• 공업화학
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• 제8권1호
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• pp.29-38
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• 1997

고농축에멀션중합방법을 이용하여 친수성-친유성 고분자복합소재를 합성하였다. w/o 형태의 고농축에멀션의 연속상은 styrene이며, 분산상은 수용성 acrylamide용액으로 분산상의 부피분율이 0.74 이상이다. 중합온도에서 에멀션의 안정성에 미치는 주요 요인들로는 친유성액체와 친수성액체의 물리화학적 특성인 극성, pH, 이온세기 및 계면활성제의 종류와 농도가 있다. 친유성액체와 친수성액체 사이의 계면장력이나 친수성액체와 계면활성제 수용액사이의 계면장력에 있어 계면장력의 값이 큰 경우는 높은 에멀션의 안정성을 나타낸다. 계면활성제의 HLB가 3.0~9.0 경우와 계면활성제의 농도가 CMC가 이상에서 에멀션이 높은 안정성을 나타낸다. 전자현미경을 이용한 조사에 의하며 복합재료는 분산상의 Poly acrylamide입자가 망상구조의 얇은 polystyrene필림에 의해 분리된 구조로 이루어져 있음을 보여주고 있다. 고농축에멀션에서부터합성된 고분자복합재료막은 물-에탄온 혼합물에서 물에 대해서 높은 선택성을 나타내었으며, 또 에탄올의 농도가 증가할수록 막의 선택도는 증가하였으나 투과속도는 감소함을 나타내었다.

• 폴리머
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• 제36권5호
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• pp.579-585
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• 2012

고분자 발포체에 전도성을 부여하기 위하여 고내상 에멀젼 중합법을 활용하여 폴리스티렌/탄소나노튜브 미세기공 발포체를 제조하였다. 본 연구에서는 고내상 에멀젼의 안정성과 중합된 미세기공 발포체의 전기 전도도를 향상시키기 위하여 탄소나노튜브의 개질, 계면활성제의 함량 및 분산 시간에 따른 영향을 고찰하였다. 탄소나노튜브는 분산이 용이하도록, 분산상인 수상에는 산처리 및 계면활성제로 분산하여 사용하였고 연속상인 유상에는 유기 작용기로 표면 개질하여 사용하였다. 탄소나노튜브의 분산성은 제조한 발포체의 전기 전도도 차이로 확인할 수 있었다. 계면활성제로 분산한 미처리 탄소나노튜브를 수상에 첨가한 경우 전기 전도도 향상에는 효과적이었지만 약간 수축된 형상의 발포체가 제조되었다. 유기 개질한 탄소나노튜브를 유상에 첨가한 경우 안정한 발포체를 얻을 수 있었으나 전기 전도도 향상에는 한계가 있었다.

• 열처리공학회지
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• 제14권5호
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• pp.286-291
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• 2001

This study was carried out to investigate the influence of ${\sigma}$ phase on the microstructure and mechanical properties in super duplex stainless steel. The precipitation of ${\sigma}$ phase during isothermal heat treatment showed the type S curves with a certain incubation period. The precipitation of ${\sigma}$ phase was precipitated at ferrite phase and interface of ferrite and austenite. Under the state of isothermal transformation, the precipitation of ${\sigma}$ phase was stimulated by applied stress. With increasing of volume fraction of precipitated ${\sigma}$ phase, tensile strength was increased and elongation was decreased with linear relationship, while in case of precipitated ${\sigma}$ phase was 5% over, impact value was rapidly decreased.

• 한국대기환경학회지
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• 제24권6호
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• pp.674-681
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• 2008

Silver as a metal catalyst has been used to remove odorous compounds. In this study, silver particles in nano sizes ($5{\sim}30nm$) were prepared on the surface of $NaHCO_3$, the supporting material, using a sputtering method. The silver nano-particles were dispersed by dissolving $Ag-NaHCO_3$ into water, and the dispersed silver nano-particles in the aqueous phase was applied to remove inorganic odor compounds, $NH_3$ and ${H_2}O$, in a scrubbing reactor. Since ammonia has high solubility, it was removed from the gas phase even by spraying water in the scrubber. However, the concentration of nitrate (${NO_3}^-$) ion increased only in the silver nano-particle solution, implying that the silver nano-particles oxidized ammonia. Hydrogen sulfide in the gas phase was rapidly removed by the silver nano-particles, and the concentration of sulfate (${SO_4}^{2-}$) ion increased with time due to the oxidation reaction by silver. As a result, the silver nano-particles in the aqueous solution can be successfully applied to remove odorous compounds without adding additional energy sources and producing any harmful byproducts.

