• Title/Summary/Keyword: distribution ratio(D)

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Studies on Solvent Extraction and Analytical Application of Metal Dithiocarbamate Complexes(II). Extraction Equilibria of Metal-Dibenzylammonium dibenzyldithiocarbamate Complexes (Dithiocarbamate 금속착물의 용매추출 및 분석적 응용(제2보) Dibenzylammonium dibenzyldithiocarbamate 금속착물의 추출평형)

  • Lee, Jong-Sun;Choi, Jong-Moon;Choi, Hee-Seon;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.9 no.3
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    • pp.221-234
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    • 1996
  • Basic studies for the effective extraction of dibenzylammonium dibenzyldithiocarbamate(DBADBDC) complexes of Ag(I), Pd(II), Au(III) and Pt(IV) into chloroform have been conducted. The effects of pH on the extraction of ligand itself and metal cemplexes showed that DBADBDC itself was uniformly extracted in the pH range of 2~9 and metal complexes were effectively extracted at the pH range as follows. That is, Ag(I) : in an acidic aqua medium, Pd(II) : > 4, Au(III) : wide range, and Pt(IV) : > 3. The distribution ratio and extractabilities were obtained from the partition and extraction equilibria of metal-DBDC complexes between aqueous solution and chloroform. Ag(I) : log D=4.226 : E(%)=99.9% in the aqueous solution of pH 0, Pd(II) : log D=1.804 : E(%)=98.5% at pH 4~7, Au(III) : log D=3.755 : E(%)=99.9% at pH 2~10, and Pt(IV) : log D=0.165 : E(%)=57.2% at pH 8.0. And also mole ratio of metal ion to ligand in complexes were determined by mole ratio method : 1 : 1 for Ag(I) and 1 : 2 for Pd(II), Au(III) and Pt(IV). $Cl^-$ was included as a coordination species in complexes of Au(III) and Pt(IV). Besides, extraction mechanisms of compleses sere examined in the presence of chloride ion in an aquous solution, and extraction reactions and estraction constants could be proposed and calculated, respectively.

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A Study on the Design of Fatigue Strength using Fractal Character of Surface Micro-crack (표면미소균열의 프랙탈 특성을 이용한 피로강도설계에 관한 연구)

  • Cho, Seok-Swoo;Joo, Won-Sik
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.12
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    • pp.143-151
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    • 1999
  • The shape of surface micro-crack is very irregular due to nonhomogeneous microstructure but is very important in respect to qualitative estimation of fatigue life. Fractal geomety can quantify the shape of surface mciro-crack. Fractal dimension is measured for surface micro-cracks with coast line and box counting method and estimates cycle ration in Al 2024-T3. The average fractal dimension $D_{favg}$ of surface micro-cracks has 3-parameter weibull distribution and location parameter is nearly constant but shape parameter decreases as cycle ration increases. The fractal dimension by coast line method is measured for individual surface micro-crack but the fractal dimension by box countin method is measured for all the surface micro-cracks under sampling area. Therefore, This paper shows fractal dimension $D_{fb}$ can predict cycle ratio $N/N_f$ more convenient than fractal dimension $D_{favg}$.

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Characteristics of a Coupled Gas Lubricated Bearing for a Scaled-Up Micro Gas Turbine

  • Lee, Yong Bok;Kwak, Hyunduck;Kim, Chang Ho;Jang, Gun Hee
    • KSTLE International Journal
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    • v.1 no.2
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    • pp.107-112
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    • 2000
  • In case of the limitation of Deep RIE fabrication far Micro Gas Turbine, bearing aspect ratio is limited in very small value. The characteristics such as pressure distribution, load capacity and non-linearity of a short bearing of L/D=0.083 and a conventional bearing of L/D=1.0 with coupled boundary effects are investigated for Micro Gas Turbine bearings. The coupled effect was analyzed by mass conservation at coupled end area. The results, increasing load capacity and non-linearity due to the coupled effect of thrust and journal bearing, are obtained and the selection of journal bearing type is discussed.

