• Title/Summary/Keyword: dyeing & finishing

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Study of Dye Encapsulated Microcapsule Polymerization Using Polyurethane Prepolymer Synthesis and Textile Finishing (폴리우레탄 프리폴리머 합성을 통한 색소 담지 마이크로캡슐 제조 및 섬유가공)

  • Kim, Ji Yeon;Woo, Ji Yun;Min, Mun Hong;Yoon, Seok Han;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.27 no.3
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    • pp.184-193
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    • 2015
  • In this study, dye encapsulated microcapsules were produced by polyurethane prepolymer synthesis method using hexamethylene diisocyanate, ethylene glycol and methyl ethyl ketone. The study showed that the average size of microcapsules were $4.697{\mu}m$ in normal distribution. These microcapsules were induced red color by thermochromic fluoran red dye with showing color change as temperature. After the textile finishing of microcapsules, durability of microcapsules were checked as crocking times and lightfastness. The microcapsules were pressed at protrusion of textile weave in 10 crocking times which meant that the microcapsules not fallen off. Lightfastness was acceptable giving rating 4. It means that the polyurethane microcapsules not affect to light durability.

Functional Dyeing and Finishing Using Catechins Extracted from Green Tea -Dyeing Optimization and Fastness- (녹차추출 카테킨을 활용한 기능성 염색가공 -염색조건 최적화 및 견뢰도 분석-)

  • Son, Song-I;Jang, Kyung-Jin;Kim, Tae-Kyeong;Jeong, Jong-Suc;Choi, Young-Hee
    • Fashion & Textile Research Journal
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    • v.11 no.2
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    • pp.344-349
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    • 2009
  • Optimum dyeing conditions of green tea extracts were investigated toward nylon, cotton, rayon, and tencel fabrics. Affinity of green tea extracts was exhibited much higher onto nylon fabric than the other cellulosics. As for nylon, the adsorption was increased with the increase of dyeing temperature and optimum dyeing pH was around 4~6. Buildup property of green tea extract was good showing a linear relationship between concentration of the extracts and color strength of dyed fabrics within experimental range. Color fastnesses were good to excellent in general except to light.

A Study on the Property of Hair Dyed with Fermented Indigo (천연염료 발효(天然染料 醱酵) 쪽으로 염색(染色)한 모발(毛髮)의 특성 연구(特性 硏究))

  • Kim, Kyung-Sun;Lee, In-Sook;Jeon, Dong-Won;Ha, Byung-Jo
    • Journal of Fashion Business
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    • v.10 no.1
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    • pp.120-131
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    • 2006
  • Recently, it has been reported that chemical hair coloring can cause allergic reactions, the toxicity issue of chemical hair color was issued. Therefore, there is an increasing interest in the hair coloration technique using non-toxic and bio-compatible hair color gotten from natural resource. In this study, the possibility using fermented Indigo as natural hair coloring agent was investigated. Bleached hair samples were dyed using Indigo, and the effect of dyeing frequency, the physical change after dyeing, color, surface and cross-section characteristics, and tensile property were also studied. In addition, the protection property of cationic detergent finishing on damaged hair samples were also studied. The following conclusions are made; 1. While bleached hair samples with low value showed the negligible effect of repeated dyeing, bleached hair samples with high value showed the good effect of repeated dyeing. 2. Hair sample dyed with Indigo showed a high light-fastness, however, tensile strength and elongation showed very low values (high damage on hair sample). 3. Cationic detergent finishing did not affect on the colorfastness because of decoloration after dyeing, however, it increased the smoothness of hair sample, and therefore, can use as protectant of damaged hair. 4. Hair scale was damaged after dyeing. It seemed that the alkali, potassium carbonate, increased pH of dyeing bath to 11, as a result, the hair was swollen, weaken, and dissolved on the prolonged dyeing time. Dyed hair sample became stiff and fine. 5. The color difference was 4.62 (a high fastness value) in the test of sunlight exposure, shampoo, cationic detergent finishing, and acid perspiration fastness.

