• Title/Summary/Keyword: diffusivity

Search Result 749, Processing Time 0.028 seconds

Study on the Sinterability and Pellet Properties of Dy2O3-TiO2 Oxides (Dy2O3-TiO2 산화물의 소결성 및 소결체 특성에 관한 연구)

  • Kim, Han-Soo;Joung, Chang-Yong;Kim, Si-Hyung;Lee, Byoung-Ho;Lee, Young-Woo;Sohn, Dong-Seong;Lee, Sang-Hyun
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.11
    • /
    • pp.1108-1112
    • /
    • 2002
  • pellets were fabricated as a reactor control material by the powder process. Sinterability of $Dy_2O_3+TiO_2$ mixtures and phases of solid solutions were analyzed by using TMA and XRD, respectively. The thermal conductivity of pellet was determined from the measurement data of the specific heat and the thermal diffusivity of the pellet. The sinterability and the sintered density varied as a function of Dy content in $Dy_xTi_yO_z$. The pellet of $3\;g\;Dy/cm^3\;Dy_xTi_yO_z$ melted in the sintering temperature of $1580{\circ}C$. There were two phases of $Dy_2TiO_5+Dy_2Ti_2O_7$ and a single phase of $Dy_2TiO_5$ for the pellet that has the Dy content of and , respectively. The thermal conductivity of $Dy_xTi_yO_z$ was nearly constant in the temperature range of $25~600{\circ}$. It was 1.69~1.78 W/mK for the pellet sintered in and 1.49~1.55 W/mK for the pellet sintered in $1550{\circ}$.

Analysis of Stream Depletion due to Groundwater Pumping in Variable Stream Stages Using an Analytical Model (해석적 모형을 이용한 지하수 양수 및 하천수위 변화에 따른 하천수 감소 특성 분석)

  • Lee, Jeongwoo
    • The Journal of Engineering Geology
    • /
    • v.29 no.4
    • /
    • pp.439-449
    • /
    • 2019
  • To prevent the drying-out of streams and to make effective use of stream water and groundwater, it is necessary to evaluate the impact of groundwater pumping on nearby streams. To this end, stream depletion due to groundwater pumping should be investigated in terms of various hydraulic characteristics of the aquifer and stream. This study used the Baalousha analytical solution, which accounts for stream-stage variation over time, to analyze stream depletion due to groundwater pumping for cases where the stream level decreases exponentially and recovers after the decrease. For conditions such as an aquifer transmissivity of 10~100 ㎡ d-1, storage coefficient 0.05~0.3, streambed hydraulic conductance 0.1~1.0 m d-1, stream-well distance 100~500 m, and stage recession coefficient 0.1~1.0 d-1, the contribution of stream water (the dimensionless ratio of stream water reduction rate to groundwater pumping rate) was analyzed in cases where stream level change was considered. Considering the effect of stream-stage recession, the contribution of stream water is greatly reduced and is less affected by the stream-depletion factor, which is a function of the stream-to-well distance and hydraulic diffusivity. However, there is no significant difference in stream depletion under constant- and variable-stage recovery after recession. These results indicate that stream level control can distribute the relative impacts on stream water and aquifer storage during groundwater pumping

Numerical Modeling of Water Transfer among Precipitation, Surface Water, Soil Moisture and Groundwater

