• 대한화학회지
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• 제25권3호
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• pp.172-176
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• 1981

형상 선택성 ZSM-5 제올라이트 촉매상에서 메탄올로부터 $C_2-C_{10}4의 탄화수소 형성을 조사하였다. 메탄올로 부터 dimethylether를 거쳐 생성되는 $C_2-C_5$의 올레핀들이 ZSM-5의 강한 산점에서 고리화 반응등에 의하여 방향족 화합물이 많이 포함된 탄화수소화합물로 전환된다고 생각된다. 메탄올의 전환반응에 대한 ZSM-5 촉매의 높은 활성과 활성저하에 대한 안정성은 특유의 교차되는 세공관구조와 소수성에 기인하는 것으로 보인다.

• 한국막학회:학술대회논문집
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• 한국막학회 2005년도 추계 총회 및 학술발표회
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• pp.204-207
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• 2005

• Journal of Mechanical Science and Technology
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• 제19권10호
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• pp.1957-1963
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• 2005

In this study, external condensation heat transfer coefficients (HTCs) of six flammable refrigerants of propylene (RI270), propane (R290), isobutane (R600a), butane (R600), dimethylether (RE170), and HFC32 were measured at the vapor temperature of $39^{\circ}C$ on a 1023 fpm low fin and Turbo-C tubes. All data were taken under the heat flux of $32\~116\;and\;42\~142kW/m^2$ for the low fin and Turbo-C tubes respectively. Flammable refrigerants' data obtained on enhanced tubes showed a typical trend that external condensation HTCs decrease with increasing wall subcooling. HFC32 and DME showed up to $30\%$ higher HTCs than those of HCFC22 due to their excellent thermophysical properties. Propylene, propane, isobutane, and butane showed similar or lower HTCs than those of HCFC22. Beatty and Katz' correlation predicted the HTCs of the flammable refrigerants obtained on a low fin tube within a mean deviation of $7.3\%$. Turbo-C tube showed the best performance due to its 3 dimensional surface geometry for fast removal of condensate.

• Bulletin of the Korean Chemical Society
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• 제23권6호
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• pp.803-807
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• 2002

The conversion of dimethyl ether(DME) has been carried out over $\gamma-alumina$, silica-alumina, and modified $\gamma-aluminal$ catalysts. Especially, the water effect has been investigated on purpose to develop a suitable catalyst for one-step synthesis of DME from $CO_2$ hydrgenation, The $\gamma-Al_2O_3$ modified with 1 wt% silica is more active and less deactivated by water than unmodified one. $CO_2has$ no effect on catalytic dehydration of methanol to DME.

• Natural Product Sciences
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• 제3권2호
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• pp.127-134
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• 1997

Two new dimeric phenolic conjugates, 2,3-di-O-dehydrodigallicmonocarboxyl-$({\alpha},{\beta})$-$^4C_1$-glucopyranose and ellagic acid 3,3'-dimethylether-4-0-$SO_3K$ were isolated from the debarked heart wood of Tamarix tetragyna (Tamaricaceae) along with the known phenolic compounds, isoferulic acid, ferulic acid, gallic acid, gallic acid 4-methyl ether, syringic acid, ellagic acid 3,3'-dimethyl ether and ellagic acid. All structures were determined mostly by ESI-MS, ID and 2D-NMR spectroscopy.

• 폴리머
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• 제32권4호
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• pp.385-389
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• 2008

반응온도의 안정화, 용매 hexafluoropropylene(HFP) 투입량, 그리고 단량체 hexafluoropropylene oxide(HFPO)의 투입속도와 같은 반응조건이 HFPO 음이온 중합의 사슬확장과 사슬이동에 미치는 영향에 대해 연구하였다. Cesium fluoride(CsF)와 tetraethyleneglycol dimethylether(TG)를 사용하여 합성된 음이온 개시제를 이용한 HFPO의 음이온 중합반응에서, 안정적인 반응온도 $-35{\sim}-36^{\circ}C$, 개시제 투입량에 대한 HFP 투입 몰비 31.5, 그리고 HFPO 투입속도 11.57 g/hr의 반응조건으로부터 평균분자량 14800의 고분자량 poly(HFPO)를 얻을 수 있었다. 반면, 불안정한 반응온도, 최적화되지 않은 용매의 투입량과 HFPO 투입속도는 중합물의 사슬이동을 증가시켜 중합체가 원활하게 성장하지 못하였다. 결론적으로, HFPO 음이온 중합반응에서의 사슬확장과 사슬이동은 반응온도의 안정화, 용매의 투입량과 단량체의 투입속도에 매우 민감하게 영향을 받고 있음을 알 수 있었다.

