• 제목/요약/키워드: direct synthesis

검색결과 592건 처리시간 0.024초

합성가스로부터 연료전지급 수소의 직접 생산을 위한 흡착분리 반응 동시 공정 (Novel Sorption Enhanced Reaction Process for Direct Production of Fuel-Cell Grade $H_2$ from Synthesis Gas)

  • 이기봉;전상구;나정걸;류호정
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.745-748
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    • 2009
  • 수소는 지구상에 풍부하게 존재하는 원소로 최근 수소경제시대에 대한 기대와 함께 청정 에너지 carrier로 주목받고 있다. 본 연구에서는 고순도 수소 생산을 위해 water gas shift (WGS) 반응과 $CO_2$의 분리를 하나의 unit operation의 형태로 수행하는 신개념의 thermal swing sorption enhanced reaction (TSSER) 공정의 타당성을 테스트하는데 목적을 두고 있다. Le Chatelier 원리를 기본으로 하는 흡착분리 동시 반응 (sorption enhanced reaction, SER)에서는 수소생산 반응의 열역학적 한계를 극복할 수 있고 정반응의 속도를 증대시킬 수 있다. 본 연구에서는 $K_2CO_3$가 첨가된 hydrotalcite에 대한 고온에서의 $CO_2$ 화학흡착 평형 및 거동 데이터를 실험을 통하여 측정하였다. 또한 WGS 상용촉매와 화학 흡착제를 이용하여 흡착분리 동시 반응을 실험과 수치해석 시뮬레이션으로 수행하였고, 연구결과로부터 연료전지에 사용할 수 있는 고순도의 수소 (~10 ppm CO)를 직접 생산할 수 있으며, 동시에 고압상태의 $CO_2$를 고순도로 포집할 수 있음을 확인할 수 있었다. 고압, 고순도의 $CO_2$ 포집은 이후 $CO_2$ 저장에 용이하게 이용되어 온실가스 저감에 기여할 수 있을 것으로 기대된다.

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Searching for Comparative Value in Small and Medium-Sized Alternative Accommodation: A Synthesis Approach

  • Baek, Unji;Lee, Seul-Ki
    • The Journal of Asian Finance, Economics and Business
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    • 제5권2호
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    • pp.139-149
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    • 2018
  • In the contemporary era of smart tourism, travelers face more accommodation options than ever before. The rapid expansions of alternative accommodation sector are partially owing to the growth of electronic commerce and the rise of online intermediary platforms. Online travel agencies serve as a critical distribution channel for tourism sectors, and the significance is further increased for small and micro entrepreneurs whose direct communication channels are scarce. Considering the holistic process of customer experience started with a third-party online intermediary, this study explores basic and extended attributes of small and medium-sized alternative accommodation where the comparative value is created. In order to achieve the objective, a research design was developed to synthesize the qualitative evidence. The synthesis encompasses both theoretical and practical perspectives, from a systematic review and opinions of academic professionals to an in-depth interview with an industry expert and the current practices of online travel agencies. This study suggests that the sources of value creation for alternative accommodation are not always consistent with those of the traditional. Accounting for the temporal and spatial dynamics in customer experience, the findings of this study provide insights on the comparative value of alternative accommodation, to both academic and industry audiences.

A review: controlled synthesis of vertically aligned carbon nanotubes

  • Hahm, Myung-Gwan;Hashim, Daniel P.;Vajtai, Robert;Ajayan, Pulickel M.
    • Carbon letters
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    • 제12권4호
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    • pp.185-193
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    • 2011
  • Carbon nanotubes (CNTs) have developed into one of the most competitively researched nano-materials of this decade because of their structural uniqueness and excellent physical properties such as nanoscale one dimensionality, high aspect ratio, high mechanical strength, thermal conductivity and excellent electrical conductivity. Mass production and structure control of CNTs are key factors for a feasible CNT industry. Water and ethanol vapor enhance the catalytic activity for massive growth of vertically aligned CNTs. A shower system for gas flow improves the growth of vertically aligned single walled CNTs (SWCNTs) by controlling the gas flow direction. Delivery of gases from the top of the nanotubes enables direct and precise supply of carbon source and water vapor to the catalysts. High quality vertically aligned SWCNTs synthesized using plasma enhance the chemical vapor deposition technique on substrate with suitable metal catalyst particles. This review provides an introduction to the concept of the growth of vertically aligned SWCNTs and covers advanced topics on the controlled synthesis of vertically aligned SWCNTs.

