• Title/Summary/Keyword: dual-column

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Headspace Analysis for Residual Hexane in Vegetable Oil

  • Oh, Chang-Hwan;Kwon, Yong-Kwan;Jang, Young-Mi;Lee, Dal-Su;Park, Jong-Sei
    • Food Science and Biotechnology
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    • v.14 no.4
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    • pp.456-460
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    • 2005
  • To enforce the maximum residue limit for residual hexane (0.005 g/kg) in commercially available Korean vegetable oil, convenient and accurate quantification methods were investigated. Using dual surrogate standards, pentane and heptane were dissolved in ethanol, and then added to hexane-tree sunflower oil for setting up the calibration curve. Gas Chromatograph-Flame Ionization Detector with a porous layer open tubular column, indicated good chromatographic separation of hexane from other inhibiting matrix components. The lowest calibration level was $0.5\;{\mu}g/g$, not exceeding a relative standard deviation of 10% (RSD%), and 1.0\;{\mu}g/g$ not exceeding a deviation of 22% RSD% using heptane as an internal standard for the Static headspace analysis by using a headspace auto-sampler and manual injection, respectively. The residual hexane was detected in nine of the samples among 87 vegetable oil samples purchased on the local market.

Control of Odor Emissions Using Biofiltration: A Case Study of Dimethyl Disulfide

  • Kim, Jo-Chun;Bora C. Arpacioglu;Eric R. Allen
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E3
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    • pp.153-163
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    • 2002
  • A laboratory- scale dual-column biofilter system was used to study the biofiltration of dimethyl disulfide (DMDS). The gas flow rate and DMDS concentration to the biofilter were varied to study their effect on the remov-al of dimethyl disulfide. Operating parameters such as pH, temperature, and water content were monitored during the biofilter operation and necessary precautions were taken to keep these parameters within the acceptable limits. It was observed that the removal efficiency of DMDS was optimal at neutral pH values. After five month op-eration, the neutralization of the filter beds with sodium carbonate became necessary for the optimum operation of the biofilters. The microbial population already present in the compost mixtures was found to be adequate in treat-ing DMDS. The compost mixtures were found to be similar in terms of biofiltration efficiency of DMDS. However, pressure drops observed in the first column compost mixture (compost/ peat mulch) was extremely high, making this compost economically not feasible. The second mixture (compost/bark) provided pressure drops within accept-able limits. A minimum residence time of 30 seconds at the optimal operating conditions appeared to be adequate for achieving high removal efficiencies (>90%).

A Case Study on Seismic Response of Haunch Repaired Steel MRFs (헌치로 보강된 철골모멘트골조의 지진응답 사례연구)

  • 이철호
    • Journal of the Earthquake Engineering Society of Korea
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    • v.1 no.2
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    • pp.69-78
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    • 1997
  • Recent test results of steel moment connections repaired with a haunch on the bottom side of the beam have been shown to be a very promising solution to enhancing the seismic performance of steel moment-resisting frames. Yet, litle is known about the effects of using such a repair scheme on the system seismic performance of structures. To investigate the effects of haunch repair on the system seismic performance, a case study was conducted for a 13-story steel frame building damaged during the 1994 Northridge earthquake. When haunches are incorporated in a steel moment frame, the response prediction is complicated by the presence of "dual" panel zones in the column. A new analytical modeling technique for the dual panel zone recently developed by the author was incorporated in the analysis. Incorporating the behavior of dual panel zone was among the most significant consideration in the analyses. Both the inelastic static and dynamic analyses did not indicate detrimental side effects resulting from the repair.he repair.