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Coupled Boundary Effects on a Gas Lubricated Bearing far a Scaled-Up Micro Gas Turbine

  • Hyunduck Kwak;Lee, Yong-Bok;Kim, Chang-Ho;Gunhee Jang
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.11a
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    • pp.243-249
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    • 2000
  • In case of the limitation of Deep RIE fabrication for Micro Gas Turbine, bearing aspect ratio is limited in very small value. The characteristics such as pressure distribution load capacity and non-linearity of a short bearing of L/D=0.083 and a conventional bearing of L/D=1.0 with coupled boundary effects are investigated far Micro Gas Tlubine bearings. The coupled efffect was analyzed by mass conservation at coupled end area. The results, increasing load capacity and non-linearity due to the coupled effect of thrust and journal bearing, are obtained and the selection of journal bearing type is discussed.

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Adaptive Correlation Noise Model for DC Coefficients in Wyner-Ziv Video Coding

  • Qin, Hao;Song, Bin;Zhao, Yue;Liu, Haihua
    • ETRI Journal
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    • v.34 no.2
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    • pp.190-198
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    • 2012
  • An adaptive correlation noise model (CNM) construction algorithm is proposed in this paper to increase the efficiency of parity bits for correcting errors of the side information in transform domain Wyner-Ziv (WZ) video coding. The proposed algorithm introduces two techniques to improve the accuracy of the CNM. First, it calculates the mean of direct current (DC) coefficients of the original WZ frame at the encoder and uses it to assist the decoder to calculate the CNM parameters. Second, by considering the statistical property of the transform domain correlation noise and the motion characteristic of the frame, the algorithm adaptively models the DC coefficients of the correlation noise with the Gaussian distribution for the low motion frames and the Laplacian distribution for the high motion frames, respectively. With these techniques, the proposed algorithm is able to make a more accurate approximation to the real distribution of the correlation noise at the expense of a very slight increment to the coding complexity. The simulation results show that the proposed algorithm can improve the average peak signal-to-noise ratio of the decoded WZ frames by 0.5 dB to 1.5 dB.

Chest dimension in spontaneous pneumothorax (자연기흉 환자의 흉곽계측)

  • Kim, Jong-Won;Lee, Jong-Su
    • Journal of Chest Surgery
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    • v.19 no.4
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    • pp.750-759
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    • 1986
  • Spontaneous pneumothorax is usually seen in young adult male. And typically, the patient is a tall, thin, 20- to 30-year-old male. Usually the pneumothorax results from rupture of a pulmonary bleb. Author reviewed 66 cases of spontaneous pneumothorax experienced in the Dept. of Thoracic & Cardiovascular Surgery, Pusan National University Hospital, since Jan., 1980 to Aug., 1986. The clinical data were summarized as follows: 1. The age distribution of spontaneous pneumothorax: 17 to 34 years old and mean age was 25.3 years. 2. The sex distribution of spontaneous pneumothorax: 52 in men, 14 in women and the ratio was 3.7:1. 3. Chest dimension in male patients: Maximum posteroanterior distance [MPA], MPA/Maximum width [MW]: Significantly smaller than control group. Distance from second to tenth rib on left [L2-10], Distance from second rib on right to diaphragm [R2-D], R2-D/MW: Significantly larger than control group. 4. Chest dimension in female patients: MPA, MW: Significantly smaller than control group. Distance from second rib on left to diaphragm [L2-D], Distance from second to tenth rib on right [R2-10], R2-D, L2-10/MW, L2-D/MW, R2-10/MW, R2-D/MW: Significantly larger than control group.

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Assessment of Daylight Environment on Light Pipe System Under Different Solar Position (태양의 위치에 따른 광파이프 시스템의 실내 주광환경평가)

