• 대한가정학회지
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• 제39권4호
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• pp.49-59
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• 2001

Natural red and yellow dyestuff was extracted from safflower (Carthamus tinctorius Linnaeus) by a new process of cellulase extraction compared with the conventional hot water extraction. Dyestuffs were extracted from safflower easily and repeatedly by means of cellulose as safflower cell wall destroyer. It means that new dyestuff extraction by cellulase improves not only yields of dyestuff from safflower successfully but also the rate of repetition of extraction. From the above experiments, the conclusions of this study were summarized as follows. 1. The optimum conditions of dyestuff extraction from safflower by general extraction method were that the solvent was the water of pH 6.0 on yellow dyestuff and 3% $K_2CO_3$ solution on red dyestuff, extraction temperature was $55^{\circ}C$, and extraction time was 30 min. 2. Among various cellulase, the NOVO cellulase was the best cell wall destroyer of safflower and finally produced the largest amount of dyestuff from safflower by cellulase extraction method. 3. The optimum conditions of dyestuff extraction by cellulase extraction method were conducted on 10 unit of cellulase per gram of safflower at $100m{\ell}$ water of pH 5.0 at $50^{\circ}C$ for 30 min.

• 약학회지
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• 제3권1호
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• pp.26-34
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• 1957

The solar evaporation method is one of the most important and popular salt manufecturing method in Korea. The rate of evaporation of sea water depends on a complex climate factors. Of these factors, the most important is solar radiation and in particular the extent to which it is absorbed in the brine. By the addition of suitable dyestuff, a further increase in absorption is obtained and can result in all the radiation entering the brine being made available as heat. "Solivap Green", one of several dyestuffs which have been suggested for accelerating solar evaporation, was tested in this experiment. The results of the experiment. 1. Increase the evaporation rate of brine up to 20-25%. 2. Elevate the temperature of brine 2-$4^{\circ}C$. higher than that of brine adding no dyestuff. 3. Optimum dyestuff concentration is 25-30 mg/L and allowable maximum concentration can not exceeded 1000 mg/$m^2$ (50 mg/L). 4. Addition of dyestuff does not cause the degradation of salt produced. 5. A conversion table which indicates the concentrations for various depths of brine was prepared for engineering purpose. 6. Absorption spectrum of the dyestuff was studies, but toxicological and structural studies for the dyestuff have not been done in this experiment.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2004년도 춘계학술발표회 논문집
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• pp.199-203
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• 2004

The azo red pigments for textile printing containing amino-N-substituted benzamide derivatives as diazo components and 2-hydroxy-3-naphthoyl derivatives as coupling components were prepared. They have been printed on cotton, and the fastness, such as light, washing, dry cleaning, rubbing and heat stability was estimated. The new azo red pigments were valuable colorants in case of textile printing.

• 공업화학
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• 제33권6호
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• pp.606-612
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• 2022

수용액에서 수용성 염료를 소수성 염료로 전환시킨 후 마이크로 버블을 이용한 침전 및 부상응집에 의한 염료를 제거하는 연구를 수행하였다. 양이온성 염료에 음이온 collector를 반응시키며, 또한 음이온성 염료에 양이온 collector를 첨가하여 소수성으로 변환시켰다. 소수성으로 전환된 염료 용액을 회분식 반응기에 저장하여 마이크로 버블을 분사시켜 색을 제거하였다. 염료 용액을 제조하기 위해 Basic Yellow 1 및 Direct Orange 10을 사용하였으며, sodium dodecyl sulfate, oleic acid sodium salt 및 amine류와 같은 음이온 및 양이온 collector를 사용하면 색 제거에 효과적이었으며, 모든 색은 8분 이내에 제거되었다. 색 제거는 collector의 첨가량과 수용액 pH의 영향을 받으며, 염료농도에 비해 극히 소량의 계면활성제를 첨가하였을 경우에는 pH에 의존하였으나, 염료농도와 비슷한 collector 양을 첨가하였을 경우에는 pH에 의존하지 않았음을 알 수 있었다. 그 이유는 collector와 염료가 1:1M로 반응하여 소수성이 완전히 부여되어야 제거됨을 알 수 있었다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2004년도 추계학술발표회 논문집
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• pp.274-275
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• 2004

The majority of dyes belong to the chromophoric class known as donor-acceptor systems, the essential structural feature of such systems being the presence of one or more electron donating groups conjugated to one or more electron withdrawing groups via an unsaturated bridge. The indigo molecule may be formally divided into two identical electron donor/acceptor subsystems, each containing an add number of pi electrons, two subsystems being joined by carbon-carbon double bond. Indigoid type dyes which show a strong colour change on protonation or dissociation have many potential functional applications, for example as analytical pH indicators, solvent polarity indicators, and in various imaging and reprographic systems.