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Characterization of the Effects of Relative Humidity and Bed-depth on $CO_2$ Capture for Maximizing the Utilization Rate of Soda Lime Sorbent

  • Cho, Il-Hoon;Park, Guen-Il;Kim, Joon-Hyung;Hwang, Taek-Sung;Lee, Mi-Kyoung
    • Carbon letters
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    • v.2 no.2
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    • pp.113-119
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    • 2001
  • The advanced method for $CO_2$capture is currently one of the most important environmental issues in worldwide and it is therefore necessary to have available technologies, which minimize the discharge of $CO_2$ including Carbon-14 from nuclear facilities into the atmosphere. A key aspect of this work is to provide the technically principal data required to improve a $CO_2$ removal system for the utilization of regenerative sorbent use, specifically include suggestions regarding its modified column design (parallel dual-bed assembly), stop-restart operation and the economic feasibility of sorbent use. The removal performance of soda lime and the effects of relative humidity (RH) and packing bed-depth (BD) on $CO_2$ removal were investigated. In a single-bed, it revealed that the utilization of soda lime for $CO_2$ removal at line velocity of 13 cm/sec and bed depth of 12 cm increased with the increased relative humidity up to 85%. However, in the parallel dual-bed assembly applied with the stop-restart operation, a maximum utilization rate of soda lime for $CO_2$ removal was obtained even at 55% of RH and 8 cm of BD, specifically the utilization rate of soda lime by using this $CO_2$ removal assembly was about two-fold superior to that in a single-bed.

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Simultaneous Determination of Polycyclic Aromatic Hydrocarbons and Their Nitro-derivatives in Airborne Particulates by Using Two-dimensional High-performance Liquid Chromatography with On-line Reduction and Fluorescence Detection

  • Boongla, Yaowatat;Orakij, Walaiporn;Nagaoka, Yuuki;Tang, Ning;Hayakawa, Kazuichi;Toriba, Akira
    • Asian Journal of Atmospheric Environment
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    • v.11 no.4
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    • pp.283-299
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    • 2017
  • An analytical method using high-performance liquid chromatography (HPLC) with fluorescence (FL) detection was developed for simultaneously analyzing 10 polycyclic aromatic hydrocarbons (PAHs) and 18 nitro-derivatives of PAHs (NPAHs). The two-dimensional HPLC system consists of an on-line clean-up and reduction for NPAHs in the 1st dimension, and separation of the PAHs and the reduced NPAHs and their FL detection in the 2nd dimension after column-switching. To identify an ideal clean-up column for removing sample matrix that may interfere with detection of the analytes, the characteristics of 8 reversed-phase columns were evaluated. The nitrophenylethyl (NPE)-bonded silica column was selected because of its shorter elution band and larger retention factors of the analytes due to strong dipole-dipole interactions. The amino-substituted PAHs (reduced NPAHs), PAHs and deuterated internal standards were separated on polymeric octadecyl-bonded silica (ODS) columns and by dual-channel detection within 120 min including clean-up and reduction steps. The limits of detection were 0.1-9.2 pg per injection for PAHs and 0.1-140 pg per injection for NPAHs. For validation, the method was applied to analyze crude extracts of fine particulate matter ($PM_{2.5}$) samples and achieved good analytical precision and accuracy. Moreover, the standard reference material (SRM1649b, urban dust) was analyzed by this method and the observed concentrations of PAHs and NPAHs were similar to those in previous reports. Thus, the method developed here-in has the potential to become a standard HPLC-based method, especially for NPAHs.

An Experimental Study on the Structural Behavior of Double-Angle Shear Connections in Steel Structures (강구조 복앵글 전단 접합부의 구조적 거동에 관한 실험적 연구)

  • Lee, Do-Hyung;Kim, Seok-Jung
    • Journal of Industrial Technology
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    • v.17
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    • pp.305-312
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    • 1997
  • Shear connections in steel structures should satisfy dual criteria of shear strength and rotational flexibility and ductility. The connection should be strong enough to transfer the shear reaction of the beam, and should have sufficient rotational flexibility and ductility to rotate easily and supply the end rotation demand of the beam. This paper is concerned with the behavior of double-angle shear connections where the parameters are numbers of high strength bolts, bolt pitch, the length of angle leg, and connection method. An experimental investigation of shear connection was conducted by testing 12 beam-to-column joint specimens. Based on experimental and analytical study, the failure modes are developed and proposed design formulas.

