• Title/Summary/Keyword: dissolved gas in oil

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Preparation of Porous SiC by Freeze Drying of Polycarbosilane Emulsion (폴리카보실란 에멀젼의 동결건조를 이용한 다공체 SiC 제조)

  • Hwang, Yeon
    • Korean Journal of Materials Research
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    • v.26 no.6
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    • pp.320-324
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    • 2016
  • Porous SiC beads were prepared by freeze-drying a polycarbosilane (PCS) emulsion. The water-in-oil (w/o) emulsion, which was composed of water, PCS dissolved p-xylene, and sodium xylenesulfonate (SXS) as an emulsifier, was frozen by dropping it onto a liquid $N_2$ bath; this process resulted in 1~2 mm sized beads. Beads were cured at $200^{\circ}C$ for 1 h in air and heat-treated at $800^{\circ}C$ and $1400^{\circ}C$ for 1 h in an Ar gas flow. Two types of pores, lamella-shaped and spherical pores, were observed. Lamellar-shaped pores were found to develop during the freezing of the xylene solvent. Water droplets in the w/o emulsion were changed into spherical pores under freeze-drying. At $1400^{\circ}C$ of heat-treatment, porous SiC was synthesized with a low level of impurities.

A Fault Diagnosis of Oil-Filled Power Transformers using Dissolved Gas Analysis and Neural Network (유중 가스 분석과 신경 회로망을 이용한 전력용 유입 변압기의 고장 진단)

  • Yoon, Yong-Han;Kim, Jae-Chul;Kim, Jae-Sung
    • Proceedings of the KIEE Conference
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    • 1999.07c
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    • pp.1493-1495
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    • 1999
  • 본 논문에서는 변압기 유중 가스 분석 자료와 고장에 관련된 특징을 학습시킨 신경 회로망을 이용하여 전력용 유입 변압기의 새로운 고장 진단 방법을 제안하였다. 본 논문에서 제안한 신경 회로망을 이용한 고장 진단 방법(유중 가스 분석 방법)은 입력으로 가스 구성비 분석(IEC 기준) 및 주요 가스 분석(한국 전력 공사 기준) 자료를 채택하였다. 또한, 출력으로 전력용 유입 변압기의 고장 유무 및 고장 종류의 특징을 신경 회로망으로 추출하였다. 따라서 입력된 유중 가스 분석 결과에 따라 전력용 유입 변압기의 진단 결과(고장 유무 인식 및 해석)가 제시되도록 구성하였다. 제안된 신경회로망을 이용한 변압기 고장 진단 방법은 한국 전력 공사의 변압기 유중 가스 기록으로 효용성을 입증하였다. 따라서 유중 가스 분석만으로 현실성 있는 변압기 진단 및 상태 추정이 가능하게 되었고, 이것의 적용으로 적절한 유지 및 보수 대책 방안을 제시할 수 있게 되었다.

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The Fault Diagnosis of a Transformer Using Neural Network and Transfer Function

  • Park, Byung-Koo;Kim, Jong-Wook;Kim, Sang-Woo;Park, Poo-Gyeon;Park, Tae-Joon
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.127.2-127
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    • 2001
  • A transformer is one of the most important elements in the power network. Transformer faults could cause costly repairs and be dangerous to personnel. To avoid this, its reliable operation has great significance and, therefore, the diagnosis system of the transformer is necessitated. The dissolved gas-in-oil analysis (DGA) is the worldwide popular method of detecting faults such as a hot spot or partial discharges inside the transformer. DGA, however, is not a reliable technique to identify aging phenomena and mechanical faults including insulation failure, inter-turn short, etc. To overcome the drawbacks of DGA, the transfer function method is used to identify effectively these kinds of the mechanical faults. The transformer has a unique transfer function independent of the shape of the input waveform, which can be evaluated through sweep test. This transfer function changes by winding ...

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A study on failure diagnosis examples of Large oil filled transformer using dissolved gas analysis (유중가스분석법을 이용한 대용량 변압기 고장진단 사례 고찰)

  • Park, Jin-Yeub;Park, In-Kyoo;Chin, Soo-Hwan
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.740_741
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    • 2009
  • 발전소에 설치된 대용량 변압기의 고장사례에 절연유 온도에 따른 가스발생 형태, 가연성가스 성분비를 이용한 Rogers Ratio 법, 발생가스별 고장형태 및 원인분석 방법을 적용하여 고장원인을 진단하고 실제 확인된 고장원인을 고찰하였다. 사례 1은 저압측 탭권선이 과열로 손상된 사례로 온도에 따른 가스발생 형태 및 발생 가스별 고장 형태를 이용한 진단결과는 $300^{\circ}C$이상에서 과열이 된 것으로 진단되어 거의 일치하나 Rogers Ratio 법을 적용하면 $150^{\circ}C$ 정도에서 저온과열된 것으로 진단되어 약간의 차이를 보였다. 사례 2는 변압기 철심의 Burr 발생, 철심간 단락으로 인한 과열 및 아크가 발생된 고장으로 가스발생 패턴이 절연유 온도에 따른 가스발생 형태 및 사례 1과는 차이가 있고 특히, 내부 아크에 의해 발생되는 아세틸렌($C_2H_2$)은 계속 증가하는 반면 "Hot Metal Gas"중의 하나인 에탄($C_2H_6$)은 미량으로 특이한 가스발생형태를 보였다. Rogers Ratio 법과 발생가스별 고장 형태 및 원인분석법에 의한 진단결과는 일치하였다.

