• Title/Summary/Keyword: direct spectrum

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Synthesis and Anaiysis of Photohnninescence Properties of $^5D_1$$^7F_1$ Transition in $LaGaO_3$:$Eu^{3+}$ Red Phosphor ($LaGaO_3$:$Eu^{3+}$형광체의 합성 및 발광 특성)

  • Kim, Kyoung Hwa;Choi, Yoon Young;Sohn, Kee Sun;Kim, Chang Hae;Park, Hee Dong;Choe, Se Young
    • Journal of the Korean Chemical Society
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    • v.44 no.5
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    • pp.453-459
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    • 2000
  • FED has deserved an intensive attentioD as a new flat panel display. The present investigationaims at undemtanding the photoluminescence and cathodoluminescent properties of hGaO$_3$: $Eu^{3+}$ phosphor bytaking into account the possibility that this phosphor could be applied for FED. In onler to investigate on.sucha detailed behavior; 8everM experimental skil18 Je conducted to the LaGaO$_3$:$Eu^{3+}$ phosphoL The excimtion srectrum artd emission spectmn were rnezsured in the UV range and then decay curve of $^5D_0$+$^7F_j$transitions\vas examined. The decay behavior of $^5D_0$ emission was anMyzed by a newly Iuoposed cross-relaxation mech-ani8In in asswiation with inteFwnter di1ffision (or migration). The cross-mlaxation from $^5D_0$ to CTB (Cha'geTransfer Band) wuld be a quite retsonable by considering the excitation spectrum. It could be also found thatthe quenching type was changed from ditfrsion controlled process to the direct quenching process -s inJeasing $Eu^{3+}$ oncntration.

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A Frequency-Sharing Method to Use Frequency Resources Efficiently (효율적인 주파수 이용을 위한 주파수 공유 방법)

  • Kang, Sang-Gee;Hwang, Taek-Jin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.8
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    • pp.1349-1355
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    • 2008
  • Recently many short-range transceiver systems, such as ZigBee, Bluetooth and RFID(Radio Frequency Identification), have been developed. These systems are mostly low-power transceivers. In the near future many more low-power transceivers are appeared for WPAN(Wireless Personal Area Network) and interference mitigation technologies are necessary to the low-power transceivers for using frequency resources efficiently. In this paper we consider two methods for sharing frequency resources. The first case is that a frequency band previously assigned fer a certain system is shared and the second case is that the white frequency band is shared. We study the method and conditions for sharing frequency resources in the above two cases. When a frequency band is shared with ZigBee, RFID, DCP (Digital Cordless Phone) and Bluetooth as an example for the first case, the sharing conditions are investigated and the results are presented. We propose a balancing factor to maintain an equal transmitting conditions between systems having a different interference mitigation technique. In the interference simulation we use FH(Frequency Hopping) as a reference system and 0.9 of a balancing factor for LBT(Listen Before Talk) and 0.8 for DS(Direct Spreading). From the simulation results we know that a balancing factor reduces interference probability therefore many more systems can be operated in the same frequency bands compared with the case without using a balancing factor.

Third Parties' Reactions to Peer Abusive Supervision: An Examination of Current Research (비인격적 감독행위에 대한 제3자 반응 연구동향)

  • Kim, Moon Joung
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.1
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    • pp.175-190
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    • 2022
  • Abusive supervision occurs in a social context in which third-party observers react and interact with the abused victims and supervisors. Despite the importance of third-party observers' behavior in abusive supervision, research on abusive supervision has mainly focused on the dyadic relationship between direct victims and supervisors. Although in recent years research on third parties' reactions to peer abusive supervision has attracted growing attention, there are still insufficient studies examining the topic especially within domestic research in Korea. As such, this study comprehensively reviews empirical studies on third parties' reactions to peer abusive supervision and aims to broaden the scope of research in the field. Firstly, the results of previous studies show that the effects of observed peer abusive supervision are mediated by cognitive and affective processes. Secondly, previous studies are found to investigate the boundary conditions where the effects of observed peer abusive supervision can be amplified or mitigated with regard to various outcomes. Overall, compared to research on direct victims, research on third-party observers of abusive supervision is found to capture a wider spectrum of responses. In order to explain the mechanisms of this phenomena, this study thoroughly examines theoretical assumptions presented in previous studies and categorizes them into five theory types. Finally, this study identifies a couple of central methodological issues, including common method bias and inadequate model specification in the literature and suggests future research directions.