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Optimal Design of Frame Structure Considering Buckling Load (좌굴하중을 고려한 프레임 그조물의 최적 설계)

  • 진경욱
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.2
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    • pp.59-65
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    • 2000
  • In this paper the comparison of the first order approximation schemes such as SLP(sequential linear programming) CONLIN(convex linearization) MMA(method of moving asymptotes) and the second order approximation scheme SQP(sequential quadratic programming) was accomplished for optimization of nonlinear structures. It was found that MMA and SQP are the most efficient methods for optimization. But the number of function call of SQP is much more than that of MMA. Therefore when it is considered with the expense of computation MMA is more efficient than SQP. In order to examine the efficiency of MMA for complex optimization problem it was applied to the helicopter tail boom con-sidering column buckling and local wall buckling constraints. it is concluded that MMA can be a very efficient approxima-tion scheme from simple problems to complex problems.

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The Structural Design of "China Zun" Tower, Beijing

  • Liu, Peng;Cheng, Yu;Zhu, Yan-Song
    • International Journal of High-Rise Buildings
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    • v.5 no.3
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    • pp.213-220
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    • 2016
  • The "China Zun" tower in Beijing will rise to 528 meters in height and will be the tallest building in Beijing once built. Inspired by an ancient Chinese vessel, the "Zun", the plan dimensions reduce gradually from the bottom of the tower to the waist and then expand again as it rises to form an aesthetically beautiful and unique geometry. To satisfy the structural requirement for seismic and wind resistance, the structure is a dual system composed of a perimeter mega structure made of composite mega columns, mega braces, and belt trusses, and a reinforced-concrete core with steel plate-embedded walls. Advanced parametric design technology is applied to find the most efficient outer-perimeter structure system. The seismic design basically follows a mixed empirical and performance-based methodology that was verified by a shaking table test and other specimen lab tests. The tower is now half-way through its construction.

Effect of Biofilter Operation Parameters on Dimethyl Disulfide Removal : Loading, Time, and Concentration

  • Arpacioglu, Bora C.;Kim, Jo-Chun;Allen, Eric R.;Kim, Seoung-Hyun
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.783-791
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    • 2002
  • A laboratory-scale dual-column biofilter system was used to study the biofiltration of dimethyl disulfide(DMDS). The biofiltration of DMDS was found to depend on the pollutant loadings rather than the inlet concentrations. It was estimated that the pollutant was only inhibitory to the operation of the biofilters at DMDS concentrations greater than 5500 ppmv A residence time of 30 seconds(120 m$^3$/m$^2$/h volumetric loading) was determined as appropriate for efficient operation(>90%). The maximum elimination capacity for both compost mixtures under the current experimental conditions was found to range from 7.5 to 10 g-DMDS/m$^3$/h. A lower DMDS maximum elimination capacity was exhibited under acidified conditions.

Optimal Design of Helicopter Tailer Boom (헬리곱터 꼬리 날개의 최적 설계)

  • 한석영
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1999.10a
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    • pp.419-424
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    • 1999
  • In this paper, the comparison of the first order approximation schemes such as SLP (sequential linear programming), CONLIN(convex linearization), MMA(method of moving asymptotes) and the second order approximation scheme, SQP(sequential quadratic programming) was accomplished for optimization of and nonlinear structures. It was found that MMA and SQP(sequential quadratic programming) was accomplished for optimization of and nonlinear structures. It was found that MMA and SQP are the most efficient methods for optimization. But the number of function call of SQP is much more than that of MMA. Therefore, when it is considered with the expense of computation, MMA is more efficient than SQP. In order to examine the efficiency of MMA for complex optimization problem, it was applied to the helicopter tail boom considering column buckling and local wall buckling constraints. It is concluded that MMA can be a very efficient approximation scheme from simple problems to complex problems.

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