• 제목/요약/키워드: droplet deposition

검색결과 77건 처리시간 0.022초

음극아크증착법으로 합성한 다층박막의 국부부식 기구에 관한 연구 (A Study of Localized Corrosion Mechanisms in the Multilayered Coatings by Cathodic Arc Deposition)

  • 김호건;안승호;이정호;김정구;한전건
    • 한국표면공학회지
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    • 제36권4호
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    • pp.301-306
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    • 2003
  • Multilayered WC-Ti/suv $1-x/Al_{x}$ N coatings were deposited on AISI D2 steel using cathodic arc deposition (CAD) method. These coatings contain structural defects such as pores or droplets. Thus, the substrate is not completely isolated from the corrosive environment. The growth defects (pores, pinholes) in the coatings are detrimental to corrosion resistance of the coatings used in severe corrosion environments. The localized corrosion behavior of the coatings was studied in deaerated 3.5 wt.% NaCl solution using electrochemical techniques (potentiodynamic polarization test) and surface analyses (GDOES, SEM, AES, TEM). The porosity was calculated from the result of potentiodynamic polarization test of the uncoated and coated specimens. The calculated porosity is higher in the $WC-Ti_{0.6}$ $Al_{0.4}$ N than others, which is closely related to the packing factor. The positive effects of greater packing factor act on inhibiting the passage of the corrosive electrolyte to the substrate and lowering the localized corrosion kinetics. From the electrochemical tests and surface analyses, the major corrosion mechanisms can be classified into two basic categories: localized corrosion and galvanic corrosion.

Effect of Working Pressure and Substrate Bias on Phase Formation and Microstructure of Cr-Al-N Coatings

  • Choi, Seon-A;Kim, Seong-Won;Lee, Sung-Min;Kim, Hyung-Tae;Oh, Yoon-Suk
    • 한국세라믹학회지
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    • 제54권6호
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    • pp.511-517
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    • 2017
  • With different working pressures and substrate biases, Cr-Al-N coatings were deposited by hybrid physical vapor deposition (PVD) method, consisting of unbalanced magnetron (UBM) sputtering and arc ion plating (AIP) processes. Cr and Al targets were used for the arc ion plating and the sputtering process, respectively. Phase analysis, and composition, binding energy, and microstructural analyses were performed using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FESEM), respectively. Surface droplet size of Cr-Al-N coatings was found to decrease with increasing substrate bias. A decrease of the deposition rate of Cr-Al-N films was expected due to the increase of substrate bias. The coatings were grown with textured CrN phase and (111), (200), and (220) planes. X-ray diffraction data show that all Cr-Al-N coatings shifted to lower diffraction angles due to the addition of Al. The XPS results were used to determine the $Cr_2N$, CrN, and (Cr,Al)N binding energies. The compositions of the Cr-Al-N films were measured by XPS to be Cr 23.2~36.9 at%, Al 30.1~40.3 at%, and N 31.3~38.6 at%.

Screening and functional validation of lipid metabolism-related lncRNA-46546 based on the transcriptome analysis of early embryonic muscle tissue in chicken

  • Ruonan, Chen;Kai, Liao;Herong, Liao;Li, Zhang;Haixuan, Zhao;Jie, Sun
    • Animal Bioscience
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    • 제36권2호
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    • pp.175-190
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    • 2023
  • Objective: The study was conducted to screen differentially expressed long noncoding RNA (lncRNA) in chickens by high-throughput sequencing and explore its mechanism of action on intramuscular fat deposition. Methods: Herein, Rose crown and Cbb broiler chicken embryo breast and leg muscle lncRNA and mRNA expression profiles were constructed by RNA sequencing. A total of 96 and 42 differentially expressed lncRNAs were obtained in Rose crown vs Cobb broiler chicken breast and leg muscle, respectively. lncRNA-ENSGALT00000046546, with high interspecific variability and a potential regulatory role in lipid metabolism, and its predicted downstream target gene 1-acylglycerol-3-phosphate-O-acyltransferase 2 (AGPAT2), were selected for further study on the preadipocytes. Results: lncRNA-46546 overexpression in chicken preadipocyte 2 cells significantly increased (p<0.01) the expression levels of AGPAT2 and its downstream genes diacylglycerol acyltransferase 1 and diacylglycerol acyltransferase 2 and those of the fat metabolism-related genes peroxisome proliferator-activated receptor γ, CCAAT/enhancer binding protein α, fatty acid synthase, sterol regulatory element-binding transcription factor 1, and fatty acid binding protein 4. The lipid droplet concentration was higher in the overexpression group than in the control cells, and the triglyceride content in cells and medium was also significantly increased (p<0.01). Conclusion: This study preliminarily concludes that lncRNA-46546 may promote intramuscular fat deposition in chickens, laying a foundation for the study of lncRNAs in chicken early embryonic development and fat deposition.