Investigation of Absorption Cross-Section Effects on the Formaldehyde Column Density Retrieval from Direct Sun Measurement (태양 직달광 관측 자료로부터 포름알데히드 연직 농도 산출 시 흡수단면적이 미치는 영향 연구)

  • Gyeong Park;Jeonghyeon Park;Hanlim Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.5_1
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    • pp.551-561
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    • 2023
  • In this study, we investigated the effects of the spectral fitting window and absorption cross-section on the retrieval of the formaldehyde (HCHO) slant column density (SCD) from the direct-sun measurement of pandora spectrometer system using differential optical absorption spectroscopy (DOAS). Pandora Level 1 data observed at Yonsei University in Seoul from October 12 to 31, 2022 were used. The HCHO column density was retrieved under eight ranges including the spectral fitting window used in the Second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2) and seven types of absorption cross-section composition. The spectral fitting window was selected from 336.5 to 359.0 nm with minimum residual and HCHO SCD error. When the nitrogen dioxide (NO2) absorption cross-section at 220 K was added to the cross-section composition used in the CINDI-2 campaign among seven types, the residual and HCHO SCD error were the smallest and the HCHO column density wasstably retrieved. The average HCHO SCD with the highest retrieval accuracy and the values retrieved under other conditions differed from a minimum of 4% to a maximum of 40%.

Performance of Initial Timing Acquisition in the DS-UWB Systems with Different Transmit Pulse Shaping Filters (DS-UWB 시스템에서 송신 필터에 따른 초기 동기 획득 성능 비교)

  • Kang, Kyu-Min
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.5
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    • pp.493-502
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    • 2009
  • In this paper, we compare the performance of initial timing acquisition in direct sequence ultra-wideband(DS-UWB) systems with different transmit pulse shaping filters through extensive computer simulations. Simulation results show that the timing acquisition performance of the DS-UWB system, whose chip rate is 1.32 Gchip/s, employing a rectangular transmit filter is similar to that employing a square root raised cosine(SRRC) filter with an interpolation factor of 4 in the realistic UWB channels(CM1 and CM3) as well as the additive white Gaussian noise(AWGN) channel. Additionally, we present both a 24-parallel digital correlator structure and a 24-parallel processing searcher operating at a 55 MHz system clock, and then briefly discuss the initial timing acquisition procedure. Because we can adopt an 1.32 Gsample/s digital-to-analog(D/A) converter and an 1.32 Gsample/s analog-to-digital(AID) converter in the DS-UWB system by employing the rectangular transmit filter, we have a realistic solution for the DS-UWB chipset development.

InP Quantum Dot-Organosilicon Nanocomposites

  • Dung, Mai Xuan;Mohapatra, Priyaranjan;Choi, Jin-Kyu;Kim, Jin-Hyeok;Jeong, So-Hee;Jeong, Hyun-Dam
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1491-1504
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    • 2012
  • InP quantum dot (QD)-organosilicon nanocomposites were synthesized and their photoluminescence quenching was mainly investigated because of their applicability to white LEDs (light emitting diodes). The as-synthesized InP QDs are capped with myristic acid (MA), which are incompatible with typical silicone encapsulants. We have introduced a new ligand, 3-aminopropyldimethylsilane (APDMS), which enables embedding the QDs into vinyl-functionalized silicones through direct chemical bonding. The exchange of ligand from MA to APDMS does not significantly affect the UV absorbance of the InP QDs, but quenches the PL to about 10% of its original value with the relative increase in surface related emission intensities, which is explained by stronger coordination of the APDMS ligands to the surface indium atoms. InP QD-organosilicon nanocomposites were synthesized by connecting the QDs using a short cross-linker such as 1,4-divinyltetramethylsilylethane (DVMSE) by the hydrosilylation reaction. The formation and changes in the optical properties of the InP QD-organosilicon nanocomposite were monitored by ultraviolet visible (UV-vis) absorbance and steady state photoluminescence (PL) spectroscopies. As the hydrosilylation reaction proceeds, the QD-organosilicon nanocomposite is formed and grows in size, causing an increase in the UV-vis absorbance due to the scattering effect. At the same time, the PL spectrum is red-shifted and, very interestingly, the PL is quenched gradually. Three PL quenching mechanisms are regarded as strong candidates for the PL quenching of the QD nanocomposites, namely the scattering effect, F$\ddot{o}$rster resonance energy transfer (FRET) and cross-linker tension preventing the QD's surface relaxation.

