• Title/Summary/Keyword: dispersion and discharge

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Electrochemical Properties of Acetylene Black/Multi-walled Carbon Nanotube Cathodes for Lithium Thionyl Chloride Batteries at High Discharge Currents

  • Song, Hee-Youb;Jung, Moon-Hyung;Jeong, Soon-Ki
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.430-436
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    • 2020
  • Lithium thionyl chloride (Li/SOCl2) batteries exhibit the highest energy densities seen in commercially available primary batteries because of their high operating voltages and discharge capacities. They are widely used in various extreme environments; however, they show signs of degradation at high discharge currents. The discharge performance of Li/SOCl2 is considered to be greatly dependent on the carbon materials used in the cathode. Therefore, suitable carbon materials must be chosen to improve discharge performances. In this work, we investigated the discharge properties of Li/SOCl2 batteries in which the cathodes contained various ratios of acetylene black (AB) and multi-walled carbon nanotubes (MWCNTs) at high discharge currents. It was confirmed that the MWCNTs were effectively dispersed in the mixed AB/MWCNT cathodes. Moreover, the discharge capacity and operating voltage improved at high discharge currents in these mixed cathodes when compared with pure AB cathodes. It was found that the mesopores present in the cathodes have a strong impact on the discharge capacity, while the macropores present on the cathode surface influence the discharge properties at high discharge rates in Li/SOCl2 batteries. These results indicate that the ratio of mesopores and macropores in the cathode is key to improving the discharge performance of Li/SOCl2 batteries, as is the dispersion of the MWCNTs.

현장 규모 biobarrier의 수리학적 특성과 기초 설계

  • 최영화;오재일;왕수균;배범한
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.426-430
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    • 2003
  • Subsurface biobarrier technology has potential applications to contain contaminated groundwater and/or to degrade toxic pollutants in groundwater. Effective biobarrier formation is need to assess of hydrogeologic characteristics and to conduct practical operation strategies and design based on this prior to design biobarrier. Thus, in this study, we examined hydrogeologic characteristics in biobarrier construction site. Hydraulic conductivities which calculated from slug test data have shown difference with each well as 1.20$\times$10$^{-3}$ -6.00$\times$10$^{-5}$ cm/sec. Tracer test is a method in which concentration of tracer solution during withdrawal in each well by vacuum extraction system is measured with time. Tracer solution was continuously injected by constant head tank. Measured tracer concentration versus time data were fitted to analytical solution of convection dispersion equation (CDE). The fitting data of CDE to the measured data at each extraction well yielded were 0.61cm/min(pore velocity), 5.38$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.47 1/min and 1.75cm/min(pore velocity), 36.34$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.93 1/min. As a result, we acquired fundamental parameters which need to design biobarrier and operation strategies.

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Analysis of Partial Discharge Pattern in XLPE/EDPM Interface Defect using the Cluster (군집화에 의한 XLPE/EPDM 계면결함 부분방전 패턴 분석)

  • Cho, Kyung-Soon;Lee, Kang-Won;Shin, Jong-Yeol;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.203-204
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    • 2007
  • This paper investigated the influence on partial discharge distribution of various defects at the model power cable joints interface using K-means clustering. As the result of analyzing discharge number distribution of ${\Phi}-n$ cluster, clusters shifted to $0^{\circ}\;and\;180^{\circ}$ with increasing applying voltage. It was confirmed that discharge quantity and euclidean distance between centroids were increased with applying voltage from the analyzing centroid distribution of ${\Phi}-q$ cluster. The degree of dispersion was increased with calculating standard deviation of ${\Phi}-q$ cluster centroid. The tendency both number of discharge and mean value of ${\Phi}-q$ cluster centroid were some different with defect types.

