• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.2
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• pp.495-506
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• 2013

This study developed the Time-split Mixing Model (TMM) which can represent the pollutant mixing process on a three-dimensional open channel through constructing the conceptual model based on Taylor's assumption (1954) that the shear flow dispersion is the result of combination of shear advection and diffusion by turbulence. The developed model splits the 2-D mixing process into longitudinal mixing and transverse mixing, and it represents the 2-D advection-dispersion by the repetitive calculation of concentration separation by the vertical non-uniformity of flow velocity and then vertical mixing by turbulent diffusion sequentially. The simulation results indicated that the proposed model explains the effect of concentration overlapping by boundary walls, and the simulated concentration was in good agreement with the analytical solution of the 2-D advection-dispersion equation in Taylor period (Chatwin, 1970). The proposed model could explain the correlation between hydraulic factors and the dispersion coefficient to provide the physical insight about the dispersion behavior. The longitudinal dispersion coefficient calculated by the TMM varied with the mixing time unlike the constant value suggested by Elder (1959), whereas the transverse dispersion coefficient was similar with the coefficient evaluated by experiments of Sayre and Chang (1968), Fischer et al. (1979).

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.697-700
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• 2003

The SASW method is a promising and effective way of profiling ground stiffness nondestructively. This method has been successfully applied to many geotechnical sites, but significant lateral variability, embedded obstacles, and pavement lead to the low reliability. To improve these problems, the horizontal wave component has been introduced to improve the reliability of the stiffness profile determined by the SASW method. To understand dispersion character of the horizontal component wave propagation in artificial profiles, FEM analysis had been performed. Used models are homogeneous half-space and two layered half- spaced layers.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.165-170
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• 2013

An external gelation method in place of an internal gelation method applied to the fabrication process of an intermediated compound of Uranium Oxy-Carbide (UCO) kernel spheres for Very High Temperature Reactor (VHTR) fuel preparation is under development in Korea. For the preliminary experiments of the UCO kernel sphere preparation using an external gelation method, the carbon black dispersion experiments were carried out using a simulated broth solution. From the selection experiments of various kinds of carbon black through dispersion experiments in a viscous metal salt solution, Cabot G carbon black was selected owing to its dispersion stability, and the homogeneous dispersing state of carbon black particles in our system. For the effective dispersion of nano-size aggregated carbon black particles in a high viscous liquid, the carbon black particles in a metal salt solution were first de-aggregated with ultrasonic force. The mixed solution was then dispersed secondly by the use of the extremely high-speed agitation with a mechanical mixer of 6000 rpm after feeding the Poly Vinyl Alcohol (PVA) in the solution. This results in the broth solution with good stability and homogeneity alongside no further changes in physical properties.

• Journal of the Korean Geophysical Society
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• v.3 no.4
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• pp.251-260
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• 2000

Applicabilities of two numerical methods, the 2-dimensional and the 3-dimensional method, are evaluated to inverse test results obtained from the underwater SASW(Spectral -Analysis-of-Surface-Waves) method. As a result of this study, it has been found that the 2-dimensional method can supposed to be applicable for the cases where stiffness of soil layer increases gradually with depth, and the stiffness is relatively low. For the other cases, however, it has been concluded that the 3-dimensional method needs to be applied to determine realistic theoretical dispersion curves. An example is also shown that in situ soil profile underwater is estimated from experimental dispersion curves using the 3-dimensional method. As a results, it can be concluded that the underwater SASW method can be effectively applied to explore the underwater soil condition.

• Polymer(Korea)
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• v.38 no.4
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• pp.434-440
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• 2014

We prepared nanoparticles containing insoluble celecoxib by the method of solid dispersions using a spray dryer to improve solubility of celecoxib. We used PVP K30 and Eudragit EPO as water-soluble carriers for the solid dispersion, and poloxamer 407 as a surfactant. Characterization of celecoxib solid dispersion was performed by scanning electron microscope (SEM), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). The results of SEM, DSC and XRD demonstrated that celecoxib is amorphous in solid dispersion. The dissolution rate measured in intestinal juice showed that the method of solid dispersion improved celecoxib solubility as compared with a conventional drug (Celebres$^{(R)}$). In conclusion, solid dispersion formulation prepared by a spray dryer would improve the solubility of celecoxib in oral administration.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.6B
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• pp.373-378
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• 2012

In this study, a new empirical equation for the transverse dispersion coefficient has been developed based on the theoretical background in river bends. The nonlinear least-square method was applied to determine regression coefficients of the equation. The estimated dispersion coefficients derived by the new equation were compared with observed transverse dispersion coefficients acquired from natural rivers and coefficients calculated by the other existing empirical equations. From a comparison of the existing transverse dispersion equations and the new proposed equation, it appears that the behavior of the existing formula in a relative sense is very much dependent on the friction factor and the river geometry. However, the new proposed equation does not vary widely according to variation of friction factor. Also, it was revealed that the equation proposed in this study becomes an asymptotic curve as the curvature effect increases.