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Utilization of Polyunsaturated Lipids in Red Muscled Fishes 2. Concentration, Refining, and Storage Stability of Polyunsaturated Lipids of Sardine Oil (적색육어류의 고도불포화지질의 이용에 관한 연구 2. 정어리유의 고도불포화지질의 농축${\cdot}$정제 및 저장 안정성)

  • LEE Kang-Ho;LEE Byeong-Ho;JEONG In-Hak;SUH Jae-Soo;CHOI Byeong-Dae;SONG Sung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.5
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    • pp.436-445
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    • 1986
  • As the second part of the studies on the utilization of polyunsaturated lipids in sardine oil as nutritional or medical supplement, the conditions of lipid extration and concentration, refining, and storage stability of EPA-condensed sardine oil were investigated. In extraction of lipids, solvent ratios of chloroform-methanol mixture(2:1 v/v) affected the final content of unsaturated lipid in extracted oil and recovery. Stepwise solvent fractionation method at various low temperatures was effective to concentrate polyenoic acids like EPA and DHA when acetone or acetone-methanol mixture, added in the ratio of 1:5 (v/v) was applied step by step to different temperatures at 0 to $-35^{\circ}C$. Addition of 1 to $5\%$ (v/v) of water to acetone was also benefit to raise EPA content but that resulted in reducing the yield of condensed oil from $65\%\;to\;28\%$. Concentration rate of polyenoic acids by solvent fractionation in lipid-actone solution (1:5, v/v) at 0 to $-30^{\circ}C$ seemed limited to $5{\sim}8\%$ in fatty acid composition depending on the initial content of those polyenoic acids in the sardine oil. During the extraction, concentration, and alkaline treatment, oxidation was rapidly induced but oxidation products could be thoroughly removed on the process of deceleration and peroxide elimination. To stabilize the reactive polyenoic acid condensed oil during the storage, stuffing nitrogen gas was essential to expel dissolved oxygen in oil or to seal the oil from open air, and the addition of antioxidative agents as BHA and tocopherols were greatly helpful to extend the storage life.

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Antioxidative Effectiveness of Water Extract and Ether Extract in Wormwood(Artemisia montana Pampan) (쑥(산쑥)의 물 추출물과 에테르 추출물의 항산화 효과)

  • Lee, Gee-Dong;Kim, Jeong-Sook;Bae, Jae-Oh;Yoon, Hyung-Sik
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.1
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    • pp.17-22
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    • 1992
  • Water extract, and free-, ester- and insoluble phenolic acids were extracted from wormwoods. The extracts were then dissolved in equal amounts of an edible soybean oil, and the resulting substrates, portion of the soybean oil (control), 0.02% BHA and 0.02% BHT were stored in incubator at $45^{\circ}C{\pm}1.0^{\circ}C$ for 32days. Peroxide values (POV) and thiobarbituric acid (TBA) values of control and the substrates were determined during th9 storage period. The POV of control, BHA, BHT and six substrates which were contained water extracts 0.5%, 1% and 1.5%, and free-, ester- and insoluble phenolic acids after 24days of storage were 77, 43, 17, 38, 26, 34, 45, 28 and 16m mole/kg oil respectively, The TBA values after 32days of storage were 0.278, 0.170, 0.070, 0.200, 0.178, 0.235, 0.167, 0.136, 0.062, respectively, It was found that the antioxidant activity in water extracts was highest in water 1 (the substrates containing water extracts 1%). It was also found that antioxidant activities in the phenolic acids were decreased in the following order ; insoluble phenolic acids>ester form>free phenolic acids. The phenolic acids separated and tentatively identified by Gas chromatography were catechol, vanillin, umbelliferone, p-coumaric acid, ferulic acid caffeic acid, protocatechuic acid, p-hydroxy benzoic acid and syringic acid.

