• Title/Summary/Keyword: dispersion method

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Preparation of Ni-GDC Powders by the Solution Reduction Method Using Hydrazine and Its Electrical Properties (하이드라진을 이용한 용액환원법에 의한 Ni-GDC 미분말 합성과 전기적 특성)

  • Kim, Sun-Jung;Kim, Kang-Min;Cho, Pyeong-Seok;Cho, Yoon-Ho;Lee, Choong-Yong;Park, Seung-Young;Kang, Yun-Chan;Lee, Jong-Heun
    • Korean Journal of Materials Research
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    • v.18 no.12
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    • pp.660-663
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    • 2008
  • Ni-GDC (gadolinia-doped ceria) composite powders, the anode material for the application of solid oxide fuel cells, were prepared by a solution reduction method using hydrazine. The distribution of Ni particles in the composite powders was homogeneous. The Ni-GDC powders were sintered at $1400^{\circ}C$ for 2 h and then reduced at $800^{\circ}C$ for 24 h in 3% $H_2$. The percolation limit of Ni of the sintered composite was 20 vol%, which was significantly lower than these values in the literature (30-35 vol%). The marked decrease of percolation limit is attributed to the small size of the Ni particles and the high degree of dispersion. The hydrazine method suggests a facile chemical route to prepare well-dispersed Ni-GDC composite powders.

QSPR analysis for predicting heat of sublimation of organic compounds (유기화합물의 승화열 예측을 위한 QSPR분석)

  • Park, Yu Sun;Lee, Jong Hyuk;Park, Han Woong;Lee, Sung Kwang
    • Analytical Science and Technology
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    • v.28 no.3
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    • pp.187-195
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    • 2015
  • The heat of sublimation (HOS) is an essential parameter used to resolve environmental problems in the transfer of organic contaminants to the atmosphere and to assess the risk of toxic chemicals. The experimental measurement of the heat of sublimation is time-consuming, expensive, and complicated. In this study, quantitative structural property relationships (QSPR) were used to develop a simple and predictive model for measuring the heat of sublimation of organic compounds. The population-based forward selection method was applied to select an informative subset of descriptors of learning algorithms, such as by using multiple linear regression (MLR) and the support vector machine (SVM) method. Each individual model and consensus model was evaluated by internal validation using the bootstrap method and y-randomization. The predictions of the performance of the external test set were improved by considering their applicability to the domain. Based on the results of the MLR model, we showed that the heat of sublimation was related to dispersion, H-bond, electrostatic forces, and the dipole-dipole interaction between inter-molecules.

An Integrated Simulation Approach for Evaluating Speed Management Strategies Considering Public Health (공공보건을 고려한 시뮬레이션 연계기반 속도관리전략 평가기법 개발)

  • JOO, Shinhye;OH, Cheol
    • Journal of Korean Society of Transportation
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    • v.34 no.6
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    • pp.548-559
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    • 2016
  • Recent interests in both vehicle emissions and public health have facilitated the development of more eco-friendly transportation systems. This study proposed an integrated simulation approach for evaluating the effectiveness of speed management strategies from the various perspectives including safety, operational efficiency, and environmental compatability. Those simulation methods include driving simulation, traffic flow simulation, emissions simulation, and air dispersion simulation. An essence of the proposed simulation framework is to create the systematic connection of each simulation method toward the evaluation of effectiveness of speed management strategies. As an example, chicane and speed hump in residential area were evaluated by the proposed method. It is expected that the proposed simulation-based approach would be effectively used for the decision-making process in selecting better alternatives considering both safety and public health.

Reducing Noise Using Degree of Scattering in Collaborative Filtering System (협력적 여과 시스템에서 산포도를 이용한 잡음 감소)

  • Ko, Su-Jeong
    • The KIPS Transactions:PartB
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    • v.14B no.7
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    • pp.549-558
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    • 2007
  • Collaborative filtering systems have problems when users rate items and the rated results depend on their feelings, as there is a possibility that the results include noise. The method proposed in this paper optimizes the matrix by excluding irrelevant ratings as information for recommendations from a user-item matrix using dispersion. It reduces the noise that results from predicting preferences based on original user ratings by inflecting the information for items and users on the matrix. The method excludes the ratings values of the utmost limits using a percentile to supply the defects of coefficient of variance and composes a weighted user-item matrix by combining the user coefficient of variance with the median of ratings for items. Finally, the preferences of the active user are predicted based on the weighted matrix. A large database of user ratings for movies from the MovieLens recommender system is used, and the performance is evaluated. The proposed method is shown to outperform earlier methods significantly.