  • Chen, Xi;Zhang, Zhicai;Chen, Yongqin
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2006.05a
    • /
    • pp.2-11
    • /
    • 2006
  • In the processes of hydrological cycle, when precipitation reaches the ground surface, water may become surface runoff or infiltrate into soil and then possibly further percolate into groundwater aquifer. A part of the water is returned to the atmosphere through evaporation and transpiration. Soil moisture dynamics driven climate fluctuations plays a key role in the simulation of water transfer among ground surface, unsaturated zone and aquifer. In this study, a one-layer canopy and a four-layer soil representation is used for a coupled soil-vegetation modeling scheme. A non-zero hydraulic diffusivity between the deepest soil layer modeled and groundwater table is used to couple the numerical equations of soil moisture and groundwater dynamics. Simulation of runoff generation is based on the mechanism of both infiltration excess overland flow and saturation overland flow nested in a numerical model of soil moisture dynamics. Thus, a comprehensive hydrological model integrating canopy, soil zone and aquifer has been developed to evaluate water resources in the plain region of Huaihe River basin in East China and simulate water transfer among precipitation, surface water, soil moisture and groundwater. The newly developed model is capable of calculating hydrological components of surface runoff, evapotranpiration from soil and aquifer, and groundwater recharge from precipitation and discharge into rivers. Regional parameterization is made by using two approaches. One is to determine most parameters representing specific physical values on the basis of characterization of soil properties in unsaturated zone and aquifer, and vegetations. The other is to calibrate the remaining few parameters on the basis of comparison between measured and simulated streamflow and groundwater tables. The integrated modeling system was successfully used in the Linhuanji catchment of Huaihe plain region. Study results demonstrate that (1) on the average 14.2% of precipitation becomes surface runoff and baseflow during a ten-year period from 1986 to 1995 and this figure fluctuates between only 3.0% in drought years of 1986, 1988, 1993 and 1994 to 24.0% in wet year of 1991; (2) groundwater directly deriving from precipitation recharge is about 15.0% t of the precipitation amount, and (3) about half of the groundwater recharge flows into rivers and loses through evaporation.

  • PDF

Studies on the Thermal Properties of Foods -I. Thermal Properties of Some Korean Foods- (식품(食品)의 열특성(熱特性)에 관(關)한 연구(硏究) -제(第) 1 보(報) : 한국고유식품(韓國固有食品)의 열특성(熱特性)-)

  • Chang, Kyu-Seob;Chun, Jae-Kun
    • Korean Journal of Food Science and Technology
    • /
    • v.14 no.2
    • /
    • pp.112-121
    • /
    • 1982
  • Thermal properties of 12 Korean foods were determined by using an apparatus constructed by authors. Specific heat of acorn mook showed the highest value $(0.856\;kcal/kg{\cdot}^{\circ}C)$ and that of Chungkookjang the lowest value $(0.606\;kcal/kg{\cdot}^{\circ}C)$ among 12 foods investigated. Thermal conductivity of the salted wild sesame leaf at the initial temperature of $20^{\circ}C$ was found to be the highest $(0.451\;kcal/m{\cdot}h{\cdot}^{\circ}C)$ among the foods investigated and that of mungbean mook the lowest$0.304\;kcal/m{\cdot}h{\cdot}^{\circ}C$. Thermal conductivity appeared to get higher as the initial temperature increased from $20^{\circ}C\;to\;60^{\circ}C$. Thermal diffusivity of Kochujang was the highest $(0.0877\;cm^2/min)$ and the mungbean mook the lowest($(0.0518\;cm^2/min)$ among the foods investigated. Thermal conductivity of foods also appeared to increase as the initial temperature increased. The difference between the calculated values and the measured values was very small (1.655 residual percent in the statistical analysis).

  • PDF

Numerical Study on H2 Preferential Diffusion Effect in Downstream Interactions between Premixed H2-air and CO-air Flames (상호작용 하는 H2-공기/CO-공기 예혼합화염에 미치는 H2 선호 확산 영향에 대한 수치적 연구)

  • Chung, Yong Ho;Park, Jeong;Kwon, Oh Boong;Keel, Sang In;Yun, Jin Han
    • Journal of the Korean Society of Combustion
    • /
    • v.18 no.4
    • /
    • pp.37-43
    • /
    • 2013
  • The effects of preferential diffusion of hydrogen in interacting counterflow $H_2$-air and CO-air premixed flames were investigated numerically. The global strain rate was varied in the range $30-5917s^{-1}$, where the upper bound of this range corresponds to the flame-stretch limit. Preferential diffusion of hydrogen was studied by comparing flame structures for a mixed average diffusivity with those where the diffusivities of H, $H_2$ and $N_2$ were assumed to be equal. Flame stability diagrams are presented, which show the mapping of the limits of the concentrations of $H_2$ and CO as a function of the strain rate. The main oxidation route for CO is $CO+O_2{\rightarrow}CO_2+O$, which is characterized by relatively slow chemical kinetics; however, a much faster route, namely $CO+OH{\rightarrow}CO_2+H$, can be significant, provided that hydrogen from the $H_2$-air flame is penetrated and then participates in the CO-oxidation. This modifies the flame characteristics in the downstream interaction between the $H_2$-air and CO-air flames, and can cause the interaction characteristics at the rich and lean extinction boundaries not to depend on the Lewis number of the deficient reactant, but rather to depend on chemical interaction between the two flames. Such anomalous behaviors include a partial opening of the upper lean extinction boundary in the interaction between a lean $H_2$-air flame and a lean CO-air flame, as well as the formation of two islands of flame sustainability in a partially premixed configuration with a rich $H_2$-air flame and a lean CO-air flame. At large strain rates, there are two islands where the flame can survive, depending on the nature of the interaction between the two flames. Furthermore, the preferential diffusion of hydrogen extends both the lean and the rich extinction boundaries.