Laboratory-scale Experiment and Model Calculation on the Washout Mechanism of Asian Dust Particles

  • Ma, Chang-Jin;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • 제7권3호
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    • pp.161-168
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    • 2013
  • In this study, an investigation was conducted to assess the washout mechanism of Asian dust particles through both laboratory-scale experiment and model calculation. To artificially simulate Asian dust particle, $CaCO_3$ particles were generated inside an experimental chamber. They were then scavenged by the artificial rain drops. The abundant $CaCO_3$ particles scavenged on a rain drop were successively identified by SEM observation. The concentrations of Ca in residual $CaCO_3$ particles on individual droplet were quantified by PIXE analysis. There was a tendency toward a high accumulation of Ca on a relatively small drop (e.g., <1.0 mm diameter). It is thus suggested that smaller rain drops can effectively scavenge a significant amount of Asian dust particles in ambient atmosphere. The numerical estimation can account for 92.1% and 83.2% of Ca that were measured in small (<1.0 mm diameter) and large (>2.0 mm diameter) size drops, respectively.

플라즈마 화학증착법, 이온 플레이팅법 및 반응성 스퍼터링법에 의해 증착된 TiN 박막의 특성 비교 연구 (A Comparative Study on the Characteristics of TiN Films Deposited by Plasma-Assisted CVD, Ion Plating and Reactive Sputtering)

  • 안치범;정병진;이원종;천성순
    • 한국세라믹학회지
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    • 제31권7호
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    • pp.731-738
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    • 1994
  • TiN films were deposited on high speed steels by plasma assisted chemical vapor deposition (PACVD), cathode arc ion plating (CAIP) and reactive magnetron sputtering (RMS). The properties of the films deposited by the three different methods were compared. The preferred oriented plane of PACVD-TiN is (200) and those of CAIP-TiN and RMS-TiN are (111). PACVD-TiN shows a dome surface and a microstructure having small grains. CAIP-TiN shows the highest microhardness and the best adhesion strength of the three because it has a dense microstructure and an ill-defined interface. But is shows the greatest surface roughness due to the Ti droplet created by the arc. RMS-TiN shows a microstructure having large voids so that its properties in microhardness and adhesion are the worst of the three.

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새로운 충돌모델을 이용한 신형식 디젤연소실 분석 (Analysis of New DI Diesel Combustion Chamber System using New Spray Wall Impaction Model)

  • 장원석;김덕줄;박권하
    • 한국전산유체공학회지
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    • 제2권1호
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    • pp.54-65
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    • 1997
  • Wall wetting in diesel engines has been considered as a bad phenomenon because of fuel deposition which makes fuel/air mixing and evaporation worse. In order to avoid the problem, many research works have been carried out. One of the studies is on new combustion chamber systems which are using spray impacting on a wall. In this study a new type of chamber system is analysed using wall impaction model introduced and assessed in the coupled paper. The gas phase is modelled in terms of the Eulerian continuum conservation equations of mass, momentum, energy and fuel vapour fraction, The liquid phase is modelled following the discrete droplet model approach in Lagrangian form. With various conditions the spray distribution, vapor contour and gas flows are analyzed, and then design factors of those combustion systems are recommended.

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Y-Jet 노즐에서의 혼합관 길이변화에 따른 분무특성 연구 (Change of Spray Characteristics with Mixing Port Length of Y-Jet Atomizers)

  • 송시홍;이상용
    • 대한기계학회논문집
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    • 제18권11호
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    • pp.3021-3031
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    • 1994
  • Experiments have been performed to find out the effect of the mixing port length of Y-jet atomizers on the spray performance, using air and water as the test fluids. Water and air flow rates and drop sizes were measured at each injection pressure condition for different mixing port length. The air flow rate was almost unaffected by the change of the mixing port length. However, the water flow rate was relatively susceptible to the change of the mixing port length. The mixing point pressure was very much influenced by the mixing port length. Variations of spatial distribution of Sauter Mean Diameter (SMD, $D_{32}$) and the cross-section-averaged SMD ($D_{32,m}$) with different mixing port length and air/water mass flow rate ratio were examined. Generally, when the mixing port length was reduced, the mean drop size decreased and became spatially even.

