• Title/Summary/Keyword: discotic

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Synthesis and Photopolymerization of Discotic Liquid Crystals Containing Hydrogen Bondings and Two Polymerizable Groups (두 종류의 중합기와 수소결합을 가지는 원반형 액정의 합성과 광중합)

  • Lee Jun-Hyup;Lee Seung-Jun;Jang Ji-Sun;Jho Jae-Young
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.373-379
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    • 2006
  • Polymerizable discotic liquid crystals containing diacetylene and acryloyl groups were formed through hydrogen bonding between phloroglucinol core and polymerizable pyridine derivatives, and their photopolymerization behavior was investigated. The discotic complexes exhibited discotic columnar and rectangular columnar mesophases depending on the number of aromatic rings. Photopolymerization of the discotic complexes was carried out by UV irradiation in the liquid crystalline state. IR and UV-Vis spectroscopy affirmed that diacetylene and acryloyl groups were selectively Polymerized, and that crosslinked polymers containing short conjugated diacetylene oligomers were produced by 1,4-addition. X-ray diffraction experiment showed that the columnar order in the discotic complex containing phenyl-pyridine moiety was maintained after photopolymerization, and that the rectangular columnar order in he discotic Complex with biphenyl units was changed to the lamellar order.

Preparation and Properties of Self-Assembled Discotic Liquid Crystals Formed by Hydrogen Bonding (수소결합에 의한 자기조립된 원반형 액정의 제조와 특성)

  • Lee, Jun Hyup
    • Journal of Adhesion and Interface
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    • v.15 no.4
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    • pp.161-168
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    • 2014
  • New self-assembled discotic liquid crystals have been prepared through single hydrogen bonding between phenol and pyridine moieties, and their liquid crystalline properties were investigated. For the construction of discotic structure, we used phloroglucinol as a core molecule and trans-4-alkoxy-4'-stilbazoles with systematically varied alkyl chain lengths as peripheral units. FTIR results showed that the intermolecular hydrogen bonds between core and peripheral molecules are successfully formed, and the stability of the hydrogen bond is strongly influenced by molecular ordering. Discotic complexes exhibited different liquid crystalline phases depending on the length of alkyl chains around the discotic mesogen. The discotic complexes with longer alkyl chains showed hexagonal columnar mesophases, while the other complexes formed nematic columnar mesophases. These results indicated that the type of mesophase structure was strongly dependent on the alkyl chain length around the aromatic core.

Wide Viewing Angle ECB TFT LCD by a Single Discotic Optical Compensation Film

  • Park, Ku-Hyun;Hong, Hyung-Ki;Shin, Hyun-Ho;Chung, In-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.800-802
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    • 2006
  • A simple wide-viewing-angle solution of electrically controlled birefringence (ECB) LCD is proposed, which is based on a single discotic compensation film. The use of a single discotic film instead of two leads to a considerable reduction in cost while high performance is maintained.

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Study on In-Plane Switching mode with discotic compensation film (Discotic 필름 보상형 In-Plane Switching 모드에 관한 연구)

  • Song, I.S.;Baik, I.S.;Jung, B.S.;Jeon, Y.M.;Lee, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.518-521
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    • 2004
  • We have investigated about compensation film to reduce the light leakage at an oblique angle in-plane switching mode. It is well known that uncompensated in-plane switching (US) and fringe field switching (FFS) liquid crystal displays (LCDs) have much better viewing angle than other modes owing to the in-plane rotation of the LC director. However, to accomplish optimal viewing angle characteristics in these devices, they must be compensated by one or more films. So, in this paper, we have studied how to reduce the light leakage with viewing angle using discotic film in dark state.

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Study on orientation distribution of discotic liquid crystal in compensating film for viewing angle improvement of liquid crystal displays

  • Ryu, J.W.;Shin, Y.S.;Kim, Y.K.;Kim, S.Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.879-882
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    • 2008
  • The discotic liquid crystal in compensating film used for the viewing angle improvement of the twist nematic liquid crystal display panel is analyzed. For the optical characterization of the compensating film, we measured the polarization state of the light passing through the film as the tilt angle and the azimuth angle of the film were varied, and then we compared the measured polarization state with the calculated one. Finally we suggested the best fit configuration of the discotic liquid crystal.

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Film Compensation based on Discotic Film in Fringe Field Switching Mode

  • Hwang, Seong-Han;Jung, Byoung-Sun;Kim, Seong-Su;Lee, Seung-Hee;Lee, Gi-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.527-530
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    • 2007
  • Film compensation to suppress a light leakage in the dark state of fringe-field switching (FFS) at off normal direction was performed by optimizing retardation value of discotic (negative A) and TAC films including in-plane switching (IPS). The normal FFS mode shows wide viewing angle characteristics that region of CR 10:1 is over $70^{\circ}$ of polar angle in all directions. The optimized FFS cell exhibits much better performances than other methods do in terms of CR and color uniformity.

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Recent Progress in WV Films - OCB-WV -

  • Mori, Hiroyuki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1501-1504
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    • 2006
  • The WV film successfully enlarged the field of view of the TN mode and made TN popular for larger size applications such as PC monitors. The hybrid alignment of the PDM (polymerized discotic material) layer is also suited for the OCB mode, which is promising as a nextgeneration LCD-TV because of fast panel response and a wide viewing angle. This paper describes recent technological progress in WV films, especially for OCB.

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Study on Improving Viewing Angle of Homogeneous Aligned Liquid Crystal Display using an Compensation Film (보상필름을 이용한 수평 배향된 액정 디스플레이의 시야각 향상에 관한 연구)

  • Lim, Young-Jin;Kim, Seong-Su;Chin, Mi-Hyung;Jeon, Eun-Jeong;Choi, Yu-Jin;Lee, Seung-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1101-1104
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    • 2008
  • We have studied electro-optic characteristics to improve viewing angle of the in-plain switching (IPS) liquid crystal display using an compensation film. The IPS mode shows relatively large light leakage and color shift in diagonal directions in a dark state. To solve this problem, we have compensated the low contrast ratio in diagonal directions using one optimized discotic film and adjusting TAC films of polarizers. The compensated IPS mode shows wide viewing angle characteristics that region of CR 50:1 is over $60^{\circ}$ of polar angle in all directions. The optimized IPS cell exhibits much better performances than other methods do in terms of CR and color uniformity.

TAC Film as a Key Component for LCDs

  • Mori, Hiroyuki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1071-1074
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    • 2005
  • TAC film is an indispensable optical component that protects the polarizing PVA (polyvinyl alcohol) film from being deteriorated and gives high durability, due to its unique features. The newly developed technology of controlling the birefringence of TAC film, together with the coating technology of a discotic material layer, enables excellent viewing angle characteristics and a cost-effective roll-to-roll polarizer manufacturing process.

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Films for Widening the Viewing Angle of LCDs

  • Mori, Hiroyuki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.76-79
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    • 2007
  • Optical compensation films are widely used to enlarge viewing angle characteristics for LCDs. A new surface film with an inner light scattering layer was newly developed to improve gray scale inversion. This paper describes technologies regarding these films that enhance the viewing angle characteristics for LCDs.

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