• Title/Summary/Keyword: dynamic capacity

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Determination of Cadmium(II) and Copper(II) by Flame Atomic Absorption Spectrometry after Preconcentration on Column with Pulverized Amberlite XAD-4 with Bismuthiol I

  • Park, Dong-Seok;Choi, Hee-Seon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1375-1382
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    • 2007
  • A column preconcentration method with pulverized Amberlite XAD-4 loaded with bismuthiol I (BI) has been developed for the determination of trace Cd(II) and Cu(II) in various real samples by flame atomic absorption spectrophotometry. Various experimental conditions, such as the size of XAD-4, adsorption flow rate, amount of bismuthiol I, stirring time for adsorbing bismuthiol I on XAD-4, pH of sample solution, amount of XAD-4- BI, desorption solvent, and desorption flow rate, were optimized. Also, the adsorption capacity and the adsorption rate of Cd(II) and Cu(II) on XAD-4-BI were investigated. The interfering effects of various concomitant ions were investigated, Bi(III), Sn(II) and Fe(III) were found to affect the determination. But the interference by these ions was completely eliminated by adjusting the amount of XAD-4-BI resin to 0.70 g, although the adsorption flow rate was slower. For Cd(II) our proposed technique obtained a dynamic range of 0.5-40 ng mL-1, a correlation coefficient (R2) of 0.9913, and a detection limit of 0.3 ng mL-1. For Cu(II), the corresponding values were 2.0-120 ng mL-1, 0.9921 and 1.02 ng mL-1. To validate this proposed technique, the aqueous samples (stream water, reservoir water, tap water and wastewater), the diluted brass sample and the plastic sample, as real samples, were used. Recovery yields of 91-103% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. Our proposed method was also validated using rice flour CRM (normal, fortified) samples. From the results of our experiment, we found that the technique we present here can be applied to the determination of Cd(II) and Cu(II) in various real samples.

Parametric Study on Reinforced Concrete Columns under Blast Load (주철근의 개수 및 단면비에 따른 폭발하중을 받는 철근콘크리트 기둥의 해석적 연구)

  • Choi, Hosoon;Kim, Min-Sook;Lee, Young-Hak
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.25 no.3
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    • pp.219-226
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    • 2012
  • Columns are the key elements supporting load in structure. Column failure causes the structure to collapse. It is important to evaluate residual strength for damaged columns under blast load for preventing progressive collapse. In this paper, columns were investigated to compare the blast resistance on the change of the number of steel bars within the range of reinforcement ratio. And this study was carried out 4 different analytical models to evaluate effects of aspect ratio. The results indicate that the vertical strain was unaffected by the number of steel bars and aspect ratio. As the number of steel bars facing blast load increase, the blast resisting capacity of the columns was improved in the lateral strain. Also, the analysis results showed that a large moment of inertia of area, as compared to a small one would be superior in residual strength as well as force of restitution.

Control of Gaseous Styrene Using a Bioactive Foam Reactor (계면활성제 미생물반응기를 이용한 기체상 스타이렌 제어)

  • Shin, Shoung-Kyu;Song, Ji-Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.7
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    • pp.770-775
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    • 2006
  • Biofilters packed with various materials commonly show problems such as low performance and clogging in a long-term operation. Recently, a bioactive foam reactor(BFR) using surfactants has been suggested to ensure efficient and stable VOCs removal performance. This study was mainly conducted to investigate the feasibility of the BFR system using styrene as a model compound. An abiotic md a biotic tests were conducted to estimate a mass transfer coefficient($K_La$) and a specific substrate utilization coefficient(k) for the BFR, showing the rate of mass transfer was greater in the BFR than in other diffuser systems. A dynamic loading test also indicated that the performance of the BFR was stable under a shock loading condition. Furthermore, the maximum elimination capacity of the BFR was determined to be 109 $g/m^3/hr$ for styrene, which was much higher than those for biofilter systems generally reported in the literature. Overall, the experimental results suggest that the BFR be a potential alternative to the conventional packed-bed biofilters.

