• 제목/요약/키워드: discharge cells

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플라즈마 제트 도핑 장치의 대기 및 기체의 압력 변화에 대한 방전 특성 (Discharge Characteristics of Plasma Jet Doping Device with the Atmospheric and Ambient Gas Pressure)

  • 김중길;이원영;김윤중;한국희;김동준;김현철;구제환;권기청;조광섭
    • 한국진공학회지
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    • 제21권6호
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    • pp.301-311
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    • 2012
  • 결정질 태양전지 등의 도핑 공정에 적용하기 위한 플라즈마 제트 장치의 기초 방전 특성을 조사한다. 대기압에서의 아르곤 플라즈마 제트와 대기 압력변화에 대한 대기 플라즈마 제트, 그리고 아르곤 분위기 압력 변화에 대한 플라즈마 제트의 전류-전압은 전형적인 정상 글로우 방전의 특성을 갖는다. 대기압 플라즈마 제트의 방전 전압은 약 2.5 kV의 높은 전압이 요구되며, 대기 및 아르곤 플라즈마 제트는 200 Torr 이하의 낮은 압력에 대한 방전 전압은 약 1 kV가 된다. 도핑용 실리콘 웨이퍼에 조사되는 단일 채널 플라즈마 제트의 전류는 인가전압의 조정에 의하여 수 10~50 mA의 고 전류를 용이하게 얻는다. 플라즈마 제트를 웨이퍼에 조사하는 경우에 웨이퍼의 온도 상승은 정상상태에서 약 $200^{\circ}C$가 된다. 실리콘 웨이퍼에 도핑 용재인 액상의 인산을 도포하여 플라즈마를 조사한 결과 얻어진 인 원자의 도핑 분포는 플라즈마 제트 도핑의 가능성을 보여준다.

PVDF 전구체를 이용한 탄소 도포 실리콘 재료의 개발 및 리튬이차전지 음극특성 (Development of Silicon Coated by Carbon with PVDF Precursor and Its Anode Characteristics for Lithium Batteries)

  • 도칠훈;정기영;진봉수;김현수;문성인;윤문수;최임구;박철완;이경직
    • 한국전기전자재료학회논문지
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    • 제19권7호
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    • pp.636-643
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    • 2006
  • Si-C materials were synthesized by the heating the mixture of silicon and polyvinylidene fluoride (PVDF). The electrochemical properties of the Si-C materials as the high capacitive anode materials of lithium secondary batteries were evaluated by the galvanostatic charge-discharge test through 2032 type $Si-C{\mid}Li$ coin cells. Charge-discharge tests were performed at C/10 hour rate(C = 372 mAh/g). Initial discharge and charge capacities of $Si-C{\mid}Li$ cell using a Si-C material derived from PVDF(20wt.%) were found to be 1,830 and 526 mAh/g respectively. The initial discharge-charge characteristics of the developed Si-C electrode were analyzed by the electrochemical galvanostatic test adopting the capacity limited charge cut-off condition(GISOC). The range of reversible specific capacity IIE(intercalation efficiency at initial discharge-charge) and IICs(surface irreversible specific capacity) were 216 mAh/g, 68 % and 31 mAh/g, respectively.

유기전해액 $LiMn_{2}O_{4}$/Lithium 전지의 전기화학적 특성 (Electrochemical Characteristics of $LiMn_{2}O_{4}$/Lithium Cells in Organic Electrolyte)

  • 임정환;도칠훈;문성인;윤문수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.371-374
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    • 2000
  • The electrochemical properties of LiM $n_2$ $O_4$as a cathode and an anode for the lithium secondary battery were evaluated. When LiM $n_2$ $O_4$ material was used as the cathode with the current collector of aluminum, the 1st specific capacity and the 1st Ah efficiency in LiM $n_2$ $O_4$/lithium cell were 123 mAh/g and 91.7%, respectively The anodic properties of LiM $n_2$ $O_4$ material was also evaluated in the LiM $n_2$ $O_4$/1ithium cell with the current collector of copper. It showed that the LiM $n_2$ $O_4$ was useful as the anode for the lithium secondary battery. During the 1st discharge, a potential plateau was observed at the potential of 0.3 $V_{Li}$ Li+/. The 1st specific charge capacity and the 1st specific discharge capacity were 790 mAh/s and 362 mAh/g, respectively. Therefore, the 1st Ah efficiency was 46%. The discharge capacity was gradually faded with the charge-discharge cycling to about 50th cycles. Thereafter, the discharge capacity was stabilized to about 110 mAh/g.

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온도조건에 따른 아연-공기 전지의 전기화학적 특성 (Effect of Temperature Conditions on Electrochemical Properties for Zinc-Air Batteries)

  • 이주광;조용남
    • 한국재료학회지
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    • 제30권12호
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    • pp.687-692
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    • 2020
  • A zinc-air battery consists of a zinc anode, an air cathode, an electrolyte, and a separator. The active material of the positive electrode is oxygen contained in the ambient air. Therefore, zinc-air batteries have an open cell configuration. The external condition is one of the main factors for zinc-air batteries. One of the most important external conditions is temperature. To confirm the effect of temperature on the electrochemical properties of zinc-air batteries, we perform various analyses under different temperatures. Under 60 ℃ condition, the zinc-air cell shows an 84.98 % self-discharge rate. In addition, high corrosion rate and electrolyte evaporation rate are achieved at 60 ℃. Among the cells stored at various temperature conditions, the cell stored at 50 ℃ delivers the highest discharge capacity; it also shows the highest self-discharge rate (65.33 %). On the other hand, the cell stored at 30 ℃ shows only 2.28 % self-discharge rate.

