• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.162-163
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• 2021

To prepare the waterborne silicone acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA), were varied to be 5, 10, 15 and 20 wt%, hydroxyl monomer, and carboxyl monomer were fixed 10 wt%, and 4 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents. The eqivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retension and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.

• Membrane Journal
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• v.20 no.2
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• pp.87-96
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• 2010

We prepared spherical silica particles by controlling various conditions of emulsion-gel procedure using a lab-scale membrane emulsification system equipped with SPG (Shirasu porous glass) membrane having pore size of 2.6 ${\mu}m$. We determined the effects of process parameters of membrane emulsification (dispersed phase pressure, stabilizer and emulsifier concentration in continuous phase, $H_2O$/TEOS ratio, ratio of dispersed phase to continuous phase) on the mean size and size distribution of silica particles. The increase of the dispersed phase pressure and ratio of dispersed phase to continuous phase led to the increase in the mean size of silica particles. On the contrary, the increase in stabilizer and emulsifier concentration and $H_2O$/TEOS ratio caused the reduction of the mean size of particles. Through controlling these parameters, monodisperse spherical silica particles with about 3 ${\mu}m$ of the mean size were finally prepared.

• Nuclear Engineering and Technology
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• v.51 no.3
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• pp.761-768
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• 2019

Understanding the phenomena of formation of single drops is necessary to understand the hydrodynamics in solvent extraction equipment which are used for separation of nuclear materials. In this work, the phenomena of aqueous phase and organic phase drop formation at submerged nozzles are compared by conducting experiments with 30%TBP (v/v) in dodecane as the organic phase and nitric acid as the aqueous phase. Two different nozzles and three different nitric acid concentrations are used. For each nozzle and nitric acid concentration, velocity of the dispersed phase is varied. Drops of aqueous phase formed at downward oriented nozzles submerged in organic phase are observed to be smaller than the drops of organic phase formed at upward oriented nozzles submerged in aqueous phase. Correlations to estimate drop diameter are proposed.

• Journal of Pharmaceutical Investigation
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• v.25 no.1
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• pp.37-46
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• 1995

The experiment was designed to investigate the sustained release dosage form of silymarin (SL) from chitosan (CS) carrier. Solid dispersed system was prepared by mixing the drug with chitosan. This solid dispersed system was cross-linked by glutaraldehyde, formaldehyde, acetaldehyde and butylaldehyde, respectively. The dissolution rates of these preparations were compared with each other in vitro. The silymarin was mired with anionic alginate gel and bead was prepared by dropping this mixture to cationic chitosan solution including calcium chloride. Chitosan encapsulated alginate bead after drying in the oven was investigated for the dissolution rate. The dissolution rate of SL-CS mixture was delayed with increase in the amounts of CS and the concentration of aldehyde. The effect on the delay of dissolution rate was in the increasing order of formaldehyde, glutaraldehyde, acetaldehyde, butylaldehyde. The dissolution rate of chitosan encapsulated alginate bead was parallel with the concentration of chitosan in diluted hydrochloric acid solution and delayed with increase in the concentration of chitosan in phosphate buffer solution.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.8
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• pp.1115-1119
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• 2013

The carbon nanotube/poly-vinylidene fluoride (CNT/PVDF) composite films for the use of electronic devices were fabricated by spray coating method using the CNT/PVDF solution, which was prepared by adding PVDF pellets into the CNT dispersed N-Methyl-2-pyrroli-done (NMP) solution. The CNT/PVDF composite films were peeled off from the glass substrate and were investigated by the scanning electron microscopy, which revealed that the CNTs were uniformly dispersed in the PVDF films and thickness of the films were approximately $20{\mu}m$. The capacitance of the CNT/PVDF films increased dramatically by adding CNTs into the PVDF matrix, and finally saturated approximately 1880 pF. However, the I-V curves didn't show any saturation effect in the CNT concentration range of 0 ~ 0.04 wt%. Therefore we can control the performance of the devices from the CNT/PVDF composite film by adjusting the current level resulted from the CNT concentration with the uniform capacitance value.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.4
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• pp.618-623
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• 2004

This paper has dealt with the heat storage characteristics of gel type micro size latent heat storage material slurry. The heat release operation to the gel type micro size latent heat storage material slurry was carried out using hot air bubbles by direct contact heat exchange. This experiment was carried out using phase change material of n-paraffin so the heat release amount is higher than cold water system. The parameters of this experiment were concentration of latent heat phase change material, height of heat release bath and inlet velocity of hot air. The main results obtained are as follows : (1) The effect of concentration of latent heat phase change material dispersed with water is very affective to the direct contact heat exchange between hot air and gel type micro size latent heat storage material slurry. (2) It is clarified that the most effective concentration of latent heat phase change material dispersed with water exists around 20mass% at this type of direct heat exchange model experiment.

