• Korean Journal of Materials Research
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• v.12 no.12
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• pp.924-929
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• 2002

To recycle waste materials, this work was focused on development of glass-ceramic from incinerator fly ash with a large content of Cl and its physical property was evaluated. In the process, water washing as a pre-treatment before melting the fly ash was used to remove large amount of Cl component in the ash and to reduce melting temperature. As a result, glass was obtained at below $100^{\circ}C$ compared to the melting temperature before washing the ash. Also, internal crystallization occurred under single stage heat treatment (at $850-950^{\circ}C$ for 20-340min) without adding other materials into the ash. It was shown that the glass-ceramic was composed of four crystals, diopside, anorthite, akermanite, and unknown phase. Hardness of 8.3GPa was found in the glass-ceramic, which is a high value compared to reported others. Thus, the present process suggests that a good glass-ceramic produced from an incinerator ash could be applicable for structural materials in terms of economic and environmental points.

• Economic and Environmental Geology
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• v.31 no.5
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• pp.447-458
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• 1998

The spinel Ihelzolite of ultramafic xenoliths are found in the alkali basalt from eastern part of the Cheju island, Korea. The xenolith is are mainly composed of olivine, orthopyroxene, clinopyroxene and spinel. Based on the chemical compositions of the constituent minerals, the ultramafic xenolith belong to upper mantle peridotite. Each minerals have a protogranular texture. Olivine with kink band texture partly shows undulatory extinction. Some clinopyroxenes have spongy textured rims. Brown spinels occur in the interstices between olivine and pyroxene grains. Olivine is mostly forsterite $(Fo_{89-90})$. Orthopyroxene is enstatite $(Wo_{1.3}En_{88.4}Fs_{10.3})$ with 3.87~5.25 wt% $Al_{2}O_{3}$. Clinopyroxene is diopside $(Wo_{48.0}En_{46.2}Fs_{5.8})$ with 6.75~5.03 wt% $Al_{2}O_{3}$. Spinel has the Mg value of 75.9 and its Cr-number is 10.2. According to the PoT estimations for the mantle xenoliths, equilibrium temperatures of the xenoliths range from 1023 to $1038^{\circ}C$ and pressure is 18 kbar. Spinellhelzolite from this area, which is characterized by lower Cr-number (10.2) and homogeneous chemical compositions, supports that these ultramafic xenoliths are derived from the upper mantle.

• The Journal of the Petrological Society of Korea
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• v.14 no.1
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• pp.45-60
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• 2005

This study was intended to elucidate the petrography and geochemical characteristics of the Someori Basalt in the Udo monogenetic volcano, eastern Jeju Island. The Someori basalts consist of plagioclase, olivine, orthopyroxene, clinopyroxene and ilmenite. The Someori basalts are plotted into subalkali rock series on the TAS diagram, and belong to tholeiitic basalts in the diagram of alkali index against to Al₂O₃ contents. The basalts belong to tholeiitic rock series, having normative quartz (less than 3.9%) + hypersthene + diopside.

• Korean Journal of Materials Research
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• v.19 no.12
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• pp.686-691
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• 2009

The effects of thermal properties on the crystallization behavior of $CaMgSi_2O_6$ glass-ceramics were investigated as a function of sintering temperature from 800$^{\circ}C$ to 900$^{\circ}C$. The crystallization behavior of the specimens depended on the sintering temperature, which could be evaluated from the differential thermal analysis, X-ray diffraction and Fourier transform infrared spectroscopy. With increasing sintering temperature, the thermal conductivity of the sintered specimens increased, while the coefficient of thermal expansion (CTE) of the sintered specimens decreased. These results could be attributed to the increase of crystallization, confirmed from the estimation by density measurements. Also, the thermal diffusivity and specific heat capacity of the sintered specimens were discussed with relation to the sintering temperature. Typically, a thermal conductivity of 3.084 $W/m^{\circ}C$, CTE of 8.049 $ppm/^{\circ}C$, thermal diffusivity of 1.389 $mm^2/s$ and specific heat capacity of 0.752 $J/g^{\circ}C$ were obtained for $CaMgSi_2O_6$ specimens sintered at 900$^{\circ}C$ for 5 h.

