• Title/Summary/Keyword: diffusion limit

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Numerical Analysis of Characteristics of Cellular Counterflow Diffusion Flames near Radiative Extinction Limit (복사 열손실에 의한 소염근처에서 셀모양 대향류 확산화염의 특성에 대한 수치해석)

  • Lee, Su Ryong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.6
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    • pp.493-500
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    • 2014
  • Nonlinear characteristics of cellular counterflow diffusion flame near the radiative extinction limit at large Damk$\ddot{o}$hler number are numerically investigated. Lewis number is assumed to be 0.5 and flame evolution is calculated by imposing an infinitesimal disturbance to a one-dimensional(1-D) steady state flame. The early stage of nonlinear development is very similar to that predicted in a linear stability analysis. The disturbance with the wavenumber of the fastest growing mode emerges and grows gradually. Eventual, an alternating pattern of reacting and quenching stripes is developed. The cellular flame temperature is higher than that of 1-D flame because of the gain of the total enthalpy. As the Damk$\ddot{o}$hler number is further increased, the shape of the cell becomes circular to increase the surface area per unit reacting volume. The cellular flames do not extinguish but survive even above the 1-D steady state extinction condition.

Dispersion Model of Initial Consequence Analysis for Instantaneous Chemical Release (순간적인 화학물질 누출에 따른 초기 피해영향 범위 산정을 위한 분산모델 연구)

  • Son, Tai Eun;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.37 no.2
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    • pp.1-9
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    • 2022
  • Most factories deal with toxic or flammable chemicals in their industrial processes. These hazardous substances pose a risk of leakage due to accidents, such as fire and explosion. In the event of chemical release, massive casualties and property damage can result; hence, quantitative risk prediction and assessment are necessary. Several methods are available for evaluating chemical dispersion in the atmosphere, and most analyses are considered neutral in dispersion models and under far-field wind condition. The foregoing assumption renders a model valid only after a considerable time has elapsed from the moment chemicals are released or dispersed from a source. Hence, an initial dispersion model is required to assess risk quantitatively and predict the extent of damage because the most dangerous locations are those near a leak source. In this study, the dispersion model for initial consequence analysis was developed with three-dimensional unsteady advective diffusion equation. In this expression, instantaneous leakage is assumed as a puff, and wind velocity is considered as a coordinate transform in the solution. To minimize the buoyant force, ethane is used as leaked fuel, and two different diffusion coefficients are introduced. The calculated concentration field with a molecular diffusion coefficient shows a moving circular iso-line in the horizontal plane. The maximum concentration decreases as time progresses and distance increases. In the case of using a coefficient for turbulent diffusion, the dispersion along the wind velocity direction is enhanced, and an elliptic iso-contour line is found. The result yielded by a widely used commercial program, ALOHA, was compared with the end point of the lower explosion limit. In the future, we plan to build a more accurate and general initial risk assessment model by considering the turbulence diffusion and buoyancy effect on dispersion.

Combustion characteristics of coaxial diffusion flame with preheated air temperature and dilution level (예열공기온도와 희석비율에 따른 동축 확산 화염의 연소 특성)

  • Kim, Jin-Sik;Kwark, Ji-Hyun;Jeon, Chung-Hwan;Chang, Young-June
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.51-56
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    • 2001
  • An experiment using preheated air in the coaxial diffusion flame burner was carried out in order to decrease NOx emission and improve the thermal efficiency. Preheated air combustion generally produces high NOx emissions but it was known very well to reduce NOx emission by diluting the combustion air with inert gas in preheated air combustion. In our study, $N_2$ gas was used for diluent and propane was utilized for fuel. We set the combustion air temperature on 300K, 500K, 700K, 900K and dilution level from 21% to 10% in terms of oxygen concentration. NOx emission increased along increment of combustion air temperature and decreased along increment of dilution level(lowering of oxygen concentration in combustion air). Flame-off limit with dilution level enhanced, flame length became longer and the location of maximum flame temperature became lower with increasing of combustion air temperature.

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Activation Energy Asymptotics Revisited (I);Quasisteady Extinction conidtion of Diffusion Flames (활성화에너지점근법의 재고찰 (I);확산화염의 준정상소화조건)

  • Kim, Jong-Soo
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.124-132
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    • 2004
  • Activation energy asymptotics (AEA) for Linan's diffusion-flame regime is revisited in this paper. The main purpose of the paper is to carefully re-examine each AEA analysis step in order to clarify the some concepts that are often misunderstood among the ordinary practitioners of the AEA. Particular attention is focused on the different AEA regimes arising from the double limit of large Zel'dovich and Damkohler numbers. In addition. the expansion procedures are shown in detail and the method that the turning point condition, commonly known as the Linan's extinction condition, is found is explained.