Telomerase reverse transcriptase in the regulation of gene expression

  • Zhou, Junzhi;Ding, Deqiang;Wang, Miao;Cong, Yu-Sheng
    • BMB Reports
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    • 제47권1호
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    • pp.8-14
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    • 2014
  • Telomerase plays a pivotal role in the pathology of aging and cancer by maintaining genome integrity, controlling cell proliferation, and regulating tissue homeostasis. Telomerase is essentially composed of an RNA component, Telomerase RNA or TERC, which serves as a template for telomeric DNA synthesis, and a catalytic subunit, telomerase reverse transcriptase (TERT). The canonical function of TERT is the synthesis of telomeric DNA repeats, and the maintenance of telomere length. However, accumulating evidence indicates that TERT may also have some fundamental functions that are independent of its enzymatic activity. Among these telomere-independent activities of hTERT, the role of hTERT in gene transcription has been investigated in detail. Transcriptional regulation is a fundamental process in biological systems. Several studies have shown a direct involvement of hTERT in gene transcription. This mini-review will focus on the role of hTERT in gene transcription regulation, and discuss its possible mechanisms.

Floating-Poing Quantization Error Analysis in Subband Codes System

  • Park, Kyu-Sik
    • The Journal of the Acoustical Society of Korea
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    • 제16권1E호
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    • pp.41-48
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    • 1997
  • The very purpose of subband codec is the attainment of data rate compression through the use of quantizer and optimum bit allocation for each decimated signal. Yet the question of floating-point quantization effects in subband codec has received scant attention. There has been no direct focus on the analysis of quantization errors, nor on design with quantization errors embedded explicitly in the criterion. This paper provides a rigorous theory for the modelling, analysis and optimum design of the general M-band subband codec in the presence of the floating-point quantization noise. The floating-point quantizers are embedded into the codec structure by its equivalent multiplicative noise model. We then decompose the analysis and synthesis subband filter banks of the codec into the polyphase form and construct an equivalent time-invariant structure to compute exact expression for the mean square quantization error in the reconstructed an equivalent time-invariant structure to compute exact expression for the mean square quantization error in the reconstructed output. The optimum design criteria of the subband codec is given to the design of the analysis/synthesis filter bank and the floating-point quantizer to minimize the output mean square error. Specific optimum design examples are developed with two types of filter of filter banks-orthonormal and biorthogonal filter bank, along with their perpormance analysis.

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고온 태양열을 이용한 합성가스 및 수소 생산 : $ZrO_2$ 나노 구조화에 따른 산화/환원 특성 (Syngas and Hydrogen Production under concentrated solar radiation : Redox system of $ZrO_2$ nano-structure)

  • 장종탁;이종민;조은수;양승찬;윤기준;한귀영
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.463-469
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    • 2012
  • Solar thermochemical syngas and hydrogen production process bv redox system of metal oxide was performed under direct irradiation of the metal oxide on the SiC ceramic foam device using solar simulator. $CeO_2/ZrO_2$ nanotube has been synthesized by anodic oxidation method. Syngas and hydrogen production process is one of the promising chemical pathway for storage and transportation of solar heat by converting solar energy to chemical energy. The produced syngas had the $H_2/CO$ ratio of 2, which was suitable for methanol synthesis or Fischer-Tropsch synthesis process. After ten cycles of redox reaction, $CeO_2$ was analyzed using XRD pattern and SEM image in order to characterize the physical and chemical change of metal oxide at the high temperature.