• Economic and Environmental Geology
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• v.5 no.4
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• pp.211-217
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• 1972

The Second Yeon Hwa Mine which belongs to a so called Lead-Zines Belt Area in the central east Korea is located at about 10 km northeast of the Seogpo railway station on Yeongdong Line. The exploitation of the mine started in June, 1969 and furnished the machinary ore dressing plant in November, 1971. The current monthly production of rude ore is 15,000 meteric tons. The results of the study on the lead-zinc-copper deposits of the Second Yeonhwa mine are summerized as follows: (1) main ore deposits of the mine are localized in the Pungchon Limestion formation of Cambrian age, (2) related ingneous rock with ore deposits is granite porphyry, which distributed in NS and $N50^{\circ}W$ trend, (3) ore solution ascended along the $N50^{\circ}W$ trend which represents folding axis and fault plane and mineralized selectively in the limestone formation. (4) high grade ore deposits are localized in concave and convex boundaries of granite porphyry, and hanging walls of shale bed ($P_2S$ shale bed) in Pungchon Limestone formation and (5) skarn minerals are consisted of garnet, hedenbergite, diopside, and sulfide minerals are composed of zincblenede, galena, phyrhotite, pyrite and some amount of chalcopyrite and arsenopyrite.

• Economic and Environmental Geology
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• v.25 no.4
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• pp.463-477
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• 1992

The study area consists of sedimentary and volcanic rocks of Gyeongsang Supergroup, granitoid intrusives, and hornfelses around the granitoids. Granitoid intrusives occur in small stocks in Nijeon-ri, Uggogri, and Yul-ri area. The masses in Nijeon-ri and Uggog-ri are hornblende-biotite granodiorite, biotite granodiorite respectively, and Yul-ri mass is biotite granite. Surrounding sediments of these masses were thermally metamorphosed and contact aureoles were formed. The studied granitoids are considered to be formed by sequential crystallization-differentiation from calc-alkalic granitoid magma. Metamorphic minerals occurring in contact aureole are chlorite, actinolite, epidote, and biotite. Diopside and hornblende are observed in small amount in some lithology around contact aureole. The lithology of contact aureole is predominantly silty and sandy, and characteristic metamorphic minerals were poorly developed because of low temperature metamorphism. Low temperature in contact aureole could be deduced from the facts that the intrusions were small size, shallow depth, low temperature, and rare movement of volatiles from magma.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.309-309
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• 2007

The LTCCs (low-temperature co-fired ceramics) are very important for electronic industry to build smaller RF modules and to fulfill the necessity for miniaturization of devices in wireless communication industry. The dielectric materials with sintering temperature $T_{sint}$<$900^{\circ}C$ are required. In this study, we investigated with glass-ceramic composition, which was crystallized with two crystals. The microstructure, crystal phases, thermal and mechanical properties, and dielectric properties of the composites were investigated using FE-SEM, XRD, TG-DTA, 4-point bending strength test and LCR measurement. The starting temperature for densification of a sintered body was at $779{\sim}844^{\circ}C$ and the glass frits were formatted to the crystal phases, $CaAl_2Si_2O_8$(anorthite) and $CaMgSi_O_6$(diopside), at sintering temperature. The sintered bodies exhibited applicable dielectric properties, namely 6-9 for ${\varepsilon}_r$. The results suggest that the glass-ceramic composite would be potentially possible to application of low dielectric L TCC materials.

• Economic and Environmental Geology
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• v.19 no.spc
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• pp.3-17
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• 1986

Hundred mineral deposits including W-Mo, Pb-Zn-Cu, fluorite and talc occur in the Cambre-Ordovician limestone contacting with the Cretaceous Muamsa and Wolak granitoids in the Susanri-Hwanggangri mineralized zone. In most mineral deposits characterized by metasomatic replacement, skarn and hydrothermal vein types, two distinct tendencies were found as W-Mo mineralization in or/and near granitoid batholith and ($Pb-Zn-Cu(CaF_2)$) mineralization which is gradually increased toward the batholith. W-Mo veins of extensive vein system occupy northly striking fractures whilst $Pb-Zn-Cu-CaF_2$ veins strike northeast or northwest. In this work, three representative lead-zinc-copper deposits choosing the Dangdu, Useog and Eoksu mines were dealt with in detail. Skarn ore bodies in the Dangdu mine were grouped into early diopside rich clinopyoxene-garnet, barren skarn and ore bearing late hedenbergite rich clinopyroxene-garnet skarn. Temperature and $X_{CO_2}$, obtained from hedenbergite-andradite-calcite-quartz mineral equilibria in the Dangdu ore deposits were $580{\sim}650^{\circ}C$ and 0.15~0.3, respectively. Fluid inclusien evidence in the Useog mine indicates that main stage mineralization temperature ranges from 224 to $389^{\circ}C$ with a salinity of 2~17 equivalent wt. percent NaCl. Sphalerites from the Dangdu and Useog mines have 16~17.7 mole percent in FeS which is relatively consistent to those of some other lend-zinc ore deposits in South Korea. Filling tcmjCerature of fluid inclusion frem the Eoksu mine shows deposition of ore within the temperature ranges from 237 to $347^{\circ}C$ and within the salinity ranges from 2.6 to 10.77 equivalent wt. percent NaCl.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.21-21
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• 2009

