• Journal of the Korean Ceramic Society
• /
• v.40 no.6
• /
• pp.507-512
• /
• 2003

The LiN $i_{l-y}$ $Co_{y}$ $O_2$ samples were synthesized at 80$0^{\circ}C$ and 85$0^{\circ}C$, by the solid-state reaction method, from the various starting materials LiOH, L $i_2$C $O_3$, NiO, NiC $O_3$, $Co_3$ $O_4$, CoC $O_3$, and their electrochemical properties are investigated. The LiN $i_{l-y}$ $Co_{y}$ $O_2$ pre-pared from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ exhibited the $\alpha$-NaFe $O_2$ structure of the rhombohedral system (space group; R3m). As the Co content increased, the lattice parameters a and c decreased. The reason is that the radius of Co ion is smaller than that of Ni ion. The increase in da shows that two-dimensional structure develops better as the Co content increases. The LiN $i_{0.7}$ $Co_{03}$. $O_2$［HOO(800,0.3)] synthesized at 80$0^{\circ}C$from LiOH, NiO, and $Co_3$ $O_4$ exhibited the largest first discharge capacity 162 mAh/g. The size of particles increases roughly as the valve of y increases. The samples with the larger particles have the larger first discharge capacities. The cycling performances of the samples with the first discharge capacity larger than 150 mAh/g were investigated. The LiN $i_{0.9}$ $Co_{0.1}$ $O_2$［COO(850,0.1)］ synthesized at 85$0^{\circ}C$ from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ showed an excellent cycling performance. The sample with the larger first discharge capacity will be under the more severe lattice destruction, due to the expansion and contraction of the lattice during intercalation and deintercalation, than the sample with the smaller first discharge capacity. As the first discharge capacity increases, the capacity fading rate thus increases.increases.s.s.s.

• Journal of the Korean Geosynthetics Society
• /
• v.6 no.2
• /
• pp.1-8
• /
• 2007

Recently, the demand for industrial and residental land are increasing with economic growth, but it is difficult to acquire areas for development with good ground condition. For efficient and balanced development of land, new development projects are being carried out not only the areas with inland but those with the soft ground as well. As soft grounds have complex engineering properties and high variations such as ground subsidence especially when their strength is low and depth is deep, we need to accurately analyze the engineering properties of soft grounds and find general measures for stable and economic design and management. Vertical drain technology is widely used to accelerate the consolidation of soft clay deposits & dredged soil under pre-loading and various types of vertical drain are used with there discharge capacity. Under field conditions, discharge capacity is changed with various reason, such as soil condition, confinement pressure, long-term clogging and folding of vertical drains and so on. Therefore, many researcher and engineer recommend the use of required discharge capacity. In this paper, the experiment study were carried out to obtain the discharge capacity of four different types of vertical drains by utilizing the large-scale model tests and the required discharge capacity was calculated by several methods.

• Geotechnical Engineering
• /
• v.13 no.2
• /
• pp.39-54
• /
• 1997

Laboratory testings were carried out on plastic board drains (PBDs) using large scale test apparatus to evaluate the physical properties and the drainage performance. The test results reveal that the domestic products of PBDs are well compared with the foreign prod acts as far as the quality and drainage performance are concerned. It has also been confirmed that the discharge capacity decreases with time in such a way that the air bubbles are entrapped inside kinky PBDs and these air bubbles block the water flow through PBDs. It has been found that the vacuum pressure iseffectively applicable to recover the discharge capacity affected by the entrapped air bubbles.

• Journal of Hydrogen and New Energy
• /
• v.10 no.4
• /
• pp.219-224
• /
• 1999

Effects of alloy modification for the $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy as an electrode materials have been investigated. When Ti in the alloy was partially substituted by Zr, the hydrogen storage capacity and subsequently the discharge capacity increased significantly, however, the activation characteristic and rate capability decreased. By substituting Mn with other elements (Cr, Co and Fe) in the alloy, discharge capacity decreased but the cycle life and rate capability were improved. Considering both the discharge capacity, the high rate discharge property and cycle life, the $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy among the alloys subjected to the test was found to be a prominent alloy for a practical usage.

• Journal of Power System Engineering
• /
• v.17 no.1
• /
• pp.104-109
• /
• 2013

Tin and Tinoxide nanoparticles were prepared by arc-discharge nanopowder process. The negative electrode were fabricated using Tin and Tinoxide nanopower. The microstructure and electrochemistry properties were investigated and compared between Tin and Tinoxide. The oxidation film has microstructure of core/shell type and the shell which was attached around Tin nanoparticle consisted of amorphous $SnO_2$. The shape of Tinoxide nanoparticles was formed with irregular shape in comparison with Tin particle. Initial discharge capcity of Tinoxide electrode possesed about 1000mAh/g, which is about 320mAh/g higher than Tin electrode. Irreversible capacity of Tin electrode is much higher than Tinoxide. The cycle performance of Tinoxide electrode was indicated that is batter than Tin. The Tin negative electrode lost most of capacity after 4 cycle but Tinoxide electrode still retained the capacity. The Tinoxide does show some promise as Li-ion battery anode due to their large reversible capacity at low potentials.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2009.03a
• /
• pp.692-701
• /
• 2009

