• Journal of Korea Soil Environment Society
• /
• v.3 no.1
• /
• pp.11-20
• /
• 1998

Inorganic nitrogens resulting from fertilizers are possible contaminants of bank-filtered ground water, which is an alternative source of safe drinking water. We conducted a laboratory study to determine the fate of inorganic nitrogens in the near field of bank filtration sites and we consequently illustrated the effects of these possible contaminants on the water quailty of bank filtration. Soil properties were found to be well equivalent to those of other cultivated field soils in Korea. Surface soil pH was about 4.3 which is slightly lower than average level. Overall, diverse concentrations of $NO_3$-N and $NH_3$-N were measured, and $NO_2$-N was nearly undetected. $NH_3$-N level in the field decreased, while $NO_3$-N increased along with increasing depth of unsaturated zone. Numbers of viable and nitrifying bacteria ranged from 6.73$\times$$10^{6}$to 10.7$\times$$10^{6}$ and 0.44$\times$$10^{4}$ to 5.21$\times$$10^{4}$ respectively, and both of them were highly correlated ($R^{2}$=0.992). Nitrifying potential assayed by batch test showed relatively lower than other reported results. The oxygen uptake potential of surface and subsurface soil was measured in the presence of ${(NH_4)_2}$$SO_4$. The results demonstrated that surface soil required shorter lag period and uptaked more oxygen than subsurface's.

• Journal of Environmental Impact Assessment
• /
• v.30 no.4
• /
• pp.215-224
• /
• 2021

In this study, to investigate the effect of stabilization of Pb-contaminated soil near a smelter site for the reduction of environmental risk of Pb leaching, commercial stabilizers were amended with the Pb-contaminated soil and evaluated leaching characteristics of Pb in soil by TCLP and SPLP leaching test. Also, performing sequential extraction procedure speciation of Pb in the amended soil was investigated. Limestone, AC-2 (Amron), Metafix (Peroxychem) that possess stabilization performance towards heavy metal in soil and mass production is available were selected as candidates. AC-2 contained a CaCO₃ and MgO crystalline phase, while Metafix had a Fe₇S₈ crystalline phase, according to XRD studies. Pb content in SPLP extract was lower than the South Korean drinking water standard for Pb in groundwater at 4% AC-2 and Metafix treatment soil, and TCLP-based stabilization effectiveness was more than 90%. The findings of the sequential extraction method of soil treated with Metafix revealed that fractions 1 and 2 of Pb, which correspond to relatively high mobility and bioavailable fractions, were lowered, while the residual fraction (fraction 5) was raised. As a consequence, the order of performance for Pb stabilization in polluted soil was Metafix>AC-2>limestone.

• Journal of Soil and Groundwater Environment
• /
• v.13 no.5
• /
• pp.8-19
• /
• 2008

The physicochemical properties of soils having high uranium content, located around Duckpyungri in Korea, were investigated and the lab scale soil washing experiments to remove uranium from the soil were preformed with several washing solutions and on various washing conditions. SPLP (Synthetic Precipitation Leaching Procedure), TCLP (Toxicity Characteristic Leaching Procedure), and SEP (Sequential Extraction Procedure) for the soil were conducted and the uranium concentration of the extracted solution in SPLP was higher than Drinking Water Limit of USEPA (30 ${\mu}g$/L), suggesting that the continuous dissolution of uranium from soil by the weak acid rain may generate the environmental pollution around the research area. For the soil washing experiments, the uranium removal efficiency of pH 1 solution for S2 soil was about 80 %, but dramatically decreased as pH of solution was > 2, suggesting that strong acidic solutions are available to remove uranium from the soil. For solutions with 0.1M of HCl and 0.05 M of ${H_2}{SO_4}$, their removal efficiencies at 1 : 1 of soil vs. washing solution ratio were higher than 70%, but the removal efficiencies of acetic acid, and EDTA were below 30%. At 1 : 3 of soil vs. solution, the uranium removal efficiencies of 0.1M HCl, 0.05 M ${H_2}{SO_4}$, and 0.5M citric acid solution increased to 88%, 100%, and 61% respectively. On appropriate washing conditions for S2 soil such as 1 : 3 ratio for the soil vs. solution ratio, 30 minute for washing time, and 2 times continuous washing, TOC (Total Organic Contents) and CEC (Cation Exchange Capacity) for S2 soil were measured before/after soil washing and their XRD (X-Ray Diffraction) and XRF (X-Ray Fluorescence) results were also compared to investigate the change of soil properties after soil washing. TOC and CEC decreased by 55% and 66%, compared to those initial values of S2 soil, suggesting that the soil reclaimant may need to improve the washed soils for the cultivated plants. Results of XRF and XRD showed that the structural change of soil after soil washing was insignificant and the washed soil will be partially used for the further purpose.