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Characteristics of Rainfall Protection for Stacks (굴뚝의 우수유입방지 특성)

  • Kim, Jong-Chul;Kim, Tae-Hyeung
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.10 no.1
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    • pp.18-31
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    • 2000
  • A stack must be designed to 1) reduce or eliminate rainfall or snowfall into a industrial exhaust system, 2) minimize a resistance to flow, 3) maximize the vertical dispersion of the contaminated air and 4) minimize maintenance. The weather cone stacks and the elbow-type stacks are very popular in Korea. But they add some resistance to the exhaust system resulting in reduction of air flow rate, but also deflect the noxious contaminants downward in undiluted form. To solve these problems, ACGIH (American Conference of Governmental Industrial Hygienists) suggested the vertical discharge stack with concentric space between the upper stack with larger diameter and the lower stack with smaller diameter. The preliminary test showed that the vertical discharge stacks did not have the good rainfall protection. The reversed cone were newly devised to satisfy the requirements for the good stack. Subsequently, the amount of rain being penetrated through the stacks was measured while the stacks were simultaneously and naturally exposed to rain in the same area outside. Test results indicate that none of the stacks tested completely exclude rain. The efficiency of rainfall protection and the pressure loss coefficient were compared. The temporary conclusion was reached to the point that the reversed cone stack is the best one. Further research is underway.

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Transverse Dispersion of Pollutant Solute in the Nonuniform Natural Channel - By Using the Cumulative Discharge Model - (불규칙한 자연하천에서 오염물질의 횡확산 - 누적유량 Model을 이용하여 -)

  • 강주복;박상길
    • Water for future
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    • v.23 no.2
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    • pp.213-225
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    • 1990
  • A mathematical model is presented for predicting the steady state two-demensional distribution of solute concentration in the meandering nonuniform natural channel. The dispersion equation derived herein employs the transverse cumulative discharge as an independent variable replacing the transverse distance and that it is developed in an orthogonal curvilinear coordinnate system which follows the flow direction of natural channel. The prediction from the results of numerical model are compared with laboratory experiment data. It is found that results from simulation and experiments are in good agreement.

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Diffusion Modelling of Cold Discharge on Coastal waters (연안역의 냉배수 확산모델링)

  • Kim, Jong-Kyu;Kim, Jong-Hwa
    • Journal of Fisheries and Marine Sciences Education
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    • v.13 no.2
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    • pp.132-145
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    • 2001
  • The cold discharge from LNG(liquefied natural gas) terminal makes the water temperature around the terminal fall down. This temperature reduction may result in serious changes on marine ecosystem of the coastal area. The numerical model experiments of material transport and tidal circulation in the inner bay, Chinhae Bay are investigated in the dispersion of cold discharge from LNG terminal. The condition of ambient water is exposed to tide, tidal current and cold discharge temperature. Simple numerical model experiments highlight the importance of tidal circulation and cold discharge at each case and some results are discussed. The results of this study can be used as the guideline for the site selection of LNG terminals and long-term marine environmental impact assessment.

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The Literatual Study on Pathologic Change Cognition to the Liver Disease (간장의 병리변화 인식에 대한 문헌적 고찰)

  • Lee Young Su;Kwack Jeong Jin;Lee Gang Nyoung;Choi Chang Won;Kim Hee Chul
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.4
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    • pp.630-636
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    • 2002
  • After The Yellow Emperor's Canon of Internal Medicine, The text researches of pathologic change to the liver disease concluded the next, 1, The category of liver-disease(肝病) include the Symptoms of abnormality due to vital energy and blood motion, emotion and intention, muscular and reproductive function, and legions around descending liver channel. 2. In the theory that Liver-Yang energy(肝陽氣) is always overproducing, Liver-Yin blood(肝陰血) is always lacking, pathologic characteristics for liver disease is functional change of malfunction of the use of body(體用失調), So nourishing the liver and kidney is used for the principal aspects of a disease. regulating and calm the liver is used for the secondary aspects of a disease as the treatment plan, 3. If malfunctioning of the functions of dispersion and discharge(疏泄), Iiver-energy(肝氣) is becoming degected, So overproduct and overflow of ascent and exhalation of liver-yang(肝陽) is becoming blood are ascending following energy. complete usage of Yin-blood(陰血) is responsible for some kinds of mass formed by blood stasis in the early stage of pathogenesis of liver disease syndrome of the energy system as the progession of disease extravasated blood is forming. the pathologic characteristics is appeared loss of control of the vital energy and blood(體用失調) at the liver disease. 4. Sthenia-syndrome of liver(肝實證) and liver-heat syndrome(肝熱證) is appered that overproducing and overflow of dispersion(疏泄太過) and discharge is responsible for overfunctioning of liver disease or some kinds of heat syndrome such as liver fire(肝火), Sthenia of liver-yang(肝陽上亢), the syndromes of sthenic liver heat(肝實熱) are appered. deficiency of the liver(肝虛證) and cold syndrome of liver(肝寒證) is classified pathologic characteristics of cold and heat, deficiency and excess that regression of sensory, motor, mental due to lack of dispersion and discharge(疏泄不及), or intruding of the cold miasma, are degected. 5. The liver is close relation of physiologic function and internal organ such as spleen, stomach, lung, heart, kidney, gall bladder by the meridian channels, because of property of wind Zang, rapid progession is classified by phthologic charateristics.