• Journal of Advanced Marine Engineering and Technology
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• 제23권5호
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• pp.687-694
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• 1999

This study was conducted to develop new drying process for automatic control and marine engi-neering system. Air-water tests were carried out to investigate dryer performance. The dispersed flow in he dryer test apparatuses was also simulated by using a numerical code which solves the Dittus-Boelter equation for continuous liquid phase and the Reynolds equation of droplet motion for continuous liquid phase and the Reynolds equation of droplet motion for dispersed phase to predict droplet removal efficiency. Proper conditions for dehumidification were optimized by response ambient conditions. When the selected indexes were constrained in the range of 85-98% moisture content above $15^{\circ}$ and more than mass flow rates of moist air 750kg/h. The numerical results were compared with the experimental data pertaining to the removal effi-ciency at chamber stage and overall pressure drop along concentric tubes Good agreement was obtained as for the efficiency while relatively poor agreement was obtained for the relative humidity. The results also showed that the efficiency depended strongly on the relative humidity at the inlet condition which indicated the importance of estimating the heat exchanger length. Effects of some design parameters in both removal efficiency and breakthrough onset condition are discussed.

• Korea-Australia Rheology Journal
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• 제18권4호
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• pp.183-189
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• 2006

High internal phase emulsions are highly concentrated emulsion systems consisting of a large volume of dispersed phase above 0.74. The rheological properties of high internal phase water-in-oil emulsions were measured conducting steady shear, oscillatory shear and creep/recovery experiments. It was found that the yield stress is inversely proportional to the drop size with the exponent of values between 1 and 2. Since the oil phase contains monomeric species, microcellular foams can easily be prepared from high internal phase emulsions. In this study, the microcellular foams combining a couple of thickeners into the conventional formulation of styrene and water system were investigated to understand the effect of viscosity ratio on cell size. Cell size variation on thickener concentration could be explained by a dimensional analysis between the capillary number and the viscosity ratio. Compression properties of foam are important end use properties in many practical applications. Crush strength and Young's modulus of microcellular foams polymerized from high internal phase emulsions were measured and compared from compression tests. Of the foams tested in this study, the foam prepared from the organoclay having reactive group as an oil phase thickener showed outstanding compression properties.

• 한국가시화정보학회지
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• 제18권3호
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• pp.23-34
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• 2020

Two-phase flow and heat transfer characteristics during the reflood phase of a single heated rod in the KHU reflood experimental facility were examined. Two-phase flow behavior during the reflooding experiment was carefully visualized along with transient temperature measurement at a point inside the heated rod. By numerically solving one-dimensional inverse heat conduction equation using the measured temperature data, time-resolved wall heat flux and temperature histories at the interface of the heated rod and coolant were obtained. Once water coolant was injected into the test section from the bottom to reflood the heated rod of >700℃, vast vapor bubbles and droplets were generated near the reflood front and dispersed flow film boiling consisted of continuous vapor flow and tiny liquid droplets appeared in the upper part. Following the dispersed flow film boiling, inverted annular/slug/churn flow film boiling regimes were sequentially observed and the wall temperature gradually decreased. When so-called minimum film boiling temperature reached, the stable vapor film between the heated rod and coolant was suddenly collapsed, resulting in the quenching transition from film boiling into nucleate boiling. The moving speed of the quench front measured in the present study showed a good agreement with prediction by a correlation in literature. The obtained results revealed that typical two-phase flow and heat transfer behaviors during the reflood phase of overheated fuel rods in light water nuclear reactors are well reproduced in the KHU facility. Thus, the verified reflood experimental facility can be used to explore the effects of other affecting parameters, such as CRUD, on the reflood heat transfer behaviors in practical nuclear reactors.

