• Title/Summary/Keyword: dispersed concentration

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Fabrication of Discontinuous Al2O3-Dispersed TZP Fibers by a Sol-Gel Method (졸-겔법을 이용한 Al2O3가 분산된 TZP 단섬유의 제조)

  • Sim, Soo-Man
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.56-60
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    • 2015
  • Discontinuous, polycrystalline $Al_2O_3$-dispersed TZP fibers were prepared by the centrifugal spinning of a colloidal $ZrO_2$ sol containing Y and Al nitrates and poly(vinyl alcohol). Factors affecting the rheological properties of the sols, such as sol concentrations, aging, and the amounts and types of additives, were investigated by measuring the shear viscosities. The flow characteristics of the sols were studied in relation to the spinnability by measuring the viscosity with respect to the shear rate. The spinnability was obtained through the addition of a polymer which increases the viscosity to a range of optimum viscosity values for spinning. Aging the sols containing the additives did not noticeably change the sol viscosities at room temperature up to 30 days. The flow behavior of the spinnable sols progressively changed from nearly Newtonian to pseudoplastic with an increase in the sol concentration.

Electrically controllable polymer-dispersed liquid crystal (전기적 스위칭이 가능한 고분자 분산형 액정 제작 및 동적 홀로그램 기록 특성)

  • 성기영;경천수;이영락;최병철;곽종훈;최옥식;이윤우
    • Korean Journal of Optics and Photonics
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    • v.10 no.6
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    • pp.494-499
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    • 1999
  • We report on the results of holographic transmission grating that can be controlled by the applied AC electric field. We have fabricated a polymer-dispersed liquid crystal material that composed of multifunctional acrylate monomer blended with the liquid crystal mixture E7. To investigate an electro-optic properties of fabricated HPDLC, diffraction efficienties (DE) are measured as a fuction of applied electric field and density of liquid crystal. Maximum DE of about 70% is obtained about 30 wt% of LC concentration at a zero field. We have also shown that optical image was recorded in the tllm, and then the reconstructive image was switchable with the applied electric fields. ields.

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Mechanical Properties and Microstructure of Aluminum Alloys with Dispersed Nanoscale Quasicrystalline Particles

  • Fujita, Masashi;Kimura, Hisamichi;Inoue, Akihisa
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.708-709
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    • 2006
  • New Al-based alloys with very high ultimate tensile strength were developed in high Al concentration range of 91-95 at.% for Al-Fe-Cr-Ti-M (M: Co and Mo) systems and Al-Fe-Cr-Mo-Ti-Co system by the dispersion of nanoscale quasicrystalline particles in Al phase. The effect of adding elements, M was discussed in the viewpoint of stability of super-cooled liquid state and formation ability of quasicrystalline phase. The P/M Al-Fe-Cr-Ti-M alloys with dispersed nanoscale quasicrystalline particles exhibited ultimate tensile strength of 350MPa at 573K and 200MPa at 673K.

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Preparation of the Narrow-dispersed Microcapsules containing Electronic Ink : Influence of Surfactant and Stirring Rate

  • Park, Youn-Jung;Kim, Chul-Am;Suh, Kyung-Soo;Kang, Seung-Youl;Park, Soo-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.914-916
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    • 2009
  • Using gelatin and acacia as wall and electronic ink as core substance, microcapsules were prepared by complex coacervation to fabricate a flexible electronic paper display. In order to obtain the microcapsules in a narrow dispersed distribution, we focus on the interfacial tension between the hydrophobic electrophoretic ink and an aqueous polyelectrolyte solution, through controlling sodium dodecyl sulphate (SDS) concentration and stirring rate. The existence of anionic surfactant of SDS not only decreases the droplet diameters, but also reduces the diameter size distribution. And, as the stirring rate is increased, the average size of microcapsule is also decreased.

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Preparation of Au fine particle dispersed $TiO_2$ film by sol-gel and photoreduction process

  • Hyun, Buh-Sng;Kim, Byeong-Il;Kang, Won-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.103-111
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    • 1998
  • Au fine particle dispersed TiO2 film was prepared on silica glass substrate by sol-gel dip and firing process. The films were fabricated from the system of titanium tetraisoproxie-EtOh-HCl_H2O-hydrogen tetrachloroaurate(III) tetrahydrate. The conditions for the formation of the clear solution and dissolving high concentration of Au compound were examined. And a photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix TiO2 and variation of Au particle with UV irradiation were investigated by XRDA, SEM, TEM and UV-visible spectrophotometer. And the effect of CPCl(Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

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Printed black internal conducting electrodes for flexible bistable cholesteric displays

  • Atkuri, H.M.;Lee, D.W.;Choi, B.O.;Kim, C.H.;West, J.L.
    • Journal of Information Display
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    • v.12 no.2
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    • pp.97-99
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    • 2011
  • We report flexible, bistable cholesteric displays utilizing polyester (PET) substrates with printed internal black electrodes. The black electrodes consist of carbon ink dispersed in butyl carbitol using a patented roll-to-roll gravure-offset printing. A transparent conducting polymer printed on PET serves as the counter electrode. The electro-optic material is a chiral nematic mixture dispersed in a low-concentration polymer binder. The device can be switched between scattering (black) and reflective (vibrant green) states upon application of an electric pulse. The internal black electrode enhances the contrast of the display and simplifies the roll-to-roll manufacture of flexible displays.