• 한국의류산업학회지
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• 제15권3호
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• pp.467-476
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• 2013

This study investigates the dyeability and the fastness of flame retardant polyester fabric developed by a thermal bonding with a low melting component of flame retardant bicomponent filament (LMFRPC). The fabrics were prepared with flame retardant polyester filaments (FRP) as warp and blended filaments of FRP and LMFRPC as weft. The LMFRPC have a sheath and a core where the core comprises a flame retardant polyester and the sheath comprises a thermoplastic polyester with a low-melting point. The thermal bonding of fabric was conducted in a pin tenter at $170^{\circ}C$ for 60 seconds. Fabric dyeing was conducted with an infrared dyeing machine at various dyeing temperatures and dyeing times. The dyestuffs used in this study were CI disperse Yellow 54, Red 60 and Blue 56 of E-type dyestuff and Orange 30, Red 167 and Blue 79 of S-type dyestuff. This study investigated the morphology of thermal bonded fabric, dyeability and fastness of dyed fabric. Dyeability increased with an increased dyeing temperature. The thermal bonded area increased with the increased LMFRPC content. The dyeability of S-type dyestuff was higher than E-type dyestuff; in addition, the saturated dyeing time was about 20minutes at $130^{\circ}C$ for E and S-type dyestuff. The fastness to washing and rubbing were excellent at a 4-5 Grade.

• 한국패션뷰티학회지
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• 제4권2호
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• pp.31-41
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• 2006

As chemistry dyes has considerably developed with industrial society, natural dyeing has gone out of people's head for a long time. But the serious problems from environmental pollutions and ecological damages make people look far Well-being. Natural dyeing also has concentrated again and the interests about it are growing larger and larger. Well-being that a modern person pursues and a Natural dyeing walk along a same string of connection. That is, people want their life to change from quantity matters into qualities. The relations of the natural dying which has the color of nature and Well-being phenomenons are analyzed through dissertations and references. The study about the correlations between natural dying and well-being shows that many advantages of natural dyestuff and the effects of dyestuff are definitely needed to people living in modern times. Also for the protection of an ecosystem, rapid popularization and the development of new design is completely required.

• 한국의류학회지
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• 제22권8호
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• pp.1011-1019
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• 1998

The natural dyestuff(squid ink) was manufactured from squid ink by boiling in 0.1% NaOH solution and powdering in freeze dryer. Cotton, wool, silk and nylon fabrics were dyed under several conditions using the manufactured squid ink to investigate the dyeability and color fastness. Dyeing was operated in acidic dyebath of pH 4 because the squid ink is anionic. Dyeabilities on wool, silk and nylon fabrics were good, especially silk fabrics were dyed deeper than others because of being amine group. But dyeability on cotton fabrics was low and developed with chitosan treatment. All the dyed fabrics showed excellent in color fastness to crocking and laundering. Also light fastness of them were excellent except nylon. The light fastness of dyed-nylon fabrics was as poor as grade 1, but they could be improved to grade 4 by aftertreatment with gallicacid. Useing the natural dyestuff-squid ink powder, we could execute whenever we want to dye fabrics in the adequate concentration. Dyeabilities were developed according to repeating times of dyeing and the increased dye concentration. We could recycle the wasting sources.

• 청정기술
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• 제15권2호
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• pp.91-101
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• 2009

아마이드계 섬유를 고농도로 염색할 때 피염물의 우수한 견뢰도를 얻기 위해 사용되는 금속착염(metal complex) 염료의 대부분은 Cr을 함유하고 있는 유독성 염료이어서, 잔욕에 남게 등의 환경적인 문제를 일으킬 뿐 아니라, $Cr^{6+}$를 함유할 경우 인체에도 심각한 질병을 줄 수 있다. 본 연구에서는 이러한 금속착염 염료를 대체하기 위해 중금속 함유량을 최소화한 반응성 염료를 양모와 나일론 염색에 응용하였다. 각 섬유에 대한 반응성 염료의 염색성을 파악하고, 실제 염색공장에서의 적용을 위해 색상 영역별 흡진률과 견뢰도 수준을 확인하였다. 또한 반응성 염료들에 대한 중금속 함량 및 유해아민분석을 통하여 그 유해성 경향을 수치적으로 검증하며, 기존 사용 염료와의 비교를 통해 미래 지향적인 청정염료로서의 가능성을 보고자 하였다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2007년도 추계학술발표회
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• pp.139-140
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• 2007