• 제목/요약/키워드: discharge cells

검색결과 388건 처리시간 0.034초

Influence of Electrolyte Composition on Electrochemical Performance of Li-S Cells

  • Kim, Tae Jeong;Jeong, Bo Ock;Koh, Jeong Yoon;Kim, Seok;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1299-1304
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    • 2014
  • The electrochemical performance of Li-S cells was investigated in various ternary electrolyte solutions composed of 1,2-dimethoxyethane (DME), tetra(ethylene glycol) dimethyl ether (TGM), and 1,3-dioxolane (DOX). The discharge capacity values and cycle data obtained at each composition were statistically treated with the Minitab program to obtain mixture contour plots, from which the optimal composition of the ternary solvent systems was predicted. The discharge capacities and capacity retention were quite dependent on the electrolyte composition. It was estimated from the contour plots of the capacity at 1.0 C that the discharge capacity sharply increased with a decrease in the TGM content. High capacities greater than 900 mAh/g at 1.0 C were expected for the electrolyte composition with a volume ratio of DME/TGM/DOX = 1/0/1. In contrast, it was predicted from the mixture contour plot of the capacity retention that the cycle performance would significantly increase with an increase in the DME content.

열전지용(MS2, M=Fe, Ni, Co)계 양극의 전기화학적 특성 연구 (Effect of Cathode Materials (MS2, M=Fe, Ni, Co) on Electrochemical Properties of Thermal Batteries)

  • 이정민;임채남;윤현기;정해원
    • 한국전기전자재료학회논문지
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    • 제30권9호
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    • pp.583-588
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    • 2017
  • Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. $FeS_2$ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. $MS_2$ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using $MS_2$ cathodes. Based on the results of this study, we propose $NiS_2$ as a potential cathode material for use in thermal batteries.

Ti1-XZrxVNi 및 Ti1-XZrxV0.5Ni1.5계 수소저장합금의 전기화학적 성질 (Electrochemical Properties of Hydrogen Absorbing Ability Ti1-XZrxVNi Ti1-XZrxV0.5Ni1.5 Alloys)

  • 조태환;박찬교
    • 한국수소및신에너지학회논문집
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    • 제2권1호
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    • pp.15-21
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    • 1990
  • Nickel-hydrogen battery systems with metal hydride alloys are expected to have both higher energy density and lower pollution than nickel-cadmium cells. Nickel-hydrogen storage cells are expected to be well-suited for use in space crafts for a large capacity power storage system. Their major advantages are not only a capability of deep DOD(depth of discharge) using but also with excellent durability under excessive overcharging and overdischarging. In this study, the charge/discharge capacities, anodic polarization characteristics and durability for the continious charge/diacharge cycling of the $Ti_{1-X}Zr_XVNi$ and $Ti_{1-X}Zr_XV_{0.5}Ni_{1.5}$ alloys were measured by electrochemical method. The electrode properties of the copper or nickel plated $Ti_{1-X}Zr_XV_{0.5}Ni_{1.5}$ alloys were examined with a battery charge/discharge testing system in the temperature range of -5 to $25^{\circ}C$.

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Mg와 Zn이 치환된 $LiMn_2O_4$ 정극 활물질의 제조 및 특성 분석 (Preparation and Analysis of$LiMn_2O_4$ Cathode Material substituted Mg and Zn)

  • 정인성;구할본;한규승
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.707-710
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    • 2002
  • Spinel $LiMn_2O_4$ and $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4$ powders were synthesized by solid-state method at $800^{\circ}C$ for 36h. Crystal structure and electrochemical properties were analyzed by X-ray diffraction, charge-discharge test, cyclic voltammetry and ac impedance to $LiMn_2O_4$ and $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$. All cathode material showed spinel structure in X-ray diffraction. $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cell substituted $Mg^{2+}$ and $Zn^{2+}$ showed excellent discharge capacities than other cells, which it presented about 120mAh/g at the 1st cycle and about 73mAh/g at the 250th cycle, respectively. AC impedance of $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cells showed the similar resistance of about $65{\sim}110{\Omega}$ before cycling.