• Korean Journal of Soil Science and Fertilizer
• /
• v.32 no.2
• /
• pp.155-163
• /
• 1999

Nutrient balance during rice cultivation in the paddy of a local area under the environmental protection for drinking water supply was investigated. To compare nutrient balance in the paddy soil applied with different types of fertilization, 7 treatments were selected as followings : Recommended level of chemical fertilizers(R), Conventional fertilization(CF), Fresh cow manure(FCM), Cow manure compost(CMC), Straw compost+reduced chemical fertilizer(SCF), Fresh straw+recommended level of fertilizers(FSC), and no fertilization as control(C). Here, FCM, CMC and SCF were applied at the same level of total nitrogen as recommended in R. Rice yield was the highest in the recommendation(R) and fresh cow manure (FCM) treatments with $6,730kg\;ha^{-1}$(index 100), and followed by SCF (index 98), FSC (index 98), CMC(index 94), and CF(index 94). But statistically significant difference was not recognized among treatments except the control. Nitrogen infiltration loss was high in the simple chemical fertilizer treatments with $63kg\;ha^{-1}$ in CF and $58kg\;ha^{-1}$ in R during rice cultivation, respectively. Nitrogen infiltration loss was decreased below half level of chemical fertilizer treatments with cow manure treatments ($23kg\;ha^{-1}$ in FCM and $27kg\;ha^{-1}$ in CMC) and with reducing chemical fertilizer treatment by adding straw compost ($25kg\;ha^{-1}$). Phosphate was not leached during rice cultivation in paddy soil of a fluvial deposit type, in which oxidation horizon was developed broadly under around 15 cm depth of surface soil. Phosphate balance (A-B) was closed to 0 in all treatments except cow manure treatment (CMC), in which it was $+30kg\;ha^{-1}$ and show the possibility of over accumulation of phosphate by continuously replicated application of cow manure compost. Potassium balance was negative value in all but straw recycling treatment (FSC). It means that potassium was continuously supplied from soil minerals, uptaken by plants or eluted out of soil. In conclusion, by substituting inorganic fertilizer for organic fertilizer or reducing application rate of chemical fertilizer through mixing organic fertilizer, it would be possible to achieve the same rice yield as in the recommendation treatment and to decrease nutrient leaching below half level in rice paddy soil.

• Journal of Appropriate Technology
• /
• v.7 no.2
• /
• pp.136-143
• /
• 2021

Pacific island countries, including Kiribati, are suffering from a shortage of essential resources as well as a reduction in their living space due to sea level rise and coastal erosion from climate change, groundwater pollution and vegetation changes. Global activities to solve these problems are being progressed by the UN's efforts to implement SDGs. Pacific island countries can adapt to climate change by using abundant marine resources. In other words, seawater plants can assist in achieving SDGs #2, #6 and #7 based on SDGs #14 in these Pacific island countries. Under the auspice of Korea International Cooperation Agency (KOICA), Korea Research Institute of Ships and Ocean Engineering (KRISO) established the Sustainable Seawater Utilization Academy (SSUA) in 2016, and its 30 graduates formed the SSUA Kiribati Association in 2017. The Ministry of Oceans and Fisheries (MOF) of the Republic of Korea awarded ODA fund to the Association. By taking advantage of seawater resource and related plants, it was able to provide drinking water and vegetables to the local community from 2018 to 2020. Among the various fields of education and practice provided by SSUA, the Association hope to realize hydroponic cultivation and seawater desalination as a self-support project through a pilot project. To this end, more than 140 households are benefiting from 3-stage hydroponics, and a seawater desalination system in connection with solar power generation was installed for operation. The Association grows and supplies vegetable seedlings from the provided seedling cultivation equipment, and is preparing to convert to self-support business from next year. The satisfaction survey shows that Tarawa residents have a high degree of satisfaction with the technical support and its benefits. In the future, it is hoped that SSUA and regional associations will be distributed to neighboring island countries to support their SDGs implementations.

• Journal of the Mineralogical Society of Korea
• /
• v.21 no.3
• /
• pp.227-237
• /
• 2008

Arsenic has recently become of the most serious environmental concerns, and the worldwide regulation of arsenic fur drinking water has been reinforced. Arsenic contaminated groundwater and soil have been frequently revealed as well, and arsenic contamination and its treatment and measures have been domestically raised as one of the most important environmental issues. Arsenic behavior in geo-environment is principally affected by oxides and clay minerals, and particularly iron (oxy)hydroxides have been well known to be most effective in controlling arsenic. Among a number of iron (oxy)hydroxides, for this reason, 2-line ferrihydrite was selected in this study to investigate its effect on arsenic behavior. Adsorption of 2-line ferrihydrite was characterized and compared between As(III) and As(V) which are known to be the most ubiquitous species among arsenic forms in natural environment. Two-line ferrihydrite synthesized in the lab as the adsorbent of arsenic had $10\sim200$ nm for diameter, $247m^{2}/g$ for specific surface area, and 8.2 for pH of zero charge, and those representative properties of 2-line ferrihydrite appeared to be greatly suitable to be used as adsorbent of arsenic. The experimental results on equilibrium adsorption indicate that As(III) showed much stronger adsorption affinity onto 2-line ferrihydrite than As(V). In addition, the maximum adsorptions of As(III) and As(V) were observed at pH 7.0 and 2.0, respectively. In particular, the adsorption of As(III) did not show any difference between pH conditions, except for pH 12.2. On the contrary, the As(V) adsorption was remarkably decreased with increase in pH. The results obtained from the detailed experiments investigating pH effect on arsenic adsorption show that As(III) adsorption increased up to pH 8.0 and dramatically decreased above pH 9.2. In case of As(V), its adsorption steadily decreased with increase in pH. The reason the adsorption characteristics became totally different depending on arsenic species is attributed to the fact that chemical speciation of arsenic and surface charge of 2-line ferrihydrite are significantly affected by pH, and it is speculated that those composite phenomena cause the difference in adsorption between As(III) and As(V). From the view point of adsorption kinetics, adsorption of arsenic species onto 2-line ferrihydrite was investigated to be mostly completed within the duration of 2 hours. Among the kinetic models proposed so for, power function and elovich model were evaluated to be the most suitable ones which can simulate adsorption kinetics of two kinds of arsenic species onto 2-line ferrihydrite.