• Title/Summary/Keyword: diffusion treatment

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Experimental and Numerical Study on the Gas Mixing and Reaction in the Freeboard of a Fluidized Bed Incinerator for Sludge Treatment (슬러지 유동층 소각로의 프리보드 내 가스 혼합 및 반응 특성에 대한 실험 및 해석적 연구)

  • Kim, Young-Min;Shin, Dong-Hoon;Hwang, Seung-Sik
    • Journal of the Korean Society of Combustion
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    • v.16 no.4
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    • pp.8-15
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    • 2011
  • The present study investigates the combustion phenomena in a sludge incinerator using experimental and numerical method. The temperature and gas concentration were measured at 33 points during operation of the incinerator in order to assess the mixing and combustion characteristics. Numerical simulation was also carried out using a commercial CFD code. Simplified inlet conditions were introduced in oder to predict the bulk solid combustion and the diffusion of the volatile matter released by pyrolysis of sludge. The experimental results showed that the combustion process is extremely inhomogeneous. Large variations were observed in the temperature and gas concentrations in the freeboard of the incinerator due to poor mixing performance between the air and the combustibles, which is caused by massive and bulk generation of volatile matter by fast pyrolysis of sludge particles. The boundary condition of the CFD simulation was found effective in predicting the poor mixing and combustion performance of the reactor.

Theory of Coagulation(I) Coagulation Theory Including Hydrodynamics and Interparticle Forces (응집의 이론 (I) - 수리동역학과 입자간 작용력을 고려한 응집의 모델 -)

  • Han, Moo Young
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.3
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    • pp.65-77
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    • 1995
  • The kinetics of flocculation of heterodisperse suspension like those in water treatment plants and natural water system are usually described by the Smoluchowski equation, which incorporates collision frequency functions for particle collisions by Brownian motion, fluid shear, and differential sedimentation. These collisionfrequeney functions have been based on a rectilinear view of collisions, i.e., one that ignores short-range forces and changes in fluid motion as particles approach one another. In this research, a curvilinear approach, i.e., one that accounts for hydrodynamic forces and particle interaction in the collision of two different size particles is developed. Collision efficiency factors of each mechanism can be calculated by trajectory analysis (fluid shear and differential sedimentation) or the solution of diffusion equation (Brownian motion). The results are presented as a set of corrections to the rectilinear collision frequency functions for each mechanism.

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Breakdown characteristics of gate oxide with tungsten polycide electrode (텅스텐 폴리사이드 전극에 따른 게이트 산화막의 내압 특성)

  • 정회환;이종현;정관수
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.12
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    • pp.77-82
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    • 1996
  • The breakdown characteristics of metal-oxide-semiconductor(MOS) capacitors fabricated by Al, polysilicon, and tungsten polycide gate electrodes onto gate oxide was evaluated by time zero dielectric breakdwon (TZDB). The average breakdown field of the gate oxide with tungsten polycide electride was lower than that of the polysilicon electrode. The B model (1~8MV/cm) failure of the gate oxide with tungsten polycide electrode was increased with increasing annealing temperature in the dry $O_{2}$ ambient. This is attributed ot fluorine and tungsten diffusion from thungsten silicide film into the gate oxide, and stress increase of tungsten polcide after annealing treatment.

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A Study on the Automobile Clutch Disc Spline Hub with High Toughness by Powder Metallurgy (분말 야금에 의한 고인성 자동차 Clutch Disc Spline Hub 개발에 관한 연구)

  • 허만대;장경복;강성수
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.2
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    • pp.28-34
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    • 1998
  • Powder metallurgy processes are able to form Net-Shape products and have been widely used in the production of automobile parts to improve its productivity. However, because of pores in powder products, the toughness of powder products are generally poor. Therefore, forged products are used in parts which suffer severe fatigue loads. In this paper, the choice of powder materials and production processes such as mixing, compaction, sintering, heat treatment to produce automobile spline hub are studied. Three type of materials are selected and processed and its microstructure and properties are investigated by tensile test, compression ring test, and impact test. Materials and processing methods are selected from the results. Finally, experimental spline hubs are manufactured by selected processes from selected powders and proved by torsional durability test.

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Nd2Fe14B Synthesis: Effect of Excess Neodymium on Phase Purity and Magnetic Property

  • Jadhav, Abhijit P.;Ma, Haoxuan;Kim, Dong Soo;Baek, Youn Kyung;Choi, Chul Jin;Kang, Young Soo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.886-890
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    • 2014
  • The properties of magnetic material of Nd-Fe-B are highly affected by various factors such as particle size, magnetic anisotropy, phase purity and crystal structure. Incorporation of excess neodymium was carried out in various percentages so that it will adjust the proportion of neodymium in the host crystal after reduction treatment and finally help to improve magnetic property of a material. The interdiffusion of Nd-Fe and boron was studied for various compositions and their effect on magnetic property was understood with theoretical concepts. The factors such as amount of hard and soft phase in the reduction treated product is also responsible for the possible exchange coupling between hard and soft phase magnets for better magnetic properties.