• 한국세라믹학회지
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• 제31권4호
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• pp.443-447
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• 1994

Compacts of mixed SiO2-Si powder were liquid phase sintered at 145$0^{\circ}C$ for up to 60 min in a hydrogen atmosphere. In contrast to the conventional microstructures of liquid phase sintered materials, the specimens showed that the solid phase of SiO2 formed a matrix while the liquid phase of Si was the dispersed in the solid matrix. The dispersion of liquid Si pockets was attributed to the high wetting angle of liquid Si on solid SiO2. Because of relatively high solubility of SiO2 in liquid Si at 145$0^{\circ}C$, SiO2 particles accommodated their shape via a solution-reprecipitation process. The liquid Si pockets grew by coalescing with their neighbour pockets. In the latter stage of the sintering, plate-shape grains appeared in the liquid Si pockets. The grains were SiO2 phase precipitated from the liquid Si which was oversaturated with oxygen during cooling to room temperature. By the formation and subsequent removal of the gaseous SiO phase due to the reaction between SiO2 and Si, the specimens became porous.

• 멤브레인
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• 제14권3호
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• pp.218-229
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• 2004

SPG (Shirasu porous glass) 관형 막이 설치된 회분식 막유화 장치를 사용하여 단분산 칼슘 알지네이트 미립자를 제조하기 위한 막유화 공정변수의 최적조건을 결정하였다. 막유화의 공정변수로는 연속상에 대한 분산상의 비율, 알지네이트 농도, 유화제의 종류와 농도, 안정제 농도, 가교제 농도, 교반속도, 막간 압력차 및 SPG 막의 세공크기로 설정하고, 이들 변수가 제조된 알지네이트 미립자의 입자 크기와 분포에 미치는 영향을 검토하였다. 막유화의 공정변수들 중에서 연속상에 대한 분산상의 비율, 막간 압력차 그리고 알지네이트 농도가 증가할수록 미립자의 크기가 증가하였다. 반면 유화제의 농도, 교반속도 그리고 가교제의 농도가 증가할수록 미립자의 크기가 감소하였다. 세공 크기 $2.9{\mu}\textrm{m}$인 SPG막을 사용한 경우 막유화의 공정변수 조절을 통해 최종적으로 평균 입자 크기 $6{\mu}\textrm{m}$, 크기 분산도 1.1인 단분산 알지네이트 미립자의 제조가 가능하였다.

• 폴리머
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• 제24권6호
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• pp.820-828
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• 2000

본 연구에서는 블렌드 내의 분산상을 잘 발달된 판상 구조로 발현시켜 폴리프로필렌 (PP)/에틸렌 비닐알코올 공중합체 (EVOH) 블렌드의 차단 성질을 향상시키기 위하여 필름 제조 공정으로써 이축연신 공정을 사용하였다. 분산상 수지와 연속상 수지의 점도비로부터 용융 압출 공정시 변형의 정도를 파악하기 위하여 각 수지의 유변물성을 측정하였으며, 상용화제 함량과 연신 배율 및 연신 온도 등이 이축연신 블렌드 필름의 산소 투과도와 모폴로지에 미치는 영향을 조사하였다. l5 wt%의 EVOH를 첨가한 PP/EVOH 블렌드 필름의 산소차단성은 EVOH 분산상이 이축연신에 의해 넓은 면적의 판상구조로 발현되어 순수 PP에 비해 10배 정도까지 증가한 것으로 나타났다. 모폴로지를 조절하친 두 상간의 계면결합력을 증진시키기 위하여 PP-g-MAH와 ionomer를 사용한 결과, 차단 효과를 효과적으로 향상시키기 위해서는 상용화제를 블렌드에 최적의 함량으로 첨가해야 한다는 사실을 알 수 있었다. 또한 높은 연신 배율과 연신 온도로 이축연신하여 제조된 블렌드 필름에서 더욱 뚜렷한 판상 모폴로지가 관찰되었으며, 차단효과는 증가한 것으로 나타났다.