  • Shin, Hwa-Young;Kim, Jeong-Tai
    • Journal of the Korean Solar Energy Society
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    • v.28 no.6
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    • pp.78-86
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    • 2008
  • The aim of this paper is to show the daylight environment of a light pipe system according to sun movement. A light pipe system has been mounted on the roof of the windowless full scale model: the solar spot has diameter of 0.65m and is 1.3m long, giving an aspect ratio of 1:2. The full scale model was installed on the rooftop of the SHINAN apartment in Yongin city that has no obstructions against sunlight. The test room is equipped with sensors for the measurements of the internal illuminance and has an area of 6m(W)$\times$6m(D)$\times$4m(H). The system has been monitored with a data-logger to evaluate the cumulative distribution of illuminance on a floor-plane from 16th, April to 29th, May, 2008 over one month and selected clear sky condition. For the daylight performance of floor area, the totally 49 measuring points has been used to determine the internal illuminance and an HP datalogger(HP34970A) records the measurements for one consecutive month. The horizontal external illuminance has been measured with two outdoor sensors. This paper presents the results of monitoring light pipe system with internal/external illuminance ratio and cumulative frequency distribution of floor-plane illuminance are discussed The results show that lightpipe is proficient device for introducing daylight into the building. However It provided different daylight indoor environment with wide or narrow Interquatile range of illuminance, internal/external illuminance ratio and cumulative frequency distribution according to solar positions under suuny sky condition. For more achieving the improvement of lightpipes also include energy savings, user visual comfort with various indicators; seasonal solar height, room and lightpipes geometries.

Spray characteristics on mixing region scale of twin fluid atomizer (이류체 분사노즐의 혼합영역 형상에 따른 분무특성)

  • 김병문;김혁주;이충원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.2147-2159
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    • 1991
  • The effects of principal dimensions of internal mixing twin-fluid atomized and operating conditions on the atomizing characteristics are experimentally investigated. The tests are conducted over the wide range of air/liquid ratio to predict influences of the diameter and length of nozzle, contacting angle between air and liquid in the mixing chamber, and air orifice diameter on the mean drop size(SMD), spray angle, distribution of drop size, and spray dispersion, And also, initial distribution of liquid column by air stream within the mixing chamber are observed through the transparent nozzles. A He-Ne laser particle sizer(MALVERN Model 2604) was used to measure the Sauter.s mean diameter( $D_{321}$) and droplet sizes distribution. In this experiment the air/liquid ratio, mixing length and nozzle diameter have a great influence on SMD, spray angle, droplet sizes distribution and spray dispersion.

A Study on Effect on Current Density Distribution, Inductance Gradient, and Contact Force by Variation of Armature and Rail Structure (아마츄어 및 레일의 구조 변화에 따른 전류 밀도, 인덕턴스 경도 및 접촉력의 영향 연구)

  • 김복기
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.50 no.2
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    • pp.59-64
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    • 2001
  • The distribution of current in the conductors influenced by the armature geometry and velocity is an important parameter for determining performance of an electromagnetic launcher(EML). the electric current in the early launching stage tends to flow on the outer surfaces of the conductors, resulting in very high local electric current density. However, the tendency for current to concentrate on the surface is driven by the velocity skin effect later in launching stage. The high current density produces high local heating and, consequently, increases armature wear which causes several defects on EML system. This paper investigates the effects of rail/armature geometry on current density distribution, launcher inductance gradient (L'), and contact force. Three geometrical parameters are used here to characterize the railgun system. These are the ratio of contact length to root length, relative position of contact leading edge to root trailing edge, and the ratio of rail overhang to the rail height. The distribution of current density, L', contact force between various configurations of the armature and the rail are analyzed and compared by using the EMAP3D program.

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Characterization of the Effect of the Inlet Operating Conditions on the Performance of Lean Premixed Gas Turbine Combustors

  • Samperio, J.L.;Santavicca, D.A.;Lee, J.G.
    • Journal of the Korean Society of Combustion
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    • v.9 no.3
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    • pp.10-18
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    • 2004
  • An experimental study of the effect of operating conditions on the behavior of a lean premixed laboratory combustor operating on natural gas has been conducted. Measurements were made characterizing the pressure fluctuations in the combustor and the flame structure over a range of inlet temperatures, inlet velocities and equivalence ratios. In addition the fuel distribution at the inlet to the combustor was varied such that it was an independent parameter in the experiment. Inlet temperature, inlet velocity and equivalence ratio were all found to have an effect on the stability characteristics of the combustor. The nature of this effect, however, depended on the fuel distribution. For example, with one fuel distribution the combustor would become unstable when the temperature was increased, whereas with a different fuel distribution the combustor would become unstable when the temperature was decreased. Similarly, the operating conditions had an effect on the flame structure. For example the intensity-weighted center of mass of the flame was found to move closer to the center body as either the temperature or equivalence ratio increased. It was interesting and somewhat surprising to note, however, that as the location of the center of mass changed with operating conditions it did so by moving along a line of constant flame angle.

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