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The Analysis of Chloride Ion Penetration into a Concrete Structure in Marine Environment (해안환경하에 있는 콘크리트의 염분침투해석)

  • Cho, Sun-Kyu;Jeon, Gui;Shin, Chee-Burm
    • Journal of Ocean Engineering and Technology
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    • v.12 no.3 s.29
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    • pp.68-74
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    • 1998
  • An increase of concrete construction in marine environments as well as an increasing use of marine aggregate at the mixing stage of concrete has provoked an important problem. A high concentration of chloride ion in the vicinity of steel bars in concrete is the principal cause of premature reinforcement corrosion in concrete structures. In this study, the behavior of chloride ions introduced into concrete from concrete surface by marine evironment was analysed. A mathematical model including the diffusion of chloride ion in aqueous phase of pores, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete and the chemical reactions of chloride ions with solid phase was presented. Finite element method was employed to carry out numerical analysis. The results of this study may be used to predict the onset of reinforcement corrosion and to identify the maximum limit of chloride ions contained in concrete admixtures.

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Corrosion initiation time models in RC coastal structures based on reliability approach

  • Djeddi, Lamine;Amirat, Abdelaziz
    • Advances in concrete construction
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    • v.9 no.2
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    • pp.149-159
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    • 2020
  • The present work proposes new engineering models for determining corrosion initiation time in concrete reinforcing steels in marine environment. The models are based on Fick's second law that is commonly used for chloride diffusion. The latter is based on deterministic analyses involving the most influencing parameters such as distance of the concrete structure from the seaside, depth of steel concrete cover, ambient temperature, relative humidity and the water-cement ratio. However, a realistic corrosion initiation time cannot be estimated because of the uncertainties associated to the different parameters of the models. Therefore a reliability approach using FORM/SORM method has been applied to develop the proposed engineering models integrating a limit state function and a reliability index β. As a result, the corrosion initiation time is expressed by new exponential engineering models where the uncertainties are associated to the model parameters. The main emerging result is a realistic decision tool for corrosion planning inspection.

Durability Evaluation of RC Structures subjected. to Chloride Attack (철근콘크리트 구조물의 염해 내구성 평가)

  • 백승우;남진원;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.663-668
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    • 2003
  • In this paper, an environmental factor and a durability resistance factor which adapts the concept of the Load Resistance Factor Design for safety design of RC structures is derived and a basic principle of a durability evaluation for RC structures using the factors is proposed. It is shown that durability of RC structures can be evaluated by comparing predicted value of chloride ion concentration with limit value of concentration for steel corrosion generation in reinforcement steel position and the durability of concrete manufactured for the RC structures can be also evaluated by comparing characteristic diffusion coefficient of concrete with predicted diffusion coefficient during mixture design.

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A Study on the Flame Structure and Stabilization in a Divergent Flow (확대관 흐름에 있어서 화염의 안정성 및 구조에 관한 연구)

  • 최병륜;이중성
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.2
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    • pp.512-518
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    • 1994
  • An experimental study is made on turbulent diffusion flames stabilized by a circular cylinder in a divergence flow. In this paper, stabilization characteristics and flame structure are examined by varying the divergence angle of duct and position of a circular cylinder. The fuel used is a commercial grade gaseous propane injected by two slit of rod. It is found that the positive pressure gradient greatly influences the eddy structure behind the rod. and that two different kinds of combustion patterns exist at the blowoff limit depending on the divergent angle of duct. They are distinguished by their wake structures: one associated with Karman vortex shedding, the other without it. Also, the blowoff velocity in the former is found to be higher than in the later.

Diffusive Shock Acceleration with Self-Consistent Injection

  • KANG HYESUNG
    • Journal of The Korean Astronomical Society
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    • v.34 no.4
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    • pp.293-295
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    • 2001
  • A numerical scheme that incorporates a self-consistent cosmic-ray (CR, hereafter) injection model into the combined gas dynamics and CR diffusion-convection code has been developed. The hydro/CR code can follow in a very cos-effective way the evolution of CR modified shocks by adopting subzone shock-tracking and multi-level Adaptive Mesh Refinement techniques. The injection model is based on interactions of the suprathermal particles with self-generated MHD waves in quasi-parallel shocks. The particle injection is followed numerically by filtering the diffusive flux of suprathermal particles across the shock to upstream region according to a velocity-dependent transparency function, which represents the fraction of leaking suprathermal particles. In the strong shock limit of Mach numbers $\ge$20, significant physical processes such as the injection and acceleration seem to become independent of M, while they are sensitively dependent on M for M < 10. Although some particles injected early in the evolution continue to be accelerated to higher energies, the postshock CR pressure reaches a time asymptotic value due to balance between acceleration and diffusion of the CR particles.

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On the Extinction Characteristics of the Interacting Lean-Lean Premixed Flames (상호작용을 하는 희박-희박 예혼합화염의 소화특성에 관한 연구)

  • 정석호;김종수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.2
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    • pp.232-240
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    • 1986
  • Extinction characteristics of the two interacting premixed flames are analyzed for the effects of flame stretch and preferential diffusion using large activation energy asymptotic analysis by adopting counterflow system as a model problem. Results show that the flammable limit of the thermally interacting premixed flames is extended compared to the single flame, and the extinction mechanism is classified into weak and strong interactions. As the lewis number of the deficient species increases, the region of strong interaction diminishes which can explain the different characteristics of the extinction boundaries of the lean (rich) methane/air and butane/air flames. The influence of the flame stretch to the interaction boundaries is also studied.