Moire Interferometry Measurement and Numerical Analysis for Hygroscopic Swelling of Al-Polymer Joint (Al-Polymer 접합체의 흡습팽창에 대한 모아레 간섭 측정 및 수치해석)

  • Kim, Kibum;Kim, Yong-Yun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.6
    • /
    • pp.3442-3447
    • /
    • 2014
  • A simple method to evaluate the hygroscopic characteristics of polymer of microelectronic plastic package is suggested. To evaluate the characteristics, specimens were prepared, and the internally absorbed moisture masses were measured as a function of the absorbing time and calculated numerically. The hygroscopic pressure ratio was calculated by heat transfer analysis supported by commercial FEM code because the hygroscopic diffusion equation has the same form as the heat transfer equation. The moisture masses were then summed by the self developed code. The nonconductive polymers had quite different characteristics for the different lots, even though they were the same products. The absorbed moisture mass variations were calculated for several different characteristics, and the optimal curve of the mass variation close to experimental data was selected, whose solubility and diffusivity were affected by the hygroscopic characteristics of the material. The method can be useful in the industrial fields to quickly characterize the polymer material of the semiconductor package because the fast correspondence is normally required in industry. The weight changes in the aluminum-nonconductive-polymer joint due to moisture absorption were measured. The deformed system was also measured using the Moire Interferometry system and compared with the results of finite element analysis.

Phase Asymmetry Effect on Vesicle Fusion Induced by Phospholipase D (인지질분해효소D에 의해 유도된 소낭 융합에 대한 상 비대칭의 영향)

  • Park, Jin-Won
    • Korean Chemical Engineering Research
    • /
    • v.53 no.6
    • /
    • pp.672-676
    • /
    • 2015
  • Spherical phospholipid bilayers, vesicles, were formed with respect to phase of each layer via a double emulsion technique. The conversion of phosphatidylcholine (PC) to phosphatidic acid (PA) at the outer layer, caused by phospholipase D (PLD), induced a curvature change in the vesicles, which eventually led them to fuse each other. The effect of the lipid layer physical-properties on the PLD-induced vesicle fusion was investigated using the fluorescence intensity change. 8-Aminonaphthalene-1,3,6-trisulfonic acid disodium salt(ANTS) and p-Xylene-bis(N-pyridinium bromide)(DPX) were encapsulated in the vesicles, respectively, for the quantification of the fusion. The fluorescence scale was calibrated with the fluorescence of a 1/1 mixture of ANTS and DPX vesicles in NaCl buffer taken as 100% fluorescence (0% fusion) and the vesicles containing both ANTS and DPX as 0% fluorescence (100% fusion), considering the leakage into the medium studied directly in a separate experiment using vesicles containing both ANTS and DPX. It was observed that the fusion occurred to the liquid-phase of the inner layer only. The fusion behaviors were very similar for both solid and liquid of the outer layer. However, the leakage was faster for the solid-phase outer-layer than the liquid-phase outer-layer. The difference in the leakage seems to be caused by the lipid concentration and the lateral diffusivity in the layer.