Swarm Control of Distributed Autonomous Robot System based on Artificial Immune System using PSO (PSO를 이용한 인공면역계 기반 자율분산로봇시스템의 군 제어)

  • Kim, Jun-Yeup;Ko, Kwang-Eun;Park, Seung-Min;Sim, Kwee-Bo
    • Journal of Institute of Control, Robotics and Systems
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    • v.18 no.5
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    • pp.465-470
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    • 2012
  • This paper proposes a distributed autonomous control method of swarm robot behavior strategy based on artificial immune system and an optimization strategy for artificial immune system. The behavior strategies of swarm robot in the system are depend on the task distribution in environment and we have to consider the dynamics of the system environment. In this paper, the behavior strategies divided into dispersion and aggregation. For applying to artificial immune system, an individual of swarm is regarded as a B-cell, each task distribution in environment as an antigen, a behavior strategy as an antibody and control parameter as a T-cell respectively. The executing process of proposed method is as follows: When the environmental condition changes, the agent selects an appropriate behavior strategy. And its behavior strategy is stimulated and suppressed by other agent using communication. Finally much stimulated strategy is adopted as a swarm behavior strategy. In order to decide more accurately select the behavior strategy, the optimized parameter learning procedure that is represented by stimulus function of antigen to antibody in artificial immune system is required. In this paper, particle swarm optimization algorithm is applied to this learning procedure. The proposed method shows more adaptive and robustness results than the existing system at the viewpoint that the swarm robots learning and adaptation degree associated with the changing of tasks.

Histomorphometric evaluation of the implant designed by shape optimization technique (성견 경골에서 최적화 기법을 이용하여 형상 개선된 임프란트의 조직계측학적 분석)

  • Kwon, Hyuk-Rak;Moon, Sang-Kwon;Shim, Joon-sung;Ahn, Sei-young;Lee, Hun;Kim, Han-Sung;Choi, Seong-ho;Kim, Chong-Kwan
    • Journal of Periodontal and Implant Science
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    • v.34 no.1
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    • pp.35-48
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    • 2004
  • Since the occlusal loading is transmitted to the surrounding bone, the success of an implant treatment is closely related to the distribution of the stress on the implant. The finite element analysis method is often used in order to produce a model for dispersion of stress. Assessment of the success of the implant is usually based on the degree of osseointegration which is a bone and implant surface interface. Implant used in this research was designed through the method of shape optimization after the stress on implant was anaylzed by the finite element analysis method. This study was pertinently assessed by a clinical, histologic, histomorphometric analysis after the shape optimized implant was installed on beagle dog tibia. The results are as follows 1. It clinically showed a good result without mobility and imflammatory reaction. 2. Implant was supported by dense bone and bone remodeling showed on the surrounding area of the implant 3. The average percentage of bone-implant contact was 58.1%.The percentage of bone density was 57.6%. Having above results, shape optimized implant showed the pertinence through clinical and histologic aspects. However, to use the shape optimized implant, the further experiment is required for finding problems, improvement.

Facile Synthesis of Pt Nanoparticle and Graphene Composite Materials: Comparison of Electrocatalytic Activity with Analogous CNT Composite

  • Lee, Jihye;Jang, Ho Young;Jung, Insub;Yoon, Yeoheung;Jang, Hee-Jeong;Lee, Hyoyoung;Park, Sungho
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.1973-1978
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    • 2014
  • Here, we present a facile method to synthesize Pt nanoparticles (NPs) and graphene composite materials (Pt/G) via vacuum filtration. Anodic aluminum oxide (AAO) templates were used to separate Pt/G composite and liquid phase. This method can be used to easily tune the mass ratio of Pt NPs and graphene. Pt NPs, graphene, and carbon nanotubes (CNTs) as building blocks were characterized by a variety of techniques such as scanning electron microscopy, UV-Vis spectroscopy, and Raman spectroscopy. We compared the electrocatalytic activities of Pt/G with Pt NP and CNT films (Pt/CNT) by cyclic voltammetry (CV), CO oxidation, and methanol oxidation. Pt/G was much more stable than pure Pt films. Also, Pt/G had better electrochemical activity, CO tolerance and methanol oxidation than Pt/CNT loaded with the same amount of Pt NPs due to the better dispersion of Pt NPs on graphene flakes without aggregation. We further synthesized Au@Pt disk/G and Pt nanorods/G to determine if our synthetic method can be applied to other NP shapes such as nanodisks and nanorods, for further electrocatalysis studies.