The use of vertical drain method to improve the soft soil ground has been continuously increased in Korea such as Busan New Port, Saemangeum reclamation project and so on in Korea. Especially PBD(Plastic Board Drain), one of the vertical drain, has been widely used due to the economic feasibility, construction compatibility and quality control. However in case of using PBD, discharge capacity reduction caused by creep deformation of the PBD filter, bending, kinking and so on can be occurred. Therefore the purpose of this study is to solve these problems by developing Deformation-Compatible Vertical Drain, DCVD which allows to deform with consolidation settlement without bending and kinking of vertical drain. In order to investigate the performance of DCVD developed in this study, discharge capacity test, centrifuge model test and complex discharge capacity test for both PBD and DCVD are performed and the results are compared.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2009.03a
• /
• pp.720-728
• /
• 2009

This thesis is results of numerical analyses about test results of discharge capacity apparatus using penetration method. Applicability of numerical approach with FEM technique, using Cam-clay model, was confirmed by analyzing the results of standard consolidation test before analyzing test results of discharge capacity apparatus using penetration method. Thus, input parameters for the model was convinced to be appropriate. For numerical analyses about test results of discharge capacity apparatus using penetration method, identical initial and loading conditions during tests were applied to simulate test results correctly. Effects of ground disturbance resulted from installment of vertical drains on the behaviors of consolidation were also simulated. Applicability of numerical approach was investigated by comparing test results with numerical ones. As results of them, both of consolidation settlement were found to be in good agreements so that its applicability was confirmed. As results of numerical estimation, degree of consolidation with the condition of considering smear zone was found to be delayed, compared with results without smear zone. On the other hands, parametric numerical analyses of changing parameters related to smear zone such as permeability and size of smear zone and permeability of vertical drain were also carried out.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.10
• /
• pp.3682-3686
• /
• 2011

The electrochemical properties of lithium-sulfur batteries with binary electrolytes based on DME and DOL, TEGDME and DOL mixed solvent containing $LiClO_4$, LiTFSI, and LiTF salts were investigated. The ionic conductivity of 1M LiTFSI and $LiClO_4$ electrolytes based on TEGDME and DOL increased as the volume ratio of DOL solvent increased, because DOL effectively reduces the viscosity of the above electrolytes medium under the same salts concentration. The first discharge capacity of lithium-sulfur batteries in the DME and DOL-based electrolyte followed this order: LiTFSI (1,000 mAh/g) > LiTF (850 mAh/g) > $LiClO_4$ (750 mAh/g). In case of the electrolyte based on TEGDME and DOL, the first discharge capacity of batteries followed this order: $LiClO_4$ (1,030 mAh/g) > LiTF (770 mAh/g) > LiTFSI (750 mAh/g). The cyclic efficiency of lithium-sulfur batteries at 1M $LiClO_4$ electrolytes is higher than that of batteries at other lithium salts-based electrolytes. Lithium-sulfur battery showed discharge capacity of 550 mAh/g until 20 cycles at all electrolytes based on DME and DOL solvent. By contrast, the discharge capacity of batteries was about 450 mAh/g at 1M LiTFSI and LiTF electrolytes based on TEGDME and DOL solvent after 20 cycles.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.05a
• /
• pp.18-22
• /
• 2001

Spinel $LiMn_{2-y}Mn_{y}O_4$ powder was prepared solid-state method by calcining the mixture of $LiOH{\cdot}H_2O$, $MnO_2$ and MgO at $800^{\circ}C$ for 36h. To investigate the effect of temperature for cycle behaviour of cathode material during cycling, charge-discharge experiments and initial impedance spectroscopy performed by the condition of the charge-discharge temperature. Initial charge-discharge capacity was gradually increased by rising charge-discharge temperature. However, capacity was suddenly decreased at high temperature during cycling. Capacity at low temperature was almost constant during cycling. It confirmed because Mn dissolution is more serious at high temperature than at low temperature.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.19 no.7
• /
• pp.636-643
• /
• 2006

Si-C materials were synthesized by the heating the mixture of silicon and polyvinylidene fluoride (PVDF). The electrochemical properties of the Si-C materials as the high capacitive anode materials of lithium secondary batteries were evaluated by the galvanostatic charge-discharge test through 2032 type $Si-C{\mid}Li$ coin cells. Charge-discharge tests were performed at C/10 hour rate(C = 372 mAh/g). Initial discharge and charge capacities of $Si-C{\mid}Li$ cell using a Si-C material derived from PVDF(20wt.%) were found to be 1,830 and 526 mAh/g respectively. The initial discharge-charge characteristics of the developed Si-C electrode were analyzed by the electrochemical galvanostatic test adopting the capacity limited charge cut-off condition(GISOC). The range of reversible specific capacity IIE(intercalation efficiency at initial discharge-charge) and IICs(surface irreversible specific capacity) were 216 mAh/g, 68 % and 31 mAh/g, respectively.