• Membrane Journal
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• v.14 no.3
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• pp.218-229
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• 2004

We prepared monodispersed calcium alginate microspheres by controlling various conditions of emulsification procedure using a lab-scale batch type membrane emulsification system equipped with SPG (Shirasu porous glass) tubular membranes. We determined the effects of process parameters of membrane emulsification (ratio of dispersed phase to continuous phase, alginate concentration, emulsifier concentration, type and concentration of stabilizer, transmembrane pressure, concentration of crosslinking agent, stirring speed and membrane pore size) on the mean size and size distribution of alginate microspheres. The increase of the ratio of dispersed phase to continuous phase, transmembrane pressure and alginate concentration led to the increase in the mean size of alginate microspheres. On the contrary, the increase in emulsifier concentration, stirring speed of the continuous phase and concentration of the crosslinking agent caused the reduction of the mean size of microspheres. Through controlling these parameters, monodisperse alginate microspheres with about $6{\mu}{\textrm{m}}$ of the mean size and 1.1 of the size distribution value were finally prepared in case of the using SPC membrane with the pore size of $2.9{\mu}{\textrm{m}}$.

• Membrane Journal
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• v.31 no.1
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• pp.52-60
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• 2021

When preparing calcium alginate microspheres using rotating membrane emulsification that rotates SPG (Shirasu porous glass) tubular membrane in the continuous phase, the optimal conditions of rotating membrane emulsification process parameters for producing monodisperse microspheres were determined. We determined the effects of process parameters of rotating membrane emulsification (the rotating speed of membrane module, the transmembrane pressure, the ratio of dispersed phase to continuous phase, the alginate concentration, the emulsifier concentration, the stabilizer concentration, the crosslinking agent concentration, and the membrane pore size) on the mean size and size distribution of alginate microspheres. As a result, the size of the microspheres decreased as the rotating speed of membrane module, the emulsifier concentration, and the crosslinking agent concentration increased among the process parameters of rotating membrane emulsification. On the contrary, as the ratio of dispersed phase to continuous phase, the transmembrane pressure, and the alginate concentration increased, the size of the microspheres increased. In the rotating membrane emulsification using an SPG membrane with a pore size of 3.2 ㎛, it was possible to finally prepare monodisperse alginate microspheres with a particle size of 4.5 ㎛ through the control of process parameters.

• Polymer(Korea)
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• v.26 no.2
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• pp.174-178
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• 2002

PLLA-POE-PLLA block copolymers were prepared using PLLA and POE with different compositions. Copolymers were obtained in high yield and the polydispersity of the copolymers was very narrow. A dispersed solution of 0.1 g/mL of PLLA-POE-PLLA copolymer was mixed with a dispersed solution of 0.1 g/mL of PDLA-POE-PDLA copolymer. Gel formation was observed from the mixed product obtained at the human body temperature of $37^{\circ}C$. The mixed product comprising PDLA-POE-PDLA and PLLA-POE-PLLA was found to have higher cloud points than that of PLLA-POE-PLLA copolymer. The cloud points decreased with increasing the concentration of the mixed copolymer dispersed solution.

• Journal of Environmental Impact Assessment
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• v.20 no.4
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• pp.557-564
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• 2011

This study was conducted to investigate the sudden rise of fine particle concentration after the passage of typhoon USAGI and NARI in Busan. Nocturnal inversion layer was formed at atmospheric boundary layer and wind direction changed from southerly wind to northeasterly wind after USAGI passed through Busan. Fine particle concentration in Busan rapidly increased by subsidence of air pollutants released from sources and dust transported from in the vicinity of industrial regions. Wind direction changed from northeasterly wind to southeasterly wind, wind velocity increased and lower atmosphere became extremely unstable after NARI passed through Busan. $PM_{10}$ concentration of Busan increased sharply because of surface dust dispersed by strong wind. Fine particle concentration generally decreases by precipitation and wind after typhoon passes through. However, the concentration can also go up not only by subsidence and transportation in nocturnal inversion layer but also by surface dust which temporarily occurs by strong wind.