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Synthesis and Optical Properties of Poly(2-ethynylpyridinum bromide) Having Glycidyl Functionality

  • Gal, Yeong-Soon;Lee, Won-Chul;Lee, Sang-Seob;Bae, Jang-Soon;Kim, Bong-Shik;Jang, Sang-Hee;Jin, Sung-Ho;Park, Jong-Wook
    • Macromolecular Research
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    • 제8권3호
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    • pp.131-136
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    • 2000
  • The synthesis of poly(2-ethynylpyridine) having glycidyl functionality was performed by the direct polymerization of 2-ethynylpyridine and epibromohydrin under mild reaction conditions without any initiator and catalysts. The polymerization proceeded well to give the resulting poly(2-ethynylpyridinium bromide) with a glycidyl functionality having relativity high molecular weight in high yields. The polymer structure was characterized by various instrumental methods to have the conjugated polymer backbone structure having glycidyl functionality. This ionic polymer was completely soluble in water, methanol, DMF, DMSO, and N,N-dimethylacetamide, but insoluble in THF, toluene, acetone, nitrobenzene, and n-hexane. This polymer system exhibited the UV-visible absorption around 300 and 520 nm and red photoluminescence spectrum around 725 nm.

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Extrusion 전분을 기질로 한 불균일상 효소반응계에서의 Cyclodextrin 효소합성 (Enzymatic Synthesis of Cyclodextrin in an Heterogeneous Enzyme Reaction System Containing Insoluble Extruded Starch)

  • 이용현;박동찬
    • 한국미생물·생명공학회지
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    • 제19권5호
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    • pp.514-520
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    • 1991
  • Extrusion시켜 구조변형시킨 전분(질)을 기질로 cyclodextrin glucanotransferse(CGTase)를 활용하여 액화과정을 거치지 않고 직접 cyclodextrin을 합성하는 불용성 extrusion된 전분-수용성 CGTase로 구성된 불균일상 효소반응계에 관하여 연구하였다. Extrusion된 전분을 기질로 이용할 경우 기존의 액화전분을 기질로하는 균일상 효소반응계에서 보다 현저히 증가된 CD 농도, 수율 그리고 합성속도를 얻을 수 있었으며, extrusion된 전분 기질농도가 100g/l일 때 CD생성량과 수율은 각각 54g/l와 0.54였다.

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페나진 유도체의 합성과 항균성 -7-치환-2,3-디히드록시페나진-5,10-디옥시드류의 합성 및 항균성- (Synthesis and Antimicrobial Activity of Phenazine Derivatives -Synthesis and Antimicrobial Activity of 7- Substituted-2,3-dihydroxyphenazine-5,10-dioxides-)

  • 이만길;김호식;한성욱
    • 약학회지
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    • 제36권5호
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    • pp.440-448
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    • 1992
  • 7-Substituted 2,3-dihydroxyphenazine 5,10-dioxides were synthesized by the reaction of 1,2,4-trihydroxybenzene with 6-substituted benzofuroxan derivatives which had been obtained from aniline derivativies bearing methoxy, methyl, acetyl and nitro group at the para position. 2,3-Dihydroxyphenazine 5,10-dioxide was also prepared by the reaction of 1,2,4-trihydroxybenzene with benzofuroxan. The antimicrobial activities of these phenazine dioxide were investigated in terms of minimum inhibitory concentration by the common twofold dilution technique. It was observed that the antimicrobial activity of the phenazine dioxides bearing electron releasing substituents was stronger than that of those bearing electron withdrawing substitutents. From this result, it was concluded that the antimicrobial activity of phenazine dioxide derivatives has a direct relationship with the electronic effect of the substituents.

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계면 제어를 통한 2차원 그래핀 성장의 최근 연구 동향 (Recent Research Trend in Synthesis of Two-Dimensional Graphene through Interface Engineering)

  • 이승구;이은호
    • 접착 및 계면
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    • 제22권3호
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    • pp.79-84
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    • 2021
  • 2 차원 소재인 그래핀은 미래 고성능 전자소자 및 에너지소자의 핵심 부품으로 많은 주목을 받고 있다. 특히, 매우 얇은 원자 한 층을 지닌 그래핀은 우수한 전기적, 기계적 특성을 활용하기 위해 성장법이 매우 중요하다. 이를 위해 2 차원 소재의 계면 및 표면 제어는 고성능 전자소자를 구현하기 위한 유망한 접근 방식이다. 본 논문에서는 계면제어를 통한 그래핀의 성장에 대한 최근 연구동향을 요약 및 소개하고, 차세대 전자 장치에서 고성능 장치를 구현하기위한 과제와 기회에 대해 깊이 논의하고자 한다.