Electrochemical Characteristics of Si/Mo Multilayer Anode for Lithium-Ion Batteries (리튬 이온 전지용 Si/Mo 다층박막 음극의 전기화학적 특성)

  • Park, Jong-Wan;Ascencio Jorge A.
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.297-301
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    • 2006
  • Si/Mo multilayer anode consisting of active/inactive material was prepared using rf/dc magnetron sputtering. Molybdenum acts as a buffer against the volume change of the Silicon. Multilayer deposited on RT (reversible treatment) copper foil current collector to enhance adhesion between Silicon and copper foil. Deposited Silicon was identified as an amorphous. Amorphous has a relatively open structure than crystal structure, thus prevents the lattice expansion and has many diffusion paths of Li ion. When deposited time of Silicon and Molybdenum is 30 second and 2 second respectably, electrode has more capacity and good cycle stability. A 3000 nm thick multilayer was maintained 99% of the initial capacity (1624 $mAhg^{-1}$) after 100 cycles. As the increase of the multilayer thickness (4500 nm, 6000 nm), Si/Mo mutilayer anodes show aggravation cycle stability.

Development of New Bimetal Material for Home Appliances by Using the Rolling Process (압연공정을 이용한 가전용 신 바이메탈재의 개발)

  • Park, S.S.;Lee, J.H.;Bae, D.H.;Bae, D.S.
    • Transactions of Materials Processing
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    • v.16 no.5 s.95
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    • pp.375-380
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    • 2007
  • The bimetals of home appliances are mainly manufactured by cladding process and these are almost consisted with Cu alloy and Ni alloy. But it is very difficult to clad these alloys, because the brittle $Cu_3O_4$ oxide film formed easily on Cu alloy surface during cladding process. Clad rolling and heat treatment processes were applied for the development of bimetals by using the Ni alloy and the 3 types of Cu alloys. Optical microstructure, micro-hardness, specific resistance, and deflection and line profile of newly processed bimetals specimens were observed and measured in this paper. Inter-diffusion was observed between Cu and Ni element in the interface of heat treated Cu alloy and Ni alloy clad material. The C1220 and Invar36 clad material showed the best property of deflection among the 3 kind of clad materials.

Diffusion-accompanied Phase Transformation of $TiSi_2$ Film Confined in Sub-micron Area

  • Kim, Yeong-Cheol
    • The Korean Journal of Ceramics
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    • v.7 no.2
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    • pp.70-73
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    • 2001
  • Phase transformation of TiSi$_2$ confined in sub-micron area of which the size is around or smaller than the grain size of C49 TiSi$_2$ phase is studied. It has been known that the C49 to C54 phase change is massive transformation that occurs abruptly starting from C54 nuclei located at triple point grain boundaries of C49 phase. When the C49 phase is confined in sub-micron area, however, the massive phase transformation is observed to be hindered due to the lack of the triple point grain boundaries of C49 phase. Heat treatment at higher temperatures starts to decompose the C49 phase, and the resulting decomposed Ti atoms diffuse to, and react with, the underneath Si material to form C54 phase that exhibits spherical interface with silicon. The newly formed C54 grains can also trigger the massive phase transformation to convert the remaining undecomposed C49 grains to C54 grains by serving as nuclei like conventional C54 nuclei located at triple point grain boundaries.

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Manufacture of Precision Thin film Resistors using Ni-Cr Alloy and Their Properties (Ni-Cr계 합금을 이용한 정밀 박막저항체의 제조 및 특성)

  • Lee Young Hwa;Park Se Il;Kim Kook Jin;Ihm Young Eon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.52-57
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    • 2006
  • Precision thin film resistors using evanohm R alloy were fabricated by do magnetron sputtering method. The physical and electrical properties of the resistors were studied after treatment of thermal annealing. The crystallization of the film was increased as the annealing temperature increase. Diffusion and oxidation of Cr and Al elements were occurred into the film surface. The minimum TCR values of 10.46 ppm/$^{\circ}C$ and 10.65 ppm/$^{\circ}C$ were measured at the annealing temperatures of $200^{\circ}C$ and $300^{\circ}C$, respectively. We are conducting additional studies to improve characteristics of our resistors for practical device application.

Characteristics of Oxynitride Dielectics Prepared in $N_2O$ Ambient by Furnace (Furnace로 $N_2O$ 분위기에서 성장시킨 Oxynitride 절연막 특성)

  • 이은구;박인길;박진성
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.31-36
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    • 1995
  • (100) Si was oxidized in N2O ambient, and the film properties of oxynitride dielectrics were compared with pure SiO2. The growth rate, after pre-oxidation in O2/N2 ambient with raising temperature, is faster than that of O2/N2O treatment during the same condition. Nitrogen piles up at the interface of SiO2 and Si substrate and the content is about 2atom%. Comparing with pure SiO2, oxynitride dielectrics shows less dielectric breakdown failures and flat-band voltage shift, and good diffusion barrier property to dopant(BF2) is also observed.

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