Preparation of High Molecular Weight Poly(methyl methacrylate) with High Yield by Room Temperature Suspension Polymerization of Methyl Methacrylate

  • Lyoo, Won-Seok;Noh, Seok-Kyun;Yeum, Jeong-Hyun;Kang, Gu-Chan;Ghim, Han-Do;Lee, Jinwon;Ji, Byung-Chul
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.75-81
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    • 2004
  • To obtain high molecular weight (HMW) poly(methyl methacrylate) (PMMA) with high conversion, methyl methacrylate (MMA) was polymerized in suspension using a room temperature initiator, 2,2'-azobis(2,4-dimethylvaleronitrile) (ADMVN), and the effects of polymerization conditions on the polymerization behavior of MMA and the molecular parameters of PMMA were investigated. On the whole, the experimental results well corresponded to the theoretically predicted tendencies. These effects could be explained by a kinetic order of ADMVN concentration calculated by an initial rate method and an activation energy difference of polymerization obtained from the Arrhenius plot. Suspension polymerization at 25℃ by adopting ADMVN proved to be successful in obtaining PMMA of HMW (number-average degree of polymerization (P/sub n/): 30,900-36,100) and of high yield (ultimate conversion of MMA into PMMA: 83-93 %) with diminishing heat generated during polymerization. The P/sub n/ and lightness were higher and polydispersity index was lower with PMMA polymerized at lower temperatures.

A Case Study on the Companies Involved in Work and Learning Dual System at the Textile Clothing Sector in Daegu (대구지역의 섬유·의복 분야 일학습병행제 참여기업 사례연구)

  • Cho, Hyunjin
    • Journal of the Korean Society of Costume
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    • v.67 no.4
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    • pp.116-130
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    • 2017
  • The aim of this study is to investigate the general status, operating status, and the satisfaction level of participating textile-clothing companies involved in the Work and Learning Dual System in Daegu. The general status and operating status of the participating companies are as follows. As of March 2016, 34 of the 43 companies in Daegu participated in this survey, and they were divided into three areas of textile: weaving, dyeing & finishing, and apparel manufacturing. The breakdown is as follows: 14 dyeing & finishing companies (41.2%), 13 apparel manufacturing companies (38.2%), and 7 textile weaving companies (23.6%). The results of the survey showed that 91.2% of the companies decided to participate in the system to cultivate their employees into experts in the field. The satisfaction rate of the theoretical education and training institutions was 3.88 out of 5 points. In particular, the satisfaction rate of the textile weaving companies was as high as 4.29, and the satisfaction level of the dyeing & finishing companies was higher than the average of 3.71. The overall satisfaction rate for the work-related paradigm was 3.97 out of 5 points. The results of this survey can be used to conclude that the Work and Learning Dual System is operating as it was intended to be by the government.

Syntheses and Characteristics of Polymethine Squarylium and Croconium Dyes (Squarylium, Croconium계 Polymethine 색소의 합성과 특성)

  • Kim, Sung Hoon;Hwang, Seok Hwan;Song, Han Chul;Yoon, Nam Sik
    • Journal of the Korean Chemical Society
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    • v.40 no.12
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    • pp.741-747
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    • 1996
  • The syntheses and absorption spectra of squarylium and croconium dyes were studied. IR data and negative solvatochromism revealed that squarylium dyes have symmetrical 1,3-bonded squarylium rings. A new class of unsymmetrical squarylium dyes and their precursor have also been synthesized. The λmax of croconium dyes undergoes a bathochromic shift of about 100 nm compared with corresponding squarylium dyes. This shift can he calculated by the Pariser-Parr-Pople molecular orbital method.