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Comparison of Performances of Forward Osmosis and Membrane Distillation Processes for Shale Gas Plant Water Treatment (셰일가스 플랜트 용수 처리를 위한 정삼투(FO)와 막증발(MD) 공정의 성능 비교)

  • Koo, Jaewuk;Lee, Sangho;Shin, Yonghyun;Yun, Taekgeun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.3
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    • pp.279-284
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    • 2015
  • As non-conventional oil resources such as shale gas have been widely developed, proper treatment of flowback and produced water is becoming important. However, application of conventional water treatment techniques is limited due to high concentration of pollutants such as oil and grease, organics, harmful chemicals, and inorganic ions. In this study, we examined the feasibility of using forward osmosis (FO) and air gap membrane distillation (AGMD) as novel treatment options for shale gas wastewater. Laboratory-scale FO and MD devices were fabricated and used for the experiments. Results showed that FO could be used to treat the synthetic wastewater. Using 5 M NaCl as the draw solution, the flux was approximately $6L/m^2-hr$ during the treatment of low range wastewater (TDS: 66,000 mg/L). Nevertheless, AGMD was more effective to treat high range wastewater (Total Dissolved Solid: 260,000 mg/L) than FO.

Electrochemical characteristics of active carbon prepared by chemical activation for anode of lithium ion battery (이차전지 음극용 화학적 활성화법으로 제조된 활성탄의 전기화학적 특성)

  • Lee, Ho-Yong;Kim, Tae-Yeong;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.480-487
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    • 2015
  • In this study, several kinds of active carbons with high specific surface area and micro pore structure were prepared from the coconut shell charcoal using chemical activation method. The physical property of prepared active carbon was investigated by experimental variables such as activating chemical agents to char coal ratio, flow rate of inert gas and temperature. It was shown that chemical activation with KOH and NaOH was successfully able to make active carbons with high surface area of $1900{\sim}2500m^2/g$ and mean pore size of 1.85~2.32 nm. The coin cell using water-based binder in the electrolyte of LiPF6 dissolved in mixed organic solvents (EC:DMC:EMC=1:1:1 vol%) showed better capacity than that of oil-based binder. Also, it was found that the coin cell of water-based binder shows an improved cycling performance and coulombic efficiency.

Preventive diagnostic system for 765kV Sin-Ga-Pyong and Sin-Tae-Baek substations (765kV 신가평, 신태백 변전소 예방진단시스템)

  • Kweon, D.J.;Shim, E.B.;Jung, G.J.;Kim, B.J.;Kim, J.H.;Yoo, Y.P.;Eun, J.Y.;Shin, H.C.
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1694-1697
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    • 2002
  • KEPCO is planing to adopt a preventive diagnostic system to obtain the reliability of transformer and GIS in 765kV substation. KEPRI has developed the preventive diagnostic system for 765kV substation since 1997. We used various sensors and fault detecting devices such as a dissolved gas analyzer in oil, a ultrasonic detector and LA leakage current detector, etc., and carried out adaptation tests at the both a laboratory and a site. We developed a data acquisition system, a communication control unit and a server system as well. Furthermore, monitoring program and diagnostic expert system were also developed. This paper describes the preventive diagnostic system for 765kV Sin-Ga-Pyong and Sin-Tae-Baek substations which will be operated from 2004.

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Nannochloris eucaryotum growth: Kinetic analysis and use of 100% CO2

  • Concas, Alessandro;Lutzu, Giovanni Antonio;Locci, Antonio Mario;Cao, Giacomo
    • Advances in environmental research
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    • v.2 no.1
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    • pp.19-33
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    • 2013
  • Microalgae are receiving an increasing attention because of their potential use as $CO_2$ capture method and/or as feedstock for biofuels production. On the other hand the current microalgae-based technology is still not widespread since it is characterized by technical and economic constraints that hinder its full scale-up. In such contest the growth kinetics of Nannochloris eucaryotum (a relatively unknown marine strain) in batch and semi-batch photobioreactors is quantitatively investigated with the aim of obtaining the corresponding kinetic parameters suitable for process engineering and its optimization. In particular the maximum growth rate was evaluated to be 1.99 $10^{-3}\;h^{-1}$. Half saturation concentrations for nitrates ($K_N$) and phosphates uptake ($K_P$) were evaluated as 5.4 $10^{-4}\;g_N\;L^{-1}$ and 2.5 $10^{-5}\;g_P\;L^{-1}$, respectively. Yield factors for nitrogen ($Y_N$) and phosphorus ($Y_P$) resulted to be 5.9 $10^{-2}\;g_N\;g^{-1}$ biomass and 6.0 $10^{-3}\;g_P\;g^{-1}{_{biomass}}$, respectively. The possibility of using 100% (v/v) $CO_2$ gas as carbon source is also evaluated for the first time in the literature as far as N. eucaryotum is concerned. The strain showed a good adaptability to high concentrations of dissolved $CO_2$ as well as to low pH. The lipid content under 100% $CO_2$ is about 16.16 %wt $wt^{-1}$ and the fatty acid methyl esters composition of the extracted oil is in compliance with the European regulation for quality biodiesel.