• Title/Summary/Keyword: eco-friendly composites

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Effect of Grafted Biobased Acrylics on the Mechanical Properties of Polylactic Acid (PLA)/Starch Eco-Friendly Composite

  • Marcela, Godoy;Jonghwan, Suhr
    • Composites Research
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    • v.35 no.6
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    • pp.419-424
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    • 2022
  • Using non-biodegradable polymers is a severe environmental problem as they are not recyclable and generate a large amount of waste. Biopolymers, such as starch-based composites, have been considered one of the most promising replacement materials. These eco-friendly materials have the advantage of being low-cost, biodegradable, and obtained from renewable sources. However, as starch tends to be brittle and hydrophilic, it can make these materials unusable when exposed to water and limit its processability for further applications. In this work, a biobased modified starch was grafted using two bioderived materials, lauryl methacrylate (LMA) and tetrahydrofurfuryl methacrylate (THFMA), by radical polymerization. A polylactic acid (PLA) composite based on the modified starch (m-St) was fabricated to enhance its toughness. These samples were characterized by Fourier transform infrared, 1H NMR and 13C NMR analysis, optical and scanning electron microscopy. The starch was successfully grafted, thus improving the compatibility with the PLA matrix. The mechanical properties of these films were also studied. Results from mechanical tests showed a slight enhancement of the mechanical performance of these composites when m-St was added to the PLA matrix. Such behavior is related to the improved dispersion of m-St 1:2 on PLA, confirmed by SEM images showing enhanced compatibility between modified starch and PLA matrix. This indicated excellent properties of the produced composite film for further eco-friendly applications.

Eco-friendly ductile cementitious composites (EDCC) technique for seismic upgrading of unreinforced masonry (URM) infill walls: A review of literature

  • Haider Ali, Abbas;Naida, Ademovic;Husain K., Jarallah
    • Earthquakes and Structures
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    • v.23 no.6
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    • pp.527-534
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    • 2022
  • EDCC (Eco-Friendly Ductile Cementitious Composites) is a recently created class of engineered cementitious composites that exhibit extremely high ductility and elastoplastic behavior under pure tension. EDCC contains reduced amounts of cement and very large volumes of fly ash. Due to these properties, EDCC has become one of the solutions to use in seismic upgrading. This paper discloses previous studies and research that discussed the seismic upgrading of unreinforced, non-grouted, unconfined, and non-load bearing masonry walls which are called URM infill walls using the EDCC technique. URM infill wall is one of the weak links in the building structure to withstand the earthquake waves, as the brittle behavior of the URM infill walls behaves poorly during seismic events. The purpose of this study is to fill a knowledge gap about the theoretical and experimental ways to use the EDCC in URM infill walls. The findings reflect the ability of the EDCC to change the behavior from brittle to ductile to a certain percentage behavior, increasing the overall drift before collapse as it increases the energy dissipation, and resists significant shaking under extensive levels with various types and intensities.

Recent Developments in Natural Fiber Reinforced Composites (천연섬유보강 복합재료의 최근 연구 개발)

  • Mirza, Foisal Ahmed;Afsar, Ali Md.;Kim, Byung-Sun;Song, Jong-Il
    • Composites Research
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    • v.22 no.4
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    • pp.41-49
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    • 2009
  • Natural fiber reinforced composites are emerging as low-cost, lightweight, recyclable, and eco-friendly materials. These are biodegradable and non-abrasive. Due to eco-friendly and biodegradable characteristics of natural fibers, they are being considered as potential candidates to replace the conventional fibers. The chemical, mechanical, and physical properties of natural fibers have distinct features depending upon the cellulose content of the fibers which varies from fiber to fiber. The mechanical properties of composites are influenced mainly by the adhesion between matrix and fibers. Several chemical and physical modification methods of fiber surface were incorporated to improve the tiber-matrix adhesion resulting in the enhancement of mechanical properties of the composites. This paper outlines the works reported on natural tiber reinforced composites with special reference to the type of fibers, polymer matrix, processing techniques, treatment of fibers, and fiber-matrix interface.

Predicting ESP and HNT effects on the mechanical properties of eco-friendly composites subjected to micro-indentation test

  • Saeed Kamarian;Ali Khalvandi;Thanh Mai Nguyen Tran;Reza Barbaz-Isfahani;Saeed Saber-Samandari;Jung-Il Song
    • Advances in nano research
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    • v.15 no.4
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    • pp.315-328
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    • 2023
  • The main goal of the present study was to assess the effects of eggshell powder (ESP) and halloysite nanotubes (HNTs) on the mechanical properties of abaca fiber (AF)-reinforced natural composites. For this purpose, a limited number of indentation tests were first performed on the AF/polypropylene (PP) composites for different HNT and ESP loadings (0 wt.% ~ 6 wt.%), load amplitudes (150, 200, and 250 N), and two types of indenters (Vickers or conical). The Young's modulus, hardness and plasticity index of each specimen were calculated using the indentation test results and Oliver-Pharr method. The accuracy of the experimental results was confirmed by comparing the values of the Young's modulus obtained from the indentation test with the results of the conventional tensile test. Then, a feed-forward shallow artificial neural network (ANN) with high efficiency was trained based on the obtained experimental data. The trained ANN could properly predict the variations of the mentioned mechanical properties of AF/PP composites incorporated with different HNT and ESP loadings. Furthermore, the trained ANN demonstrated that HNTs increase the elastic modulus and hardness of the composite, while the incorporation of ESP reduces these properties. For instance, the Young's modulus of composites incorporated with 3 wt.% of ESP decreased by 30.7% compared with the pure composite, while increasing the weight fraction of ESP up to 6% decreased the Young's modulus by 34.8%. Moreover, the trained ANN indicated that HNTs have a more significant effect on reducing the plasticity index than ESP.