An Analytical Study on Evaluation of Opening Performance of Steam Safety Valve for Nuclear Power Plant (원자력 증기용 안전밸브의 개방성능 평가를 위한 해석적 연구)

  • Sohn, Sangho
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.1
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    • pp.5-11
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    • 2014
  • The purpose of this paper is to investigate an analytical approach for opening performance evaluation of the nuclear pressure safety valve based on standard codes such as ASME or KEPIC. It is well-known that safety valve is considered as one of pressure relief valves for protecting a boiler or pressure vessel from exceeding the maximum allowable working pressure. When pressure in a container reaches its set pressure, the safety valve commences discharging the internal fluid by a sudden opening called as popping. Safety valve is usually evaluated by set pressure, full open, blow-down, leakage and flow capacity. The test procedure and technical requirement for performance evaluation is described in international code of ASME code such as BPVC. The opening characteristics of steam safety valve can be analyzed by computational fluid dynamics (CFD) and steam shaft dynamics. First, the flow analysis along opening process is simulated by running the CFD models of the ten types of opening steps from 0 to 100%. As a analysis result, the various CFD outputs of flow pattern, pressure, forces on the disc and mass flow at each simulation step is demonstrated. The lift force is calculated by using the forces applied on disc from static pressure and secondary flow. And, the effect of huddle chamber or control chamber is studied by dynamic analysis based on CFD simulation results such as lift force. As a result, dynamics analysis shows opening features according to the sizes of control chamber.

Seismic Performance Evaluation of Building Structures Based on the Adaptive Lateral Load Distribution (적응적 횡하중 분배방법을 이용한 건축구조물의 내진성능평가)

  • 이동근;최원호;정명채
    • Journal of the Earthquake Engineering Society of Korea
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    • v.8 no.1
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    • pp.39-58
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    • 2004
  • It is very important that predict the inelastic seismic behavior exactly for seismic performance evaluation of a building in the performance based seismic design. Evaluation method of seismic performance based on the pushover analysis reflected in PBSE was developed by some researchers. For the evaluation of inelastic global and local seismic responses by pushover analysis exactly. lateral load distribution should be adjusted and reflected the dynamic characteristics of structural system and various seismic ground motions. And performance point should be determined based on the evaluation of reasonable deformation capacity of a building more exactly. An effective method based on the improved the adaptive lateral load distribution and the equivalent responses of a multistory building is proposed in this study to efficiently estimate the accurate inelastic seismic responses. The proposed method can be used to evaluate the seismic performance for the global inelastic behavior of a building and to accurately estimate its local inelastic seismic responses. In order to demonstrate the accuracy and validity of this method, inelastic seismic responses estimated by the proposed method are compared with those obtained from other analytical methods.

Collapse Probability of a Low-rise Piloti-type Building Considering Domestic Seismic Hazard (국내 지진재해도를 고려한 저층 필로티 건물의 붕괴 확률)

  • Kim, Dae-Hwan;Kim, Taewan;Chu, Yurim
    • Journal of the Earthquake Engineering Society of Korea
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    • v.20 no.7_spc
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    • pp.485-494
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    • 2016
  • The risk-based assessment, also called time-based assessment of structure is usually performed to provide seismic risk evaluation of a target structure for its entire life-cycle, e.g. 50 years. The prediction of collapse probability is the estimator in the risk-based assessment. While the risk-based assessment is the key in the performance-based earthquake engineering, its application is very limited because this evaluation method is very expensive in terms of simulation and computational efforts. So the evaluation database for many archetype structures usually serve as representative of the specific system. However, there is no such an assessment performed for building stocks in Korea. Consequently, the performance objective of current building code, KBC is not clear at least in a quantitative way. This shortcoming gives an unresolved issue to insurance industry, socio-economic impact, seismic safety policy in national and local governments. In this study, we evaluate the comprehensive seismic performance of an low-rise residential buildings with discontinuous structural walls, so called piloti-type structure which is commonly found in low-rise domestic building stocks. The collapse probability is obtained using the risk integral of a conditioned collapse capacity function and regression of current hazard curve. Based on this approach it is expected to provide a robust tool to seismic safety policy as well as seismic risk analysis such as Probable Maximum Loss (PML) commonly used in the insurance industry.

Dynamic Resistance of Anchor using Blasting Test and Numerical analysis for Earthquake (발파실험과 내진해석을 통한 Anchor의 동적 저항성에 관한 연구)

  • Choi, Kyung-Jip;Cho, Kook-Hwan
    • Journal of the Korean Society for Railway
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    • v.20 no.4
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    • pp.500-511
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    • 2017
  • Recently, as earthquakes have occurred in Gyeongju, interest in the stability of structures against vibration from earthquakes has increased. In Korea, the capacity of load resistance is mainly considered in the design of anchors. However, the vibration resistance characteristics of anchors have not been fully elucidated. The traditional type of anchor, which is a frictional resistance anchor, is often reported to fail due to vibration in construction procedures, such as blasting. The expansion type of anchor, on the other hand, could have more resistance to vibration but its capability of demonstrating vibratory resistance has to be investigated. In order to verify the vibratory resistance characteristics of expansion anchors against blasting and earthquake vibration, field tests and numerical analyses for seismic wave were performed. Field blasting test results show that the expansion anchor has better capability against vibratory load than does the frictional type anchor. Numerical analysis to earthquake also show that the expansion type anchor provides more resistance than does the frictional type anchor.

