• Title/Summary/Keyword: dissolving

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Dissolution Behavior and Hydrate Effect on $CO_{2}$ Ocean Sequestration

  • Kim Nam Jin;Kim Chong Bo
    • Journal of Mechanical Science and Technology
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    • v.19 no.5
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    • pp.1216-1225
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    • 2005
  • $CO_{2}$ ocean sequestration is one of the promising options to reduce $CO_{2}$ concentration in the atmosphere because the ocean has vast capacity for $CO_{2}$ absorption. Therefore, in the present investigation, calculations for solubility and dissolution behavior of liquid $CO_{2}$ droplets released at 1000 m and 1500 m deep in the ocean from a moving ship and a fixed pipeline have been carried out in order to estimate the $CO_{2}$ dissolution characteristics in the ocean. The results show liquid $CO_{2}$ becomes bubble at around 500 m in depth, and the solubility of seawater is about $5{\%}$ less than of pure water. Also, it is shown that the injection of liquid from a moving ship is a more effective method for dissolution than from a fixed pipeline, and the presence of hydrate on liquid $CO_{2}$ acts as a resistant layer in dissolving liquid $CO_{2}$.

Impact of Alkali Pretreatment to Enzymatic Hydrolysis of Cork Oak (Quercus Variabilis) (알칼리 전처리가 굴참나무의 효소 당화에 미치는 영향)

  • Yoon, Su Young;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.6
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    • pp.1-7
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    • 2014
  • Dissolving part of xylan and lignin in lignocellulosic biomass by base can be used as pretreatment technique. Cork oak was pretreated with sodium hydroxide solution and the pretreatment effects were evaluated with two critical factors - NaOH concentration and pretreatment temperature. Some of xylan and lignin were removed by base pretreatment. At $90^{\circ}C$ and 13% NaOH pretreatment, 22.0% of lignin and 78.8% of xylan removed by base treatment. Enzymatic hydrolysis of cork oak which was pretreated at higher temperature or concentration was further improved. After pretreatment of cork oak with 13% NaOH at $90^{\circ}C$, the conversion rate of cellulose to fermentable sugars were reached up to 91.3%. At ethanol fermentation with enzymatic hydrolysate from different pretreatment conditions, all enzymatic saccharification liquids were well fermented by Saccharomyces cerevisiae.

Characterization of Hydrazine Solution Processed Multi-layered CuInSe2 Thin Films (하이드라진 용액법으로 형성된 CuInSe2 다층 박막 분석)

  • Chung, Choong-Heui
    • Journal of the Korean institute of surface engineering
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    • v.48 no.4
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    • pp.169-173
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    • 2015
  • $CuInSe_2$ thin films which have been widely used for thin solar cells as a light absorber were prepared by hydrazine solution processing, and their microstructural properties were investigated. Hydrazine $CuInSe_2$ precursor solutions were prepared by dissolving $Cu_2S$, S, $In_2Se_3$ and Se powder in hydrazine solvent. Multilayer $CuInSe_2$ chalcopyrite phase thin films were prepared by repeating spin-coating process using the precursor solution. Unfortunately, the presence of the interfaces between each $CuInSe_2$ layer formed by multi-layer coating impeded grain growth across the interface. Here, by doing simple interface engineering to solve the limited grain growth issue, the large grained (${\sim}1{\mu}m$) $CuInSe_2$ thin films were obtained.

Aqueous alkali-developable Photosensitive Barrier Rib Paste for PDP and Photolithographic Process

  • Park, Lee-Soon;Jeong, Seung-Won;Kim, Soon-Hak;Tae, Heung-Sik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.177-179
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    • 2000
  • Barrier rib for the plasma display panel (PDP) was made by photolithographic process utilizing photosensitive barrier rib paste. The barrier rib paste was prepared by first dissolving poly(MMA-co-MAA) binder polymer in butyl carbitol(BC) solvent at 15 wt% concentration. To this solution were added a mixture of functional monomers , Irgacure 651 photoinitiator, and barrier rib power and then the whole mixture was dispersed in the three roll mill for 2 hour. The effect of component and concentration of photosensitive barrier rib paste was studied. After optimization of the paste formulation and photolithographic process, barrier rib could be obtained with good resolution up to 110-120 ${\mu}m$ height and 80-90 ${\mu}m$ width.

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플라스마 디스플레이 패널의 격벽 형성의 에칭 메커니즘

  • Jeong Yu-Jin;Jeon Jae-Sam;Seong U-Gyeong;Kim Hyeong-Sun
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.05a
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    • pp.198-201
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    • 2006
  • To produce fine structure with uniform surface of barrier ribs in PDP, acid etching process has been used in manufacture process. It is necessary to understand the mechanism of etching, particularly on the interface of ceramic fillers and matrix glass. We investigated the effect of ceramic fillers (ZnO, $Al_{2}O_3$) on the microstructure of borate glass system to find an etching mechanism of barrier ribs. The harrier ribs was etched with a several steps, dissolving a small amount of residual glass, taking out alumina fillers, and removing a cluster type of ZnO fillers and glass matrix.