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Influence of Fine Structure on Dyeability of PET Fibers (PET섬유의 염색성에 미치는 미세구조 해석)

  • Son, Young-A;Hu, Jae Won;Kim, Jong Ho;Lim, Yong Jin
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.68-75
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    • 1996
  • Even if fibers are practically identical with respect to chemical composition and denier, the dyeabilities are freqently a little different in an industrial processing. It is difficult to interpret the numerical values of dye diffusion coefficients from a dye solution into fibers. The main reasons are the multicomponent nature of the diffusion process and the inhomogeneities of the substrate, so-called, various kinds of ordered and disordered regions of polymers, void and pores. The equilibrium dye adsorptions and dyeing rates of a disperse dye into the several PET fibers having the same denier were determined at various temperatures. The dyeability of examined samples was divided into two groups, that is, lower dye adsorption fiber and higher ones at the lower temperatures. This result was discussed with the degree of crystallinity, DSC diagram, X-ray diffractometry and Porosimetry of the PET fiber, and an appropriate model for fine structure of PET fiber was proposed.

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Syntheses of Infrared Absorbing Nickel Complex Dyes (적외흡수 니켈 착체색소의 합성)

  • Kim, Sung-Hoon;Lim, Yong-Jin
    • Textile Coloration and Finishing
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    • v.3 no.3
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    • pp.29-33
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    • 1991
  • Some ir absorbing nickel complex dyes were synthesized by the reaction of phenylene diamines, 2-aminobenzenethiols and 2-aminobenzene selenols, tetrathiols with nickel (II) chloride. These dyes absorbed ir light, but those from phenylene diamines absorbed at 780-800 nm which is the most favorable wavelength region for semiconductor laser optical recording dye medium.

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A Study on Properties of the Glass Fiber Reinforced PPS Composites for Automotive Headlight Source Module (자동차 전조등 광원 모듈용 유리섬유강화 PPS 복합재료 특성 연구)

  • Heo, Kwang-Yeol;Park, Sung-Min;Lee, Eun-Soo;Kim, Myung-Soon;Sim, Ji-Hyun;Bae, Jin-Seok
    • Composites Research
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    • v.29 no.5
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    • pp.293-298
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    • 2016
  • In this paper, Glass Fiber Reinforced Thermoplastic (GFRTP) for automotive headlight source module was fabricated by compounding and injection molding using PPS (Poly Phenylene Sulfide) resin with glass fiber which has three cross section (round type, cocoon type, flat type). Tensile, flexural, impact properties were investigated on effect of cross section, glass fiber contents. And it was observed flatness, dimensional stability, fluidity depending on glass fiber cross section. As a result, flat glass fiber reinforced thermoplastic's mechanical properties were most excellent. Also, dimensional stability and flatness showed better results when using flat glass fiber.

Synthesis and Characterization of a Near-Infrared Optical Materials for Shielding Infrared Rays

  • Park Su-Yeol;Sin Seung-Rim;Sin Jong-Il;O Se-Hwa;Jeon Geun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2005.05a
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    • pp.213-215
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    • 2005
  • The metal complexes can be influenced not only by the central metal atoms and the substituent groups, but also by the native of the chelating atoms. For example, near-infrared absorbing chromophores were synthesized by the reaction of phenylenediamine derivatives with a solution of pottassium hydroxide followed by the addition of nickel(II) chloride. These dyes provide absorbing infrared light over 780-840 nm with an extinction coefficient of $2.5-6.0{\times}10^4$. By introduction of alkyl, alkoxyl, cyano, and other functional group into the parent dye, these dyes greatly improved the solubility in organic solvent. New near-infrared absorbing donor-acceptor chromophores have been investigated by varying the electron donating and accepting strength of the two halves of the molecule. The cyanine chromophores permit the simplest way of obtaining systems that absorb well into the near-infrared region of the spectrum. Cyanine dyes possess high extinction coefficients that initially increase with Increasing chain length. These chromophores could be useful in near-infrared optical materials.

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