• 한국전산유체공학회:학술대회논문집
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• 2009.11a
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• pp.121-128
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• 2009

During a hypothetical high-pressure accident in a nuclear power plant (NPP), molten corium can be ejected through a breach of a reactor pressure vessel (RPV) and dispersed by a following jet of a high-pressure steam in the RPV. The dispersed corium is fragmented into smaller droplets in a reactor cavity of the NPP by the steam jet and released into other compartments of the NPP by a overpressure in the cavity. The fragments of the corium transfer thermal energy to the ambient air in the containment or interact chemically with steam and generate hydrogen which may be burnt in the containment. The thermal loads from the ejected molten corium on the containment which is called direct containment heating (DCH) can threaten the integrity of the containment. DCH in a NPP containment is related to many physical phenomena such as multi-phase hydrodynamics, thermodynamics and chemical process. In the evaluation of the DCH load, the melt dispersion rates depending on the RPV pressure are the most important parameter. Mostly, DCH was evaluated by using lumped-analysis codes with some correlations obtained from experiments for the dispersion rates. In this study, MC3D code was used to evaluate the dispersion rates in the APR1400 NPP during the high-pressure accidents. MC3D is a two-phase analysis code based on Eulerian four-fields for melt jet, melt droplets, gas and water. The dispersion rates of the corium melt depending on the RPV pressure were obtained from the MC3D analyses and the values specific to the APR1400 cavity geometry were compared to a currently available correlation.

• Textile Coloration and Finishing
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• v.29 no.4
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• pp.195-201
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• 2017

To study the effect of oxyfluorination on water dispersion of phthalocyanine blue(C.I. pigment blue 15:3), the pigment was oxyfluorinated using various oxygen to fluorine ratio of the reactant gas. After the oxyfluorination of the phthalocyanine blue pigment, no significant change in FT-IR spectra was observed, whereas XPS spectra showed the introduction of oxygen and fluorine containing functional groups. This suggests that the oxyfluorination of the pigment only occurred on the surface of the pigment particle and resulted in no significant change in UV-Vis spectra of the pigment. However, the oxyflurinated pigments showed improved water dispersion, compared to the non-treated pigment. Especially, when the oxygen to fluorine ratio was 47:3, the water dispersion of the oxyfluorinated pigments significantly increased, compared to the non-treated pigments. This suggests that the oxyfluorination of the phthalocyanine blue pigment has a potential to be used as a water dispersion improving method.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.391-395
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• 2013

In this study, zinc oxide (ZnO) nano powder, well known as an UV absorbing material, was synthesized with three synthetic conditions by the hydrothermal method. After ZnO nano powder was surface-modified with various silane coupling agents to improve dispersion property, a dispersion sol was prepared with dispersant for 72 h by the ball-milling of surface-modified ZnO nano powder. The dispersion sol, prepared by modifying the surface of the ZnO nano powder with an average size of about 30 nm using 3-chloropropyl trimethoxy silane, showed an excellent dispersion stability with a high UV-shielding and visible trnasparency.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.31 no.3
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• pp.8-14
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• 2003

The particle dispersion in the turbulent mixing layer has been numerically investigated to clarify the effect of the velocity ratio in the large-scale vortical structures. In this study the LES with subgrid-scale model is employed. The Lagrangian method to predict the particle motion is applied. The particles of 10, 50, 150, 200${\mu}m$ in mean diameter were loaded into the origin of the mixing layer. It is shown that the characteristics of flow and growth rate are strongly dependent on the variation of the velocity ratio. It is also shown the relationship between the Stokes number and the particle dispersion. As a result, in the case of St~1 the particle dispersion is faster than the diffustion of the flow field while in the cases of both St<<1 and St>>1 it is shown that the particle dispersion in lower than the diffusion of the flow filed.