A Model of Context Awareness and Integration for Users Situation Awareness in Mobile P2P Environment (모바일 P2P 환경에서 사용자 상황 인식을 위한 컨텍스트 인식 및 통합 모델)

  • Yoon, Hyo-Gun;Lee, Sang-Yong
    • Journal of the Korean Institute of Intelligent Systems
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    • v.17 no.3
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    • pp.304-309
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    • 2007
  • What is important in ubiquitous computing is collecting users' context information from various sensors and providing services suitable for use's current situation. Particularly in mobile environment, each area has different context awareness structure and this makes it difficult to share information with other areas. As a result, context resources for recognizing users' context ate insufficient. Moreover, because mobile devices have a limited processing capacity, there are difficulties in the real time analysis of users' context. This paper proposed a context awareness and integration model for analyzing users' context actively and providing adaptive services using mobile devices. The proposed model distinguishes users' context between dynamic and static structure to analyze the context, and obtains context resources by sharing context information of users within an area.

Sampling Efficiency of Organic Vapor Passive Samplers by Diffusive Length (확산길이에 따른 수동식 유기용제 시료채취기의 시료채취성능에 관한 연구)

  • Lee, Byung-Kyu;Jang, Jae-Kil;Jeong, Jee-Yeon
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.500-509
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    • 2009
  • Passive samplers have been used for many years for the sampling of organic vapors in work environment atmospheres. Currently, all passive samplers used in domestic occupational monitoring are foreign products. This study was performed to evaluate variable parameters for the development of passive organic samplers, which include the geometry of the device and diffusive length for the sampler design. Four prototype diffusive lengths; A-1(4.5 mm), A-2(7.0 mm), A-3(9.5 mm), A-4(12.0 mm) were tested for adsorption performances to a chemical mixture (benzene, toluene, trichloroethylene, and n-hexane) according to the US-OSHA's evaluation protocol. A dynamic vapor exposure chamber developed and verified by related research was used for this study. The results of study are as follows. The results in terms of sampling rate and recommended sampling time test indicate that the most suitable model was A-3 (9.5 mm diffusive lengths on both sides) for passive sampler design in time weighted average (TWA) assessment. Sampling rates of this A-3 model were 45.8, 41.5, 41.4, and 40.3 ml/min for benzene, toluene, trichloroethylene, and n-hexane, respectively. The A-3 models were tested on reverse diffusion and conditions of low humidity air (35% RH) and low concentrations (0.2 times of TLV). These conditions had no affect on the diffusion capacity of samplers. In conclusion, the most suitable design parameters of passive sampler are: 1) Geometry and structure - 25 mm diameter and 490 $mm^2$ cross sectional area of diffusion face with cylindrical form of two-sided opposite diffusion direction; 2) Diffusive length - 9.5 mm in both faces; 3) Amount of adsorbent - 300 mg of coconut shell charcoal; 4) Wind screen - using nylon net filters (11 ${\mu}m$ pore size).

Development of FBG Accelerometer for Railway Tunnel Vibration (철도터널 진동 모니터링을 위한 광섬유 가속도계 개발)

  • Lee, Su-Hyung;Shin, Min-Ho;Kim, Hyun-Ki;Lee, Kyu-Wan
    • Journal of the Korean Society for Railway
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    • v.14 no.4
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    • pp.364-369
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    • 2011
  • For the safety management of tunnel, effective measurements should be continuously carried out. Most of sensors currently being applied for tunnels measure only the local status, thus many of them are needed to monitor an entire tunnel. For the railway tunnel where trains of same conditions are regularly operated, dynamic responses of tunnel structure to train operations can be a good index to estimate the deformation of tunnel structure in wide area. Meanwhile, the electromagnetic interference caused by overhead centenary in railway tunnel obstructs the use of electric-based sensors. In this study a brand new accelerometer using FBG optical fiber sensors is developed to solve these problems. Sensitivity and capacity of the accelerometer are enhanced with effective structural design of its components and verified with laboratory tests. A case history where the developed accelerometers were applied to a safety monitoring system of a high-speed train tunnel is presented. The performances of the developed accelerometers are validated from the measured acceleration data.