Antibacterial properties of composite resins incorporating silver and zinc oxide nanoparticles on Streptococcus mutans and Lactobacillus

  • Kasraei, Shahin;Sami, Lida;Hendi, Sareh;AliKhani, Mohammad-Yousef;Rezaei-Soufi, Loghman;Khamverdi, Zahra
    • Restorative Dentistry and Endodontics
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    • v.39 no.2
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    • pp.109-114
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    • 2014
  • Objectives: Recurrent caries was partly ascribed to lack of antibacterial properties in composite resin. Silver and zinc nanoparticles are considered to be broad-spectrum antibacterial agents. The aim of the present study was to evaluate the antibacterial properties of composite resins containing 1% silver and zinc-oxide nanoparticles on Streptococcus mutans and Lactobacillus. Materials and Methods: Ninety discoid tablets containing 0%, 1% nano-silver and 1% nano zinc-oxide particles were prepared from flowable composite resin (n = 30). The antibacterial properties of composite resin discs were evaluated by direct contact test. Diluted solutions of Streptococcus mutans (PTCC 1683) and Lactobacillus (PTCC 1643) were prepared. 0.01 mL of each bacterial species was separately placed on the discs. The discs were transferred to liquid culture media and were incubated at $37^{\circ}C$ for 8 hr. 0.01 mL of each solution was cultured on blood agar and the colonies were counted. Data was analyzed with Kruskall-Wallis and Mann-Whitney U tests. Results: Composites containing nano zinc-oxide particles or silver nanoparticles exhibited higher antibacterial activity against Streptococcus mutans and Lactobacillus compared to the control group (p < 0.05). The effect of zinc-oxide on Streptococcus mutans was significantly higher than that of silver (p < 0.05). There were no significant differences in the antibacterial activity against Lactobacillus between composites containing silver nanoparticles and those containing zinc-oxide nanoparticles. Conclusions: Composite resins containing silver or zinc-oxide nanoparticles exhibited antibacterial activity against Streptococcus mutans and Lactobacillus.

A study on Electronic Properties of Passive Film Formed on Ti

  • Kim, DongYung;Kwon, HyukSang
    • Corrosion Science and Technology
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    • v.2 no.5
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    • pp.212-218
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    • 2003
  • Electronic properties of passive films formed on Ti at film formation potentials $(E_f)V_{SCE}$ in pH 8.5 buffer solution and in an artificial seawater were examined through the photocurrent measurement and Mott-Schottky analysis. The passive films formed on Ti in pH 8.5 buffer solution exhibited a n-type semiconductor with a band gap energys $(E_g);E_g^{n=2}=3.4$ eV for nondirect electron transition, and $E_g^{n=0.5}=3.7$ eV for direct electron transition. These band gap values were almost same as those for the passive films formed in artificial seawater, indicating that chloride ion ($Cl^-$ in solution did not affect the electronic structure of the passive film on Ti. $E_g$ for passive films formed on Ti were found to be greater than those ($E_g^{n=0.5}=3.1$ eV, $E_g^{n=2}=3.4$) for a thermal oxide film formed on Ti in air at $400^{\circ}C$. The disorder energy of passive film, determined from the absorption tail of photocurrent spectrum, was much greater than that for the thermal oxide film farmed on Ti in air at $400^{\circ}C$. The greater $E_g$ and the higher disorder energy for the passive film compared with those for the thermal oxide fIlm suggest that the passive film on Ti exhibited more disorded structure than the thermal oxide film. The donor density (about $2.4{\times}10^{20}cm^{-3}$) for the passive film formed in artificial seawater was greater than that (about $20{\times}10^{20}cm^{-3}$) formed in pH 8.5 buffer solution, indicating that $Cl^-$ increased the donor density for the passive film on Ti.