후막 광식각 기술을 이용하여 형성된 Ag 전극과 LTCC 기판 사이의 접착력을 향상시키기 위하여 무기 바인더로서 anorthite, diopside 및 MLS-62 glass frit을 첨가하여 감광성 Ag paste를 제조하였다. 소성 후의 glass pool effect를 감소시키기 위해 attrition mill을 통하여 미세 glass 분말을 준비하였다. Glass frit은 Ag powder의 5vol%~25vol%의 함량으로 첨가하여 감광성 Ag paste를 제조하였고 패턴 형성 후 $850^{\circ}C$에서 1시간 소결하였다. 전극과 기판 사이의 접착력은 micro-ball shear test 법으로 측정하였으며, Ag 전극 부착력은 glass frit의 함량 증가에 따라 증가하다가 감소하는 경향을 보이는데, 이는 과량의 glass frit 첨가로 인한 전극 내부에 액상 풀의 형성에 기인한 것으로 보여진다. Ag 전극의 면저항은 glass frit의 함량이 증가함에 따라 $0.13m{\Omega}{/\square}$에서 $2.06m{\Omega}{/\square}$까지 증가하는 경향을 나타내었다. 소성 전후의 전극 패턴의-수축율은 $100{\mu}m$의 선폭을 기준으로 glass frit의 첨가랑이 증가할수록 43.3%에서 35.0%로 감소하였으며, 그 결과 최소 선폭 $25{\mu}m$의 미세 전극 패턴의 형성이 가능하였다.

• Economic and Environmental Geology
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• v.19 no.2
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• pp.133-146
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• 1986

Primary uraninite and secondary uranium minerals such as torbernite, metatorbernite, tyuyamunite, metatyuyamunite, autunite and metaautunite have been identified from various types of uranium ores. Uranium minerals occur as accessory minerals in both the primary and secondary ores. Low·grade uranium ores consist of various kinds of primary and secondary minerals. Major constituent minerals of primary uranium ores are graphite. quartz. Ba-feldspar and sericite/muscovite, and accessories are calcite, chlorite, fluorapatite, barite, diopside, sphene, rutile, biotite, laumontite, heulandite, pyrite, sphalerite and chalcopyrite, and secondary minerals consist of kaolinite, gypsum and goethite. Uraninite grains occur as microscopic very fine-grained anhedral to euhedral disseminated particles in the graphitic matrix, showing well·stratified or zonal distribution of uranium on auto-radiographs of low-grade uranium ores. Some uraninite grains are closely associated with very fine-grained pyrite aggregates, showing an elliptical form parallel to the schistosity. Some uraninite grains include extremely fine-grained pyrite particle. Sphalerite and pyrite are often associated with uraninite in graphite-fluorapatite nodule. The size of uraninite is $2{\mu}m$ to $20{\mu}m$ in diameter. Low-grade uranium ores are classified into 5 types on the basis of geometrical pattern of mineralization. They are massive, banded, nodular, quartz or sulfide veinlet-rich and cavity filling types. Well-developed alternation of uranium-rich and uranium-poor layers, concentric distribution of uranium in graphite-fluorapatite nodule and geopetal fabrics due to the load cast of the nodule suggest that the uranium was originally deposited syngenetically. Uraninite crystals might have been formed from organo-uranium complex during diagenesis and recrystallized by metamorphism. Secondary uranium minerals such as torbernite, tyuyamunite and autunite have been formed by supergene leaching of primary ores and subsequent crystallization in cavities.