전해중합법에 의한 Polypyrrole/SPE/Li Cell의 온도에 따른 충방전 특성 (Charge/discharge Characteristics of Polypyrrole/SPE/Li Cell with Polypyrrole film Prepared by Electropolymerization Method as a Function of Temperature)

  • 김종욱;유영한;조재철;정운조;박계춘;박복기;구할본;문성인
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1703-1706
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    • 1996
  • The purpose of this study is to research and develop polypyrrole(PPy) positive for thin film rechargeable lithium battery. We investigated cyclic voltammetry, AC impedance response and charge/discharge cycling of PPy/SPE/Li cells as a function of temperature. The redox capacity of $PPy/CF_{3}SO_{3}$ film was the most large. The discharge capacity of PPy/SPE/Li cell with $PPy/CF_{3}SO_{3}$ film was higher than those of $PPy/ClO_{4}$ and $PPy/AsF_6$ films at all cycles. The energy density of PPy/SPE/Li cells during 1st cycle was 73, 90 and 101Wh/kg at $25^{\circ}C$, $45^{\circ}C$ and $60^{\circ}C$, respectively. The improvement of energy density is due to reduction of charge-transfer resistance associated doping-undoping process in PPy film with Increasing temperature. $PPy/CF_{3}SO_{3}$ film shows a good property on charge/discharge cycling in PEO-$LiClO_4$-PC-EC electrolyte.

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양극 활물질의 입도에 따른 열전지 출력 특성 연구 (Effect of Particle Size of Cathode Materials on Discharge Properties of Thermal Batteries)

  • 이정민
    • 한국전기전자재료학회논문지
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    • 제27권6호
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    • pp.399-406
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    • 2014
  • Thermal batteries are used for military power sources that require robustness and long storage life such as missiles and torpedoes. $FeS_2$ powder is currently used for cathode materials because of its high specific energy density, environmental non-toxicity and low cost. However, large particle size of conventional $FeS_2$ has been deterred its possible application for higher power thermal batteries. In order to improve the power density, high energy ball milling of $FeS_2$ has been introduced to crush the micron-sized $FeS_2$. Discharge characteristics of the single cells fabricated with nano-materials and conventional $FeS_2$ powder were evaluated.

정전집진기내의 입자궤적 가시화 (Particle Trajectory Visualization in Electrostatic Precipitator)

  • 박석주;김상수
    • 대한기계학회논문집
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    • 제18권12호
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    • pp.3270-3275
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    • 1994
  • Particle trajectory visualization using laser sheet was performed to investigate the corona wind flow interactions in the one-wire and two-wire type electrostatic precipitators. The corona wind generated by corona discharge was not negligible, and strong flow interactions took place owing to the induced circulatory cells. In the case of one-wire type, as the applied voltage was increased and the cross-section mean velocity was decreased, the effect of corona wind became active. In the case of two-wire type, if upstream discharge voltage was relatively higher than downstream discharge voltage, the effect of upstream corona wind was reduced.

AC 플라즈마 디스플레이패널의 방전개시전압에 모델과 실험의 비교에 관한 연구 (Comparision Study Between Modeling and Experiment of the Breakdown Voltage for AC Plasma Display Panel)

  • 박장식
    • 한국전기전자재료학회논문지
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    • 제13권12호
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    • pp.1039-1044
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    • 2000
  • Breakdown voltage model and expertiments are compared for discharge cells of AC plasma display panel. In the model, discharge paths are assumed to be initial electric field lines and the one-dimensional continuity equation is applied to the charged particle transport at each field line. The comparisons are performed in the wide range of gas pressure (50-600torr), Xe partial pressure over total pressure (1-6%), sustain electrode gap(100-1000$\mu\textrm{m}$), wall height(130, 300$\mu\textrm{m}$), and voltage pulse width(2-6${\mu}$s). The presented breakdown voltage model well agree with experiments in the above wide range. The increase of breakdown voltage with the decrease of the width(L) of protruding electrode is also described by the model.

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Application of the New Panel Structure for High Luminous Efficiency in AC-PDPs

  • Kim, Jae-Sung;Jeon, Chung-Huan;Lee, Eun-Cheol;Ahn, Young-Joon;Kang, Seok-Dong;Ahn, Sung-Yong;Shin, Young-Kyo;Ryu, Jae-Hwa;Schemerhorn, Jerry D.
    • Journal of Information Display
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    • 제1권1호
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    • pp.32-34
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    • 2000
  • A new PDP cell structure called CSP(Charge Storage Pad) improves the luminous efficiency by 1.6 times and prevents cross talk between adjacent cells. The CSP, which is a conducting material, is inserted between the dielectric layer and the MgO film in the front plate. This CSP produces a longer time-averaged discharge path to get a high luminous efficiency and confines the discharge to prevent cross talk.

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리튬 고체전지용 $LiMn_2O_4$ Composite Cathode의 충방전 특성 (Charge/discharge Properties of $LiMn_2O_4$ Composite Cathode for All-solid state Rechargeable Batteris)

  • 김종욱;박계춘;구할본
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1511-1513
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    • 1998
  • The purpose of this study is to research and develop PEO/PVDF electrolytes and $LiMn_2O_4$ composite cathode for all-solid state lithium rechargeable battery. We investigated AC impedance response and charge/discharge cycling of $LiMn_2O_4$/SPE/Li cells. The cell resistance was decreased so much initial charge process from 0% SOC to 100% SOC. The radius of semicircle of $LiMn_2O_4$/SPE/Li cell was so much from initial state to 20th cycling. The discharge capacity of the $LiMn_2O_4$ composite cathode was 144mAh/g based on $LiMn_2O_4$.

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