액막형성을 고려한 분무-벽 상호작용에 대한 모델 (Modeling of Spray-Wall Interactions Considering Liquid Film Formation)

  • 이성혁;유홍선
    • 대한기계학회논문집B
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    • 제24권7호
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    • pp.1010-1019
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    • 2000
  • The main purpose of this article is to propose and assess a new spray impingement model considering film formation, which is capable of describing the droplet distribution and film flows in direct injection diesel engines. The spray-wall interaction model includes several mathematical formulae, newly made by the energy conservation law and some experimental results. The model consists of three representative regimes, rebound, deposition and splash. In addition, the film flow is described in the present model by solving the continuity and momentum equations for film flows using the integral method. To assess the new spray impingement model, the calculated results using the new model are compared with several experimental data for the normally impinging diesel sprays. The film model is also validated through comparing film radius and thickness against experimental data. The results show that the new model is generally in better agreement with experimental data and acceptable for prediction of the film radius and thickness.

무인항공 변량방제 시스템의 살포 균일도 분석 (Uniformity Analysis of Unmanned Aerial Application with Variable Rate Spray System)

  • 구영모;배영환
    • 농업생명과학연구
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    • 제52권6호
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    • pp.111-125
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    • 2018
  • 본 연구에서는 변량방제기술을 적용한 농용 회전익기를 이용하여 살포한 입자의 구간비행 상태에서의 거리별 살포 패턴을 측정함으로써 무인 항공방제의 농약 부착률과 입자경의 분포 균일도를 평가하였다. 비행을 등속으로 유지하는 안내비행과 자동비행 모드에서 유효살포폭 3.6m로 인접비행 구간과 살포폭이 일부 중첩된 피복률에 대한 가로방향 분포의 변이계수는 30% 정도를 보였고, 비행방향 진로위치에 대한 피복률의 변이계수는 10% 미만으로 매우 균등한 것으로 평가되었다. 따라서 살포작업시 기체의 지면속도(ground speed)의 변이를 보상하는 변량살포기술은 균일도 측면에서 우수한 것으로 판명되었으며, 또한 입자경의 분포에 있어서 체적중위직경(VMD)과 개체중위직경(NMD) 모두 항공방제에 적절한 크기와 균일한 분포를 보였다. 따라서 농용 회전익기를 이용하여 소필지의 항공방제작업을 무인화 하는데 있어, 변량방제장치를 적용함으로써 소규모 필지의 균일 정밀방제를 도모하고자 하였다.

F-Doped SnO2 Thin Film/Ag Nanowire 이중층의 전기적 및 광학적 특성 (Electrical and Optical Properties of F-Doped SnO2 Thin Film/Ag Nanowire Double Layers)

  • 김종민;구본율;안효진;이태근
    • 한국재료학회지
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    • 제25권3호
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    • pp.125-131
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    • 2015
  • Fluorine-doped $SnO_2$ (FTO) thin film/Ag nanowire (NW) double layers were fabricated by means of spin coating and ultrasonic spray pyrolysis. To investigate the optimum thickness of the FTO thin films when used as protection layer for Ag NWs, the deposition time of the ultrasonic spray pyrolysis process was varied at 0, 1, 3, 5, or 10 min. The structural, chemical, morphological, electrical, and optical properties of the double layers were examined using X-ray diffraction, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, the Hall effect measurement system, and UV-Vis spectrophotometry. Although pure Ag NWs formed isolated droplet-shaped Ag particles at an annealing temperature of $300^{\circ}C$, Ag NWs covered by FTO thin films maintained their high-aspect-ratio morphology. As the deposition time of the FTO thin films increased, the electrical and optical properties of the double layers degraded gradually. Therefore, the double layer fabricated with FTO thin films deposited for 1 min exhibited superb sheet resistance (${\sim}14.9{\Omega}/{\Box}$), high optical transmittance (~88.6 %), the best FOM (${\sim}19.9{\times}10^{-3}{\Omega}^{-1}$), and excellent thermal stability at an annealing temperature of $300^{\circ}C$ owing to the good morphology maintenance of the Ag NWs covered by FTO thin films.