects of Herb Aroma Components on the Reduction of Depression - Focused on University Students -

  • Lee, Min-Hee;Koh, Jae-Won;ChoJo, Tae-Dong
    • 한국환경과학회지
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    • 제20권4호
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    • pp.435-442
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    • 2011
  • In this study, to investigate the effects of herb aroma components, the BDI test was performed with the 124 students of the Youngdong University and the subjects whose score was 16 or higher were selected and allocated to the herb-extracted aroma-treated group and the non-treated group, 27 and 10 students for each group. The BDI and SDS tests were carried out at each stage (before and after the treatment, 10 days later and 30 days later). The result showed that the pre-treatment BDI test result was significantly different from all those of the post-treatment test, and the tests after 10 days and 30 days in the aroma-treated group. In the SDS test, the pre-treatment test result was significantly different from the results of the post-treatment test and the test after 10 days, while it was not significantly different from the result of the test after 30 days. Additionally, to verify whether the change within the group is larger than that by natural recovery or not, ANCOVA was performed with respect to the difference in the pre-treatment test score between the groups depending on whether the treatment was given or not, having the SDS pre-treatment score as the covariate, and the result showed that the post-treatment test scores were significantly different. Thus, it was verified that, if the SDS test score is considered as the depression indicator, the effect of aromatherapy was greater than the change by natural recovery. The difference in the post-treatment test score was analyzed depending on whether the treatment was given or not, having the BDI pre-treatment test score as the control variable, and the result showed that the post-treatment test scores were not significantly different. Based on such a theoretical verification, it is assumed that the nature-friendly treatment method using herb aroma components can be a great help in suppressing depression. Therefore, it is expected that herb aroma components can provide systematic therapeutic effect on the suppression of depression.

무선 센서망에서의 주파수 차이 추정 비동기 Ranging 방식 (Asynchronous Ranging Method using Estimated Frequency Differences in Wireless Sensor Networks)

  • 남윤석;허재두
    • 정보처리학회논문지C
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    • 제15C권1호
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    • pp.31-36
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    • 2008
  • 무선 센서망에서 이동노드의 위치를 추정하는데 센서노드의 클럭주파수 차이는 TOF 추정에 중요한 파라메타이며, 이동노드와 고정노드 간의 거리 추정에 크게 영향을 미친다. IEEE802.15.4a에서는 별도의 유선 등에 의한 망동기 공급이 없는 상태에서도 주파수 차이에 둔감한 비동기 TWR 및 SDS-TWR 거리 추정 방식을 제안하고 있다. 그러나 제안된 비동기 TWR 및 SDS-TWR 방식은 여전히 노드 쌍에 따른 주파수 차이, 프레임 처리 시간, 프레임 처리 시간 차이 등에 의한 영향을 충분히 제거하지 못하고 있다. 특히 주파수 차이가 큰 저가의 발진기 사용, 서로 다른 하드웨어 및 소프트웨어에서 동작하는 센서노드는 더 큰 위치추정 오류를 유발할 수 있다. 본 논문은 주파수 차이를 추정하는 방식을 제안하고, 기존의 TWR 및 SDS-TWR 방식에 적용하였다. 시뮬레이션을 통하여 주파수 차이 추정을 적용한 제안된 방식은 주파수 차이의 영향을 감소시켜 TWR 및 SDS-TWR 등의 성능을 개선시켰으며, 25cm 이하의 위치오류가 발생하는 것을 확인하였다.