Shape Control of Silica-Polymethylsilsesquioxane (PMSQ) Composites by Varying Ratios of Precursors (전구체 비율에 따른 실리카-폴리메틸실세스퀴옥세인(PMSQ) 복합분체의 형태 제어)

  • Choi, Yigun;Choi, Jongmin;Kim, Hyojoong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.45 no.4
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    • pp.409-414
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    • 2019
  • Silica and polymethylsilsesquioxane (PMSQ) are silicone powders widely used as cosmetics. We synthesized silica-PMSQ composites via sol-gel method using tetraethoxysilane (TEOS) and methyltrimethoxysilane (MTMS) as precursors of silica and PMSQ, respectively. Shape of the composites was controlled by varying the ratios of TEOS and MTMS, which were used as silane monomers. Silica-PMSQ composites showed three different shapes, which were sphere-shape, raspberry- shape, and donut- shape. All of them had soft touch, easy water dispersion, and soft focus effect in common. However, each shape showed some differences in sense of use, adhesion, and strength of the soft focus effect. Raspberry-shape composite had the strongest soft focus effect, donut-shape one had the strongest adhesion, and sphere-shape one had the best in softness. Thus, it is concluded that by varying the ratios of TEOS and MTMS silica-PMSQ composites could be easily synthesized into different shapes, providing various functions. This method can be applied to manufacture functional cosmetics.

An Analysis of A Circularly Polarized Conformal Microstrip Parch Antenna Using The Unsplit Anisotropic Perfectly Matched Layer(UAPML) (비분리형 비등방성 완전 정합층(UAPML)을 이용한 원형편파 등각 마이크로스트립 패치 안테나의 해석)

  • 박동희;김정기
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.6
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    • pp.813-823
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    • 1998
  • This paper analyzed the circularly polarized conformal microstrip patch antennal using the unsplit anisotropic perfectly matched layer(UAPML) method. Also, this paper are treated effectively the edge and corner parts on the 3 dimensional UAPML. Especially, to analyze microstrip patch antennas with the coaxial feeder line, it was applied to mixed the UAPML with Mur's first order absorbing boundary condition. Therefore this paper suggest the new the method to mix the UAPML with Mur's first order absorbing boundary condition. The results show the time responses of electromagnetics $E_z$ and $H\chi'$, input impedances of coaxial cable and radiation patterns of strip parchs on the single and the array patchs with central frequencies 1.575 GHz, 1.778 GHz and 4.8 GHz in L-band and C-band for mobile communication. The results of this paper shows that its results was compared the Mur's first order abc and mixed the second order dispersion boundary condition(SDBC) with the Mur's first order absorbing boundary condition. In accordance with, the validity of the method is confirmed.

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Approaching Target above Ground Tracking Technique Based on Noise Covariance Estimation Method-Kalman Filter (잡음 공분산 추정 방식을 적용한 칼만필터 기반 지면밀착 접근표적 추적기법)

  • Park, Young-Sik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.10
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    • pp.810-818
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    • 2017
  • This paper presents the approaching target above ground tracking based on Kalman filter applied to the proximity sensor for the active defense system. The proximity sensor located on the front of the countermeasure is not easy to detect when the anti-tank threat enters a fragment dispersion range due to limited antenna beamwidth. In addition, it is difficult for the proximity sensor to detect the anti-tank threat accurately at a terrestrial environment including various clutters. To solve these problems, this study presents the approaching target above ground tracking based on Kalman filter and applies the novel estimation method for a noise covariance matrix to improve a tracking performance. Then, a high tracking performance of Kalman filter applied the proposed noise covariance matrix is presented through field firing test results and the validity of the proposed study is examined.