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AC PDP의 오방전 개선을 위한 어드레스 방전 특성 연구 (Study on the Address Discharge Characteristics for the Improvement of the Mis-firing Problem in AC PDP)

  • 전원재;김동훈;이석현
    • 전기학회논문지
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    • 제58권6호
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    • pp.1151-1156
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    • 2009
  • Unstable sustain discharges can occur at the bottom cells of the panel at high temperature. To solve this problem, the wall charge variation during an address period was investigated. A test panel of 7.5 inch XGA level was used and one green cell was measured. In order to realize operating condition equal to that of the bottom cells of 50 inch panel, the addressing stress pulses are applied. It seems that the resultant wall charge loss during address period increased with increase of stress time, temperature, pressure and Xe %. Wall charge loss increases with potential difference between scan electrode and address electrode, therefore wall charge loss can be minimized by the increase of scan voltage during address period.

Effect of Mo-doped LiFePO4 Positive Electrode Material for Lithium Batteries

  • Oh, Seung-Min;Sun, Yang-Kook
    • Journal of Electrochemical Science and Technology
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    • 제3권4호
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    • pp.172-177
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    • 2012
  • Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

리튬이온폴리머전지용 가교형 겔폴리머전해질의 중합조건 최적화 연구 (Optimization Study on Polymerization of Crosslink-type Gel Polymer Electrolyte for Lithium-ion Polymer Battery)

  • 김현수;문성인;김상필
    • 한국전기전자재료학회논문지
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    • 제18권1호
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    • pp.68-74
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    • 2005
  • In this work, polymerization conditions of the gel polymer electrolyte (GPE) were studied to obtain better electrochemical performances in a lithium-ion polymer battery. When the polymerization temperature and time of the GPE were 70$^{\circ}C$ and 70 min, respectively, the lithium polymer battery showed excellent a rate capability and cycleability. The TMPETA (trimethylolpropane ethoxylate triacrylate)/TEGDMA (triethylene glycol dimethacrylate)-based cells prepared under optimized polymerization conditions showed excellent rate capability and low-temperature performances: The discharge capacity of cells at 2 Crate showed 92.1 % against 0.2C rate. The cell at -20 $^{\circ}C$ also delivered 82.4 % of the discharge capacity at room temperature.

Luminous efficacy of 12 lm/W in an AC PDP in terms of measurement of the discharge in Ne+20%Xe and green cells

  • Lee, Sung-Min;Cho, Kwan-Hyun;Choi, Kyung-Cheol
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.119-122
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    • 2007
  • Dual auxiliary pulses are adopted in an AC PDP with an auxiliary electrode. The secondary auxiliary pulse of dual auxiliary pulses efficiently utilizes priming particles and contributes to improved luminous efficacy. A shorter time interval between the two auxiliary pulses resulted in better efficacy. The maximum luminous efficacy was approximately 12 lm/W according to measurement of the discharge in a Ne+20%Xe gas-mixture and green cells.

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반응성 플라즈마를 이용한 태양전지용 Si기판의 표면 처리 (Surface treatment of Si wafer for solar cell using reactive plasma method)

  • 박병욱;곽동주;성열문
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1305-1306
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    • 2007
  • To lower the fabrication cost of silicon solar cells, a surface treatment using a dielectric barrier discharge instead of a wet cleaning technique was examined on electrode surfaces on silicon solar cells. The fill factor obtained through measuring current-voltage characteristics was evaluated, and the treated surface state was characterized by energy-dispersive X-ray. It was found that the dielectric barrier discharge effectively activated the electrode surface and the surface treatment on finger electrodes contributed greatly to improve the fill factor.

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플라즈마 방전에서 패닝 효과에 관한 연구 (A Study on Penning Effect in Plasma Discharge)

  • Lee, Jong-chan;Lee, Cheong-hak;Park, Dae-hee
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.515-517
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    • 1997
  • In this paper, the penning effect was studded to control accelerating of the ionization that means Increasing of cross-sectional collision through penning reactions in the plasma cells of Hg-Ar-Ne (x: 10-x, 60Torr) gas discharge under various concentrations of Ar.

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