Development of a Dispersion Analysis Program for the Liquid Rocket Engine and its Application (액체로켓 엔진 성능 분산해석 프로그램의 개발 및 응용)

  • Park, Soon-Young;Nam, Chang-Ho;Seol, Woo-Seok
    • Aerospace Engineering and Technology
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    • v.10 no.1
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    • pp.63-69
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    • 2011
  • In this study, we developed a dispersion analysis program of the gas-generator cycle liquid propellant rocket engine by expanding the mode analysis software(GEMAT). The performance dispersions of an engine that are arisen from the internal dispersion factors of engine's sub-components were formulated and solved to find the effects of each dispersion factor. We were also able to present the calculation method to find the required pressure margin for the compensation of those dispersion to satisfy the required performances of engine. Using this method, we could propose a novel procedure of compensating during the ground firing test which would induce the performance improvement by lessening the pumps discharge pressures or augmenting the combustion chamber pressure.

Surface Modification of Multi-walled Carbon Nanotubes for Enhancement of Dispersion and Electrochemical Properties

  • Kim, Young-Ja;Zhang, Wentao;Lee, Hong-Ro;Kim, Jong-Hyee
    • Journal of the Korean institute of surface engineering
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    • v.41 no.5
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    • pp.194-198
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    • 2008
  • Several methods for improving dispersion of carbon nanotubes (CNTs) have been investigated. CNTs modified by acids and hydrogen peroxide ($H_2O_2$) showed improved dispersion. From SEM micrographs and photos of dispersion, CNTs modified with nitric acid and $H_2O_2$, showed no agglomeration in solution even standing for 4 months, which means successfully improved dispersion property. TEM micrographs of surface modified single CNT treated with 69% $HNO_3$ in boiling acid solution as the optimum method were obtained. For confirmation of CNTs' application to EDLC electrode materials, characteristics of EDLC have been analyzed by cyclic voltammetry curve, specific capacitance of unit cell, electrode discharge curves and AC impedance curve. From the results, it could be confirmed that electrochemical properties of CNTs were enhanced after surface modification with 69% $HNO_3$ acid treatment.

Numerical Investigation of Transverse Dispersion in Natural Channels (자연하천에서 오염물질의 횡확산에 관한 수치모형)

  • 서일원;김대근
    • Water for future
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    • v.28 no.5
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    • pp.151-162
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    • 1995
  • A two-dimensional stream tube dispersion model is developed to simulate accurately transverse dispersion processes of pollutants in natural channels. Two distinct features of the stream tube dispersion model derived herein are that it employs the transverse cumulative discharge as an independent variable replacing the transverse distance and that it is developed in a natural coordinate system which follows the general direction of the channel flow. In the model studied, Eulerian-Lagrangian method is used to solve the stream tube dispersion equation. The stream tube dispersion equation is decoupled into two components by the operator-splitting approach; one is governing advection and the other is governing dispersion. The advection equation has been solved using the method of characteristics and the results are interpolated onto Eulerian grid on which the dispersion equation is solved by centered difference method. In solving the advection equation, cubic spline interpolating polynomials is used. In the present study, the results of the application of this model to a natural channel are compared with a steady-state flow measurements. Simulation results are in good accordance with measured data.

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