Investigation of the Effect of Seaweed Nanofibers in Jute Fiber-reinforced Composites as an Additive (해초 나노섬유가 황마섬유 강화 복합재료의 기계적 물성에 미치는 영향)

  • Kim, Jae-Cheol;Lee, Dong-Woo;Song, Jung-Il
    • Composites Research
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    • v.31 no.6
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    • pp.398-403
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    • 2018
  • Recently, environmental pollution caused by plastic waste, ecosystem disturbance of micro-plastics and human body accumulation are becoming big problems. In order to replace the traditional plastic, eco-friendly resin and natural fiber-based composite materials have been developed, but they have a disadvantage that their mechanical properties are significantly lower than those of synthetic fiber-based composites. In this study, eco - friendly nanofiber was extracted from seaweed and used as an additive in order to improve the mechanical properties of jute fiber-reinforced composites. Through the hand lay-up process, the composites were fabricated, and it was confirmed that the nanofiber was effective in improving the mechanical properties of natural fiber composites through tensile, bending and drop weight impact tests.

Structural Test Analysis Study for Manufacturing of Flax Fiber Composite Blades for 30kW Wind Turbines (30kW 풍력터빈용 아마섬유 복합재 블레이드 제조를 위한 구조 시험 분석 연구)

  • Hye-Jin Shin;Ji-Hyun Lee;Sung-Young Moon;Jounghwan Lee
    • Composites Research
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    • v.36 no.1
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    • pp.32-36
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    • 2023
  • Recently, as global environmental issues for sustainable development, such as carbon neutrality, have emerged, disposal methods of glass fiber composites, a material of existing wind turbines, have become a problem. To solve this problem, in this study, 30kW wind turbine blades were manufactured using flax fiber-based composites, which are eco-friendly natural fiber composites that can replace existing glass fiber composites, and their suitability was evaluated. First, mechanical strength tests were conducted to verify the feasibility of using eco-friendly natural flax fiber composites as a wind turbine blade material, and as a result, better strength were confirmed compared to previous studies on the properties of flax fiber composites. In addition, the suitability was confirmed through a static strength performance evaluation test to measure the static strength of the flax fiber composite blade using the manufactured 30kW class flax fiber composite blade.

Development of Eco-friendly Basalt Fiber-reinforced Furan-based Composite Material with Improved Fire and Flame Retardants for Shipbuilding and Offshore Pipe Insulation Cover (조선해양 파이프 단열재 커버 적용을 위한 내화/난연 성능을 갖는 친환경 바잘트섬유 강화 퓨란계 복합재료 개발 연구)

  • Kwon, Dong-Jun;Seo, Hyoung-Seock
    • Composites Research
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    • v.34 no.1
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    • pp.57-62
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    • 2021
  • As interest in the eco-friendly ships and lightweight equipment is increasing in the shipbuilding and marine industry, composite materials are applied to equipment such as pipes. In this study, a basalt fiber reinforced furan composite (BFC), an eco-friendly material, was manufactured to apply the pipe insulation cover that requires environment-friendly and heat/flame retardant performance. An optimization study of post-curing conditions of BFC was conducted, and experiments and analysis were performed on mechanical strength, heat/flame retardant properties, and affinity properties. Finally, as a result of the study BFC material is proved to be a good candidate to apply pipe insulation cover.

AC Electrical and Mechanical Properties of Epoxy-Nano-Microsilica Mixed Composites for Eco-Friendly GIS Spacer (친환경 GIS Spacer용, 에폭시-나노-마이크로실리카 혼합 콤포지트의 교류 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.9
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    • pp.1181-1188
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    • 2018
  • In order to develop new insulating materials for GIS Spacer using environmentally friendly insulating gas, three kinds of dispersed liquid nano composites of solid epoxy /nano layered silicate filled material were prepared. And the epoxy/nano/micro silica composite was prepared by mixing epoxy/nano 3 phr dispersion/4 kinds of filler contents(40,50,60, 70wt%). The electrical insulation breakdown strengths of the nano and nano/micro mixed composites were evaluated by using 8 kinds of samples including the original epoxy. The mechanical tensile strength of the epoxy / nano / micro silica composite were evaluated, also. The TEM was measured to evaluate the internal structure of nano/micro composites. As a result, it was confirmed that the layered silicate nano particles was exfoliated through the process of inserting epoxy resin between silicate layers and the layers. In addition, dispersion of nano / micro silica resulted in improvement of electrical insulation breakdown strength with increase of filling amount of dense tissue with nanoparticles inserted between microparticles. In addition, the tensile strength showed a similar tendency, and as the content of microsilica filler increased, the mechanical improvement was further increased.

A Study on the Preparation of the Eco-friendly Carbon Fibers-Reinforced Composites

  • Choi, Kyeong-Eun;Seo, Min-Kang
    • Carbon letters
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    • v.14 no.1
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    • pp.58-61
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    • 2013
  • In this work, the effect of catalysts on the mechanical properties of carbon fibers-reinforced epoxy matrix composites cured by cationic latent thermal catalysts, i.e., N-benzylpyrazinium hexafluoroantimonate (BPH) was studied. Differential scanning calorimetry was executed for thermal characterization of the epoxy matrix system. Mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and specific fracture energy ($G_{IC}$). As a result, the conversion of neat epoxy matrix cured by BPH was higher than that of one cured by diaminodiphenyl methane (DDM). The ILSS, $K_{IC}$, $G_{IC}$, and impact strength of the composites cured by BPH were also superior to those of the composites cured by DDM. This was probably the consequence of the effect of the substituted benzene group of BPH catalyst, resulting in an increase in the cross-link density and structural stability of the composites studied.