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Etching Mechanism of Barrier Ribs in Plasma Display Panel (플라즈마 디스플레이 패널의 격벽형성의 에칭 메커니즘)

  • Chong, Eu-Gene;Jeon, Jae-Sam;Sung, Woo-Kyung;Kim, Hyung-Sun
    • Journal of the Semiconductor & Display Technology
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    • v.5 no.3 s.16
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    • pp.33-36
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    • 2006
  • To produce a fine structure with uniform surface of barrier ribs in PDP, acid etching process has been used in manufacture process. It is necessary to understand the mechanism of etching, particularly on the interface of ceramic fillers and matrix glass. We investigated the effect of ceramic fillers (ZnO, $Al_2O_3$) on the microstructure of borate glass system to find an etching mechanism of barrier ribs. The barrier ribs was etched with several steps, dissolving a small amount of residual glass, taking out alumina fillers, and removing a cluster type of ZnO fillers and glass matrix.

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Determination of panthenol, cholecalciferol and tocopherol in cosmetic products by gas chromatography-mass spectrometry in SIM mode

  • Hye-Jin Jeong;Myo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.2
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    • pp.153-160
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    • 1996
  • A novel simple method to detect vitamins in cosmetic products by gas chromatography-mass spectrometry(GC-MS) has been developed. Three vitamins(panthenol, cholecalciferol and tocopherol) were used for this study. Vitamins were prepared by dissolving in tetrahydrofuran(THF), and silylated with bis-trimethylsilyltrifluoroacetamide-trichloromethylsilane(BSTFA). Silated vitamins were separated on a fuses-silica capillary column coated with DB-5. The identification of each vitamin was accomplished by retention time and mass spectrum library search with a computer, and the quantitation was made in the selected-ion monitoring(SIM) mode of GC-MS. SIM mode had given sensitivity to determine 50pg of panthenol, 285pg of cholecalciferol and 130pg of tocopherol. Linearity was maintained over the range 0.005-0.20% for each vitamin. Each cosmetic product(i.e. hair tonic and lotion) was found to contain amounts of the vitamins. This method was sensitive and gave 77.5-99.9% recovery of each vitamin from these cosmetic products. From these results, we concluded that silylation with BSTFA followed by GC-MS analysis allows the simple, covenient and exact determination of panthenol, cholecalciferol and tocopherol.

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Studies on Utilizations of Serpentine [I] Chemical Studies on the Fertilizer of Ignited Serpentine (蛇紋石의 利用에 關한 硏究 [I] 蛇紋石의 化學的 方法에 依한 肥效檢討)

  • Ham, Yong-Mook;Chun, Hai-Soo;Kim, Yong-Bai
    • Journal of the Korean Chemical Society
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    • v.8 no.1
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    • pp.5-8
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    • 1964
  • In order to investigate the availability of serpentines occurring in Korea as fertilizer, the dissolving rates of Magnesia and Silicate contents in 0.5N HCl solution after heat treatment of the serpentines, have been studied. It was found that calcination of the serpentines at $700^{\circC$ for 30 min. was the best condition for utilization of serpentines as fertilizer. The weight decrease on calcining has also been discussed from the chemical point of view.

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Fluorescent Silk Fibroin Nanoparticles Prepared Using a Reverse Microemulsion

  • Myung, Seung-Jun;Kim, Hun-Sik;Kim, Yeseul;Chen, Peng;Jin, Hyoung-Joon
    • Macromolecular Research
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    • v.16 no.7
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    • pp.604-608
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    • 2008
  • Color dye-doped silk fibroin nanoparticles were successfully fabricated using a microemulsion method. An aqueous silk fibroin solution was prepared by dissolving cocoons (Bombyx mori) in a concentrated lithium bromide solution followed by dialysis. A color dye solution was also mixed with the aqueous silk fibroin solution. The surfactants used for the microemulsion were then removed by methanol and ethanol, yielding color dye-doped silk fibroin nanoparticles, approximately 167 nm in diameter. The secondary structure of the nanoparticles showed a $\beta$-sheet conformation, as characterized by Fourier transform infrared spectroscopy. The morphology of the nanoparticles was determined by field emission scanning electron microscopy, transmission electron microscopy and atomic force microscopy, and their size and size distribution were measured by dynamic light scattering. The color dye-doped silk fibroin nanoparticles were examined by confocal laser scanning microscopy.

Production of Ag- Ni fine powder by coprecipitation (공침법을 이용한 Ag-Ni 초미분 제조)

  • Kim, Bong-Seo;Woo, Byung-Chul;Byun, Woo-Bong;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1342-1344
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    • 1994
  • Silver-Nickel alloy has been used as a electrical contact material for low voltage, low current. Since the solubility between Ag and Ni is very low, it is difficult to produce Ag-Ni alloy by using conventional melting method and disperse Ni powder homogeneously in Ag matrix. In this study we have been produced fine Ag-Ni alloy powder by using coprecipitation method. Firstly, we have produced silver-nickel nitrate solution by dissolving the Ag and Ni ingot in nitric acid solution and then, coprecipitate (Ag, Ni)carbonate dropping Ag-Ni nitrate solution to sodium carbonate solution. (Ag, Ni) carbonate is heat-treated in $H_2$ atmosphere, $400^{\circ}C$ and it has been analysed by TGA, SEM, XRD, ICP. It is represented Silver-Nickel alloy powder in the particle range of $0.1{\sim}0.5{\mu}m$.

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