• 한국대기환경학회지
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• 제22권1호
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• pp.53-61
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• 2006

Recently, lots of researchers have been attracted to develop various alternative fuels and to use renewable fuels in order to solve the exhaust emission problems. DME (Dimethylether) is synthetic fuel, and can be produced from natural gas, coal and biomass. The emission is clean because it contains little sulfur and aromatic components In this study, the fuel was tested to investigate the applicability as an alternative fuel for diesel. This study was carried out by comparing the exhaust emissions and performance of diesel engine with DME, ULSD (ultra low sulfur diesel), LSD (low sulfur diesel) respectively. In order to measure regulated emissions, CO, $NO_{3}$, HC from vehicle different fuel types were used on chassis dynamometer CVS (constant volume sampler)-75 mode and EPA TO-I1A method was chosen for aldehydes analysis.

• Korean Membrane Journal
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• 제6권1호
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• pp.10-15
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• 2004

We developed a water-selective ceramic composite membrane for use as a dehydration membrane reactor for dimethylether (DME) synthesis from methanol. The membranes were modified on the porous stainless steel support by the sol-gel method accompanied by a suction process. The improved membrane modification process was effective in increasing the vapour permselectivity by removal of defects and pinholes. The optimized alumina/silica composite membrane exhibited a water permeance of 1.14${\times}$10$^{-7}$ mol/$m^2$.sec.Pa and a water/methanol selectivity of 8.4 at permeation temperature of 25$0^{\circ}C$. The catalytic reaction for DME synthesis from methanol using the membrane was performed at 23$0^{\circ}C$, and the reaction conversion was compared with that of the conventional fixed-bed reactor. The reaction conversion of the membrane reactor was much higher than that of the conventional fixed-bed reactor. The reaction conversion of the membrane reactor and the conventional fixed-bed reactor was 82.5 and 68.0%, respectively. This improvement of reaction efficiency can last if the water vapour produced in the reaction zone is removed continuously.

• Archives of Pharmacal Research
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• 제27권4호
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• pp.386-389
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• 2004

Repeated column chromatography of the CHCI_3-soluble fraction of Zingiber zerumbet led to the isolation and identification of two aromatic compounds, p-hydroxybenzaldehyde (1) and vanillin (2), and six kaempferol derivatives, kaempferol-3,4',7-O-trimethylether (3), kaempferol-3-O-methylether (4), kaempferol-3,4'-O-dimethylether (5), 4'-O-acetylafzel in (6), kaempferol-3-O-(4-O-acetyl-$\alpha$-L-rhamnopyranoside)], 2',4'-O-diacetylafzelin (7), kaempferol-3-O-(2,4-O-diacetyl-$\alpha$-L-rhamnopyranoside)], and 3',4'-O-diacetylafzelin (8), kaempferol-3-O-(3,4-O-diacetyl-$\alpha$-L-rhamnopyranoside)]. The structures of 1-8 were identifed by analysis of spectroscopic data as well as by comparison with published values. This is the first report on the isolation of compounds 1-3 from this plant.

• 한국자동차공학회논문집
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• 제9권4호
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• pp.44-49
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• 2001

Reduced chemical kinetics mechanism has been derived, which can be applicable for autoignition model of hydrocarbon fuels, and contains 23 reactions and 18 species. The present model is validated with the experimental data, where the ignition delays of several hydrocarbon fuels, such as n-heptane, i-octane, n-decane and DME(dimethylether) are measured as equivalence ratios are varied. Especially, the effects of different fuels on ignition delays can be explained by changing the rate constants of three reactions among the present model. As a result, the proposed model can be applicable to two stage ignition model of Diesel combustion.