Scattering characteristics of metal and dielectric optical nano-antennas

  • Ee, Ho-Seok;Lee, Eun-Khwang;Song, Jung-Hwan;Kim, Jinhyung;Seo, Min-Kyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.76.1-76.1
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    • 2015
  • Optical resonances of metallic or dielectric nanoantennas enable to effectively convert free-propagating electromagnetic waves to localized electromagnetic fields and vice versa. Plasmonic resonances of metal nanoantennas extremely modify the local density of optical states beyond the optical diffraction limit and thus facilitate highly-efficient light-emitting, nonlinear signal conversion, photovoltaics, and optical trapping. The leaky-mode resonances, or termed Mie resonances, allow dielectric nanoantennas to have a compact size even less than the wavelength scale. The dielectric nanoantennas exhibiting low optical losses and supporting both electric and magnetic resonances provide an alternative to their metallic counterparts. To extend the utility of metal and dielectric nanoantennas in further applications, e.g. metasurfaces and metamaterials, it is required to understand and engineer their scattering characteristics. At first, we characterize resonant plasmonic antenna radiations of a single-crystalline Ag nanowire over a wide spectral range from visible to near infrared regions. Dark-field optical microscope and direct far-field scanning measurements successfully identify the FP resonances and mode matching conditions of the antenna radiation, and reveal the mutual relation between the SPP dispersion and the far-field antenna radiation. Secondly, we perform a systematical study on resonant scattering properties of high-refractive-index dielectric nanoantennas. In this research, we examined Si nanoblock and electron-beam induced deposition (EBID) carbonaceous nanorod structures. Scattering spectra of the transverse-electric (TE) and transverse-magnetic (TM) leaky-mode resonances are measured by dark-field microscope spectroscopy. The leaky-mode resonances result a large scattering cross section approaching the theoretical single-channel scattering limit, and their wide tuning ranges enable vivid structural color generation over the full visible spectrum range from blue to green, yellow, and red. In particular, the lowest-order TM01 mode overcomes the diffraction limit. The finite-difference time-domain method and modal dispersion model successfully reproduce the experimental results.

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Electrical Properties of Laser CVD Silicon Nitride Film (Laser CVD SiN막의 전기적 특성)

  • Kim, Yong-Woo;Kim, Sang-Wook;Park, Jong-Wook;Kim, Chun-Sub;Sung, Yung-Kwon
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.85-87
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    • 1990
  • Silicon nitride film was deposited on a silicon wafer using a laser CVD(LCVD) technique, which is based on direct photolysis of $SiH_4/NH_3$ gas mixture by ArF laser beam(${\lambda}=193\;nm$). The refractive index of deposited SiN film is 1.9 at the temperature of $300^{\circ}C$, pressure of 5 torr. The breakdown field strength of LCVD SiN film was 10MV/cm. In IR spectrum, the absorption peak of Si-H, N-H, and Si-N is detected and it is shown that hydrogen is included in SiN film. From analysis of absorption band. it is calculated that density of Si-H, N-H bond is higher than $5{\times}10^{22}cm^{-3}$. LCVD MIS capacitor and PECVD MIS capacitor have injection-type hysteresis but it is known that hysteresis loss of LCVD MIS capacitor is smaller than that of PECVD MIS capacitor. It means that Interface state density of LCVD capacitor is smaller than that of PECVD capacitor. In addition, the flatband voltage($V_{FB}$) of LCVD is smaller than that of PECVD capacitor. And it means that fixed charged density($Q_{FIX}$) of LCVD capacitor is smaller than that of PECVD MIS capacitor.

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