Simulation of Mixing Behavior for Dredging Plume using Puff Model (퍼프모형을 이용한 준설플륨의 혼합거동 모의)

  • Kim, Young-Do;Park, Jae-Hyeon;Lee, Man-Soo
    • Journal of Korea Water Resources Association
    • /
    • v.42 no.10
    • /
    • pp.891-896
    • /
    • 2009
  • The puff models have been developed to simulate the advection-diffusion processes of dredging suspended solids, either alone or in combination with Eulerian models. Computational efficiency and accuracy are of prime importance in designing these hybrid approaches to simulate a pollutant discharge, and we characterize two relatively simple Lagrangian techniques in this regard: forward Gaussian puff tracking (FGPT), and backward Gaussian puff tracking (BGPT). FGPT and BGPT offer dramatic savings in computational expense, but their applicability is limited by accuracy concerns in the presence of spatially variable flow or diffusivity fields or complex no-flux or open boundary conditions. For long simulations, particle and/or puff methods can transition to an Eulerian model if appropriate, since the relative computational expense of Lagrangian methods increases with time for continuous sources. Although we focus on simple Lagrangian models that are not suitable to all environmental applications, many of the implementation and computational efficiency concerns outlined herein would also be relevant to using higher order particle and puff methods to extend the near field.

A Numerical Model for Wind-Induced Circulation in a Thermally Stratified Flow (수온성층흐름에서 바람에 의해 발생하는 순환흐름을 해석하기 위한 수치모형개발)

  • Lee, Jin-Woo;Kim, Hyung-Jun;Cho, Yong-Sik
    • Journal of Korea Water Resources Association
    • /
    • v.43 no.10
    • /
    • pp.911-920
    • /
    • 2010
  • The closed water bodies, such as reservoirs and lakes, could be contaminated by an inflow of pollutants in the upstream as well as a stratification caused by seasonal natural phenomena. The vertical circulation particularly plays an important role in reduction of environmental pollutants. The factors of the vertical circulation are the temperature, wind, thermal diffusivity and sunlight. The wind is probably the most significant factor among them. Thus, it is necessary to describe the validation and application of a three-dimensional numerical model of wind-induced circulation in a thermally stratified flow. In this paper, a three-dimensional numerical model for the thermally stratified flows is presented. The model is conducted in three steps to calculate the velocity components from the momentum equations in x- and y- axis directions, the elevations from the free surface equation and the temperature from the scalar transport equation. Numerical predictions are compared with available analytical solutions for the sloshing free surface movement in a rectangular basin. The numerical results generally show a reasonable agreement with analytical solutions. And the model is applied to the circulation for the wind induced flow in a thermally stratification. Consequently, the developed model is validated by two verifications and phenomena of the internal flow.

Evaluation of stream depletion from groundwater pumping in shallow aquifer using the Hunt's analytical solution (Hunt 해석해를 이용한 천부대수층 지하수 양수로 인한 하천수 감소 영향 분석)

  • Lee, Jeongwoo;Chung, Il Moon;Kim, Nam Won;Hong, Sung Hoon
    • Journal of Korea Water Resources Association
    • /
    • v.49 no.11
    • /
    • pp.923-930
    • /
    • 2016
  • This study was to evaluate the stream depletion from groundwater pumping in shallow aquifer using the Hunt's analytical solution (2009) which considers a two-layer leaky aquifer-stream system. From the total 2,187 cases of simulations with combinations of various aquifer and stream properties, the streamflow depletion rates divided by the groundwater pumping rate showed the low values when the stream depletion factor (SDF) is higher than 1,000-10,000, and was more sensitive to the aquitard hydraulic conductivity than the streambed hydraulic conductivity. The comparison of the Hunt's solution (2009) with the Hunt's solution (1999) of a single layer aquifer indicated that the maximum difference between the dimensionless stream depletions calculated by using both solutions is above 0.3, and the stream depletion is significantly affected by the hydraulic properties of the $2^{nd}$ layer as the SDF of the first layer increases. The Hunt's solution (2009) was applied to the real shallow groundwater well that is located in Chunju-Si, and the results revealed that the groundwater pumping has significant effects on streamflow in a short period of time, showing that the dimensionless stream depletion exceeds 0.8 within a few days. It was also found that the shallow groundwater pumping effects on stream depletion are highly dependent on the stream-well distance for the locations with high hydraulic diffusivity of $1^{st}$ layer and low vertical leakance between $1^{st}$ and $2^{nd}$ layers.