Influence of the Distribution of Wind Velocity and Mist Concentration for the Improvement of Efficiency with an Electrostatic Precipitator (전기집진장치의 효율 개선을 위한 풍속 분포 및 입자농도 분포의 영향)

  • 임헌찬;이덕출
    • Journal of the Korean Society of Safety
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    • v.13 no.4
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    • pp.155-161
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    • 1998
  • Recently, there are widely needs of small scale electrostatic precipitator(ESP) in machine shop and other factories. Since the space of such factories is limited, the improvement of collection efficiency is predominant subject. In this study, we examine the influence of distribution of wind velocity and oil mist concentration inside the ESP in order to improve the performance of the ESP. The distribution of wind velocity and mist concentration is measured respectively in a cross-sectional plane of the ESP. The former is controlled by using a louver which is placed in front of an ionizer and the latter is controlled by lengthening the pipe of entrance of the ESP in order to have plenty of time that mist is dispersed evenly. It is shown that the uniformity of distribution of wind velocity and mist concentration inside the ESP can be getting by adopting a louver with proper shape and lengthening the pipe of entrance and is also contributed to collection efficiency considerably.

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Rheological Study on bentonite Clay Sedimentation with various concentrations of Sea water (해수의 농도 변화에 따른 bentonite 침전에 대한 유변학적 고찰)

  • 최상원;서호준
    • Journal of Environmental Science International
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    • v.5 no.1
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    • pp.35-41
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    • 1996
  • For studying of coagulation and sedimentation in estuarine clay, we obtained several flow curves with various concentrations of sea water by using Coutte type rotational rheometer. The initial shear stress on high concentration of sea water was observed big, but after this, its value is decreasing with increasing shear rate. The maximum pick of shear stress is decreasing with the decreasing of concentration of sea water The trend is same totally above for viscosity. The sedimentation times with the concentration of sea water vary in $\infty$ ~ 5 minutes. The zeta potential is changed dramatically between 114 and 118 concentration of sea water. That is consistent with the sedimentation graph. From these results, the phenomena of coagulation and sedimentation can be explained with viscoelastic terms on structual formation among particles by the changes of surface potential affected from contacting sea water to dispersed particles.

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Effects of Ammonia Swelling Treatment in Carboxymethylation of Domestic Kraft Pulp on Characteristics of Corboxymethylcellulose(CMC) and CMC Solution (국산(國産) 크라프트 펄프의 카르복시메틸화시(化時) 암모니아 팽윤처리(膨潤處理)가 카르복시메틸셀룰로오스와 카르복시메틸셀룰로오스 용액(溶液)의 특성(特性)에 미치는 효과(效果))

  • Ahn, Byoung-Kuk;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.2
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    • pp.25-35
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    • 1990
  • To investigate the effects of swelling treatment by ammonia on characteristics of carboxymethy1cellulose(CMC) and CMC solution, the domestic kraft pulp pretreated with 5%, 10%, 15% and 20% $NH_4OH$ solution, was carboxymethylated by the standard method, and then the CMC prepared was tested. The physical properties of CMC and CMC solution, such as degree of substitution, transparency. viscosity, weight increase and solubility, were measured, and the comparison with commercial domestic CMC used as a food additive was done. The results obtained were as follows; 1. In CMC manufactured by standard solvent method, hardwood bleached kraft pulp(LBKP) was more substituted than safwood bleached kraft pulp(NBKP), and viscosity of NBKP was higher than that of LBKP. 2. When ammonia swelling treatment was done, degree of substitution gradually decreased with increasing concentration of $NH_4OH$, and degree of substitution of LBKP decreased with a larger range than that of NBKP. 3. When ammonia swelling treatment was done. transparency of CMC solution from LBKP was hardly effected, but in case of NBKP gradually increased with increasing concentration of $NH_4OH$. 4. When ammonia swelling treatment was done, viscosity of CMC solution was higher than that of CMC solution without ammonia swelling treatment. Especially, CMC of high viscosity could be manufactured in 5%, 10% concentration levels of $NH_4OH$. 5. In CMC manufactured from domestic NBKP, CMC at the range of 0.40 to 0.50 in DS was dispersed easily and quickly dissolved, and CMC at more than 0.50 in DS was dispersed slowly in water solution. 6. In comparison with commercial domestic CMC used as a food additive, CMC manufactured from domestic NBKP was higher in DS, and was lower in viscosity and transparency.

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Synthesis of Highly Dispersible Metal Nanoparticles in P3HT:PCBM Layers and Their Effects on the Performance of Polymer Solar Cells (P3HT:PCBM 층 내 분산 가능한 금속 나노입자의 제조 및 이를 포함한 고분자 태양전지 소자의 특성에 관한 연구)

  • Kim, Min-Ji;Choi, Gyu-Chae;Kim, Young-Kuk;Kim, Yang-Do;Baek, Youn-Kyoung
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.179-184
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    • 2014
  • In this study, we prepare polymer solar cells incorporating organic ligand-modified Ag nanoparticles (O-AgNPs) highly dispersed in the P3HT:PCBM layer. Ag nanoparticles decorated with water-dispersible ligands (WAgNPs) were also utilized as a control sample. The existence of the ligands on the Ag surface was confirmed by FT-IR spectra. Metal nanoparticles with different surface chemistries exhibited different dispersion tendencies. O-AgNPs were highly dispersed even at high concentrations, whereas W-AgNPs exhibited significant aggregation in the polymer layer. Both dispersion and blending concentration of the Ag nanoparticles in P3HT:PCBM matrix had critical effects on the device performance as well as light absorption. The significant changes in short-circuit current density ($J_{SC}$) of the solar cells seemed to be related to the change in the polymer morphology according to the concentration of AgNPs introduced. These findings suggested the importance of uniform dispersion of plasmonic metal nanoparticles and their